Surface modification of halloysite nanotubes by vulcanization accelerator and properties of styrene-butadiene rubber nanocomposites with modified halloysite nanotubes

2016 ◽  
Vol 366 ◽  
pp. 193-201 ◽  
Author(s):  
Bangchao Zhong ◽  
Zhixin Jia ◽  
Dechao Hu ◽  
Yuanfang Luo ◽  
Baochun Guo ◽  
...  
ACS Omega ◽  
2019 ◽  
Vol 4 (8) ◽  
pp. 13189-13199 ◽  
Author(s):  
Alex Sinclair ◽  
Xiaoyi Zhou ◽  
Siwakorn Tangpong ◽  
Dilpreet S. Bajwa ◽  
Mohiuddin Quadir ◽  
...  

2006 ◽  
Vol 101 (5) ◽  
pp. 2725-2731 ◽  
Author(s):  
Ming Tian ◽  
Lijun Cheng ◽  
Wenli Liang ◽  
Liqun Zhang

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 883 ◽  
Author(s):  
Jing Lin ◽  
Dechao Hu ◽  
Yuanfang Luo ◽  
Bangchao Zhong ◽  
Yongjun Chen ◽  
...  

Vulcanization and reinforcement are critical factors in governing the ultimate practical applications of elastomer composites. Here we achieved a simultaneous improvement of curing and mechanical properties of elastomer composites by the incorporation of a functionalized halloysite nanotubes–silica hybrid (HS-s-M). Typically, HS-s-M was synthesized by 2-mercapto benzothiazole (M) immobilized on the surface of halloysite nanotubes–silica hybrid (HS). It was found that the HS-s-M uniformly dispersed in the styrene-butadiene rubber (SBR) matrix, offering more opportunity for M molecules to communicate with rubber. In addition, the physical loss of accelerator M from migration and volatilization was efficiently suspended. Therefore, SBR/HS-s-M composites showed a lower curing activation energy and a higher crosslinking density than SBR/HS composites. Moreover, a stronger interfacial interaction between HS-s-M and SBR was formed by the cross-linking reaction, giving a positive contribution to the eventual mechanical properties. The possible vulcanization and reinforcement mechanisms of SBR/HS-s-M composites were also analyzed in detail.


2010 ◽  
Vol 150-151 ◽  
pp. 762-765
Author(s):  
Ji Hu Wang ◽  
Hong Bo Liu ◽  
Shao Guo Wen ◽  
Yan Shen

Attapulgite (AT)/natural rubber (NR)/ styrene-butadiene rubber (SBR) nanocomposites have been prepared after attapulgite was modified by different coupling agent. The treatment of AT caused the adhesion between AT nanorods and the nature rubber/styrene-butadiene rubber was improved, which enhanced the tensile properties of the matrix. The tensile strength of composites attained 15.6 MPa after AT was modified by 3%wt Si-69 coupling with addition of 20 phr.


2017 ◽  
Vol 58 (8) ◽  
pp. 1409-1418 ◽  
Author(s):  
Yang Chen ◽  
Qing Yin ◽  
Xumin Zhang ◽  
Hongbing Jia ◽  
Qingmin Ji ◽  
...  

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