Effect of cetyl trimethyl ammonium bromide concentration on structure, morphology and carbon dioxide adsorption capacity of calcium hydroxide based sorbents

2016 ◽  
Vol 363 ◽  
pp. 586-592 ◽  
Author(s):  
Nwe Ni Hlaing ◽  
K. Vignesh ◽  
Srimala Sreekantan ◽  
Swee-Yong Pung ◽  
Hirofumi Hinode ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Calcium Hydroxide ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Ammonium Bromide ◽  
Carbon Dioxide Adsorption ◽  
Structure Morphology ◽  
Cetyl Trimethyl Ammonium

Influence of intramolecular interactions on carbon dioxide gas adsorption capacity in Mesoporous Imine polymers

2018 ◽  
Author(s):  
Jaya Prakash Madda ◽  
Pilli Govindaiah ◽  
Sushant Kumar Jena ◽  
Sabbhavat Krishna ◽  
Rupak Kishor
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Density Functional ◽  
Gas Adsorption ◽  
Ambient Pressure ◽  
Condensation Reaction ◽  
Intramolecular Interactions ◽  
Carbon Dioxide Adsorption ◽  
Nitrogen Gas ◽  
Adsorption Characteristic

<p>Covalent organic Imine polymers with intrinsic meso-porosity were synthesized by condensation reaction between 4,4-diamino diphenyl methane and (para/meta/ortho)-phthaladehyde. Even though these polymers were synthesized from precursors of bis-bis covalent link mode, the bulk materials were micrometer size particles with intrinsic mesoporous enables nitrogen as well as carbon dioxide adsorption in the void spaces. These polymers were showed stability up to 260<sup>o</sup> centigrade. Nitrogen gas adsorption capacity up to 250 cc/g in the ambient pressure was observed with type III adsorption characteristic nature. Carbon dioxide adsorption experiments reveal the possible terminal amine functional group to carbamate with CO<sub>2</sub> gas molecule to the polymers. One of the imine polymers, COP-3 showed more carbon dioxide sorption capacity and isosteric heat of adsorption (Q<sub>st</sub>) than COP-1 and COP-2 at 273 K even though COP-3 had lower porosity for nitrogen gas than COP-1 and COP-2. We explained the trends in gas adsorption capacities and Qst values as a consequence of the intra molecular interactions confirmed by Density Functional Theory computational experiments on small molecular fragments.</p>

scholarly journals Preparation of Porous Hydroxyapatite Using Cetyl Trimethyl Ammonium Bromide as Surfactant for the Removal of Lead Ions from Aquatic Solutions

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1617
Author(s):  
Silviu-Adrian Predoi ◽  
Carmen Steluta Ciobanu ◽  
Mikael Motelica-Heino ◽  
Mariana Carmen Chifiriuc ◽  
Monica Luminita Badea ◽  
...  
Keyword(s):  
Cetyl Trimethyl Ammonium Bromide ◽  
Morphological Changes ◽  
Low Cost ◽  
Lead Ions ◽  
Ammonium Bromide ◽  
Porous Hydroxyapatite ◽  
X Ray ◽  
Composition And Structure ◽  
Cetyl Trimethyl Ammonium ◽  
Co Precipitation

In the present study, a new low-cost bioceramic nanocomposite based on porous hydroxyapatite (HAp) and cetyl trimethyl ammonium bromide (CTAB) as surfactant was successfully obtained by a simple chemical co-precipitation. The composition and structure of the HAp-CTAB were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), scanning electron microscope (SEM) equipped with an energy dispersive X-ray (EDX) spectrometer, and N2 adsorption/desorption analysis. The capacity of HAp-CTAB nanocomposites to remove the lead ions from aqueous solutions was studied by adsorption batch experiments and proved by Langmuir and Freundlich models. The Pb2+ removal efficiency of HAp-CTAB biocomposite was also confirmed by non-destructive ultrasound studies. The cytotoxicity assays showed that the HAp-CTAB nanocomposites did not induce any significant morphological changes of HeLa cells after 24 h of incubation or other toxic effects. Taken together, our results suggests that the obtained porous HAp-CTAB powder could be used for the decontamination of water polluted with heavy metals, such as Pb2+.

Influence of Different Dispersants on the Dispersion Property of Nano-Aluminium Powders

2011 ◽  
Vol 71-78 ◽  
pp. 122-125 ◽  
Author(s):  
Ling Li Song ◽  
Ren Yuan Zhang ◽  
Ling Bo Mao ◽  
Wen Jie Zhu ◽  
Miao Yan Zheng
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Ultrasonic Vibration ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Sodium Dodecyl ◽  
Dispersion Property ◽  
Ammonium Bromide ◽  
Aluminum Powders ◽  
Ultrasonic Time ◽  
Dodecyl Sulfate ◽  
Cetyl Trimethyl Ammonium

The influences of dispersant type, supersonic time and concentration on the dispersion property of the nano-aluminium powders in glycol water were systematically studied by using Sodium dodecyl sulfate (SDS)，cetyl trimethyl ammonium bromide (CTAB) and sodium hexa metah posphate（SHMP）as dispersants. During the first stage of the experiments, influences of dispersant type and ultrasonic time with these dispersants were evaluated. The next stage of the study was focused on SHMP concentration. The influence of SHMP concentration was assessed. The results show that with the increasing of ultrasonic time, the dispersion property of nano-aluminum powders first increases and then decreases, and SHMP is the best one. The excellent dispersing condition on the dispersion property of nano-aluminium is: 5g/L SHMP and 50 min ultrasonic vibration.

scholarly journals SYNTHESIS OF COPPER NANOPARTICLES USING ASCORBIC ACID AND CETYL TRIMETHYL AMMONIUM BROMIDE

2018 ◽  
Vol 11 (14) ◽  
pp. 62
Author(s):  
Saurabh Singh ◽  
Bimlesh Kumar ◽  
Narendra Kumar Pandey ◽  
Barinder Kaur ◽  
Arun Kumar ◽  
...  
Keyword(s):  
Ascorbic Acid ◽  
Copper Nanoparticles ◽  
Cetyl Trimethyl Ammonium Bromide ◽  
Ammonium Bromide ◽  
Distilled Water ◽  
Bromide Solution ◽  
Cetyl Trimethyl Ammonium ◽  
Dialysis Bag ◽  
Spray Dried ◽  
Glass Beaker

Objective: The present study highlights the development of a method to synthesize copper nanoparticles (CuNPs).Methods: CuNPs were developed using 0.01 M copper penta sulfate and 0.11 M of ascorbic acid (AA) and 0.03 M of cetyl trimethyl ammonium bromide solution. The synthesized CuNPs were differentiated through filtration and washed by water (deionized). CuNPs were kept in dialysis bag 70 KD in a 250 mL glass beaker along with distilled water. The assembly was kept on a magnetic stirrer for 24 h at 500 rpm. Then, the dialysis bag containing CuNPs solution was filtered by a filter assembly with 0.2 μm nylon filter. The filtered CuNPs were spray dried with the help of spray drier.Results: The prepared CuNPs were found to be 440 nm with zeta potential of −10 mV and polydispersity index 0.314.Conclusion: The investigation deciphers the promising and material technique to synthesis of CuNPs by methods for synthetic reduction utilizing strategy using AA (0.2 M) and sodium hydroxide (1 M), and Syloid 244FP.

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