Comparison of corrosion behavior between coarse grained and nano/ultrafine grained alloy 690

2016 ◽  
Vol 360 ◽  
pp. 403-408 ◽  
Author(s):  
Lv Jinlong ◽  
Liang Tongxiang ◽  
Wang Chen ◽  
Guo Ting
Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 917 ◽  
Author(s):  
Jiang Liu ◽  
Junbiao Liu ◽  
Xuehui Zhang ◽  
Tahir Ahmad ◽  
Tongxiang Liang ◽  
...  

The nanograins (NG) on the top surface layer of alloy 690 were successfully prepared by ultrasonic surface rolling treatment (USRT). The average grain size of NG alloy 690 was 55 nm, and the thickness of the NG surface layer was about 1 μm. Meanwhile, the surface roughness was significantly reduced after surface nanocrystalliztion. The corrosion behavior of alloy 690 before and after USRT was studied in a secondary side environment containing chloride. Electrochemical corrosion experiments demonstrated that the passive film generated by USRT was denser than that formed on coarse-grained (CG) alloy 690. Pitting corrosion was prone to occur in grain boundaries of CG alloy 690, and the pits on the surface of NG alloy 690 were smaller than those generated on CG alloy 690 after 1000 h of an immersion experiment.


Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 950 ◽  
Author(s):  
Zequn Yu ◽  
Yuecheng Dong ◽  
Xin Li ◽  
Jingzhe Niu ◽  
Igor Alexandrov ◽  
...  

The aim of this study was to investigate the corrosion resistance of ultrafine-grained (UFG) Ti-6Al-7Nb fabricated by equal channel angular pressing (ECAP) and coarse-grained (CG) Ti- 6Al- 7Nb. The microstructure of each specimen was investigated by the electron backscattered diffraction (EBSD) method. The corrosion behavior of each specimen was determined by electrochemical measurement in Ringer’s solution. The surface corroded morphologies and oxide film formed on Ti-6Al-7Nb alloy after electrochemical measurement were investigated by scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). EBSD investigation shows that the grain size of UFG Ti-6Al-7Nb decreased to ~0.4 µm, accompanied by low angle grain boundaries (LAGBs) accounting for 39%. Potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) results indicated that UFG Ti-6Al-7Nb alloy possessed a better corrosion resistance. The surface corroded morphologies revealed many small and shallow corrosion pits, which can be attributed to the good compactness of the oxide film and a rapid self- repairing ability of the UFG Ti-6Al-7Nb alloy.


2021 ◽  
Vol 2124 (1) ◽  
pp. 012026
Author(s):  
E M Kayumova ◽  
A A Churakova ◽  
O R Latypov

Abstract This article studies the corrosion behavior of the TiNi alloy in the coarse-grained and ultrafine-grained states. The study of the influence of the initial microstructure on the corrosion behavior of the TiNi alloy was carried out by the gravimetric method in the NaCl and H2SO4 solution for a month. Studies was shown that as a result of the action of a corrosive medium from a sample in a coarse-grained state, it undergoes greater destruction, pitting corrosion was observed, at the same time, in an ultrafine-grained sample only traces of corrosion products are observed on the surface of the samples. Investigations with an inverted light microscope in a dark field made it possible to observe corrosion products and determine their volume fraction. Evaluation of the corrosion rate showed that in the coarse-grained state it is 126 times higher than the corrosion rate in the ultrafine-grained state. Analysis of X-ray phase analysis showed that in the coarse-grained state after corrosion tests, a significant proportion of the TiNiH1.4 phase is observed, while in the ultrafine-grained state all phases correspond only to the TiNi phases. The TiNi alloy contains an Ti2Ni phase enriched Ti both in the coarse-grained state and in the ultrafine-grained state. Moreover, in a coarse-grained state, its share is 2 times higher.


2015 ◽  
Vol 60 (2) ◽  
pp. 605-614 ◽  
Author(s):  
T. Kvačkaj ◽  
A. Kováčová ◽  
J. Bidulská ◽  
R. Bidulský ◽  
R. Kočičko

AbstractIn this study, static, dynamic and tribological properties of ultrafine-grained (UFG) oxygen-free high thermal conductivity (OFHC) copper were investigated in detail. In order to evaluate the mechanical behaviour at different strain rates, OFHC copper was tested using two devices resulting in static and dynamic regimes. Moreover, the copper was subjected to two different processing methods, which made possible to study the influence of structure. The study of strain rate and microstructure was focused on progress in the mechanical properties after tensile tests. It was found that the strain rate is an important parameter affecting mechanical properties of copper. The ultimate tensile strength increased with the strain rate increasing and this effect was more visible at high strain rates$({\dot \varepsilon} \sim 10^2 \;{\rm{s}}^{ - 1} )$. However, the reduction of area had a different progress depending on microstructural features of materials (coarse-grained vs. ultrafine-grained structure) and introduced strain rate conditions during plastic deformation (static vs. dynamic regime). The wear behaviour of copper was investigated through pin-on-disk tests. The wear tracks examination showed that the delamination and the mild oxidational wears are the main wear mechanisms.


2017 ◽  
Vol 19 (7) ◽  
pp. 1600807 ◽  
Author(s):  
Marta Lipińska ◽  
Ewa Ura-Bińczyk ◽  
Lech Olejnik ◽  
Andrzej Rosochowski ◽  
Małgorzata Lewandowska

2008 ◽  
Vol 584-586 ◽  
pp. 182-187
Author(s):  
Lilia Kurmanaeva ◽  
Yulia Ivanisenko ◽  
J. Markmann ◽  
Ruslan Valiev ◽  
Hans Jorg Fecht

Investigations of mechanical properties of nanocrystalline (nc) materials are still in interest of materials science, because they offer wide application as structural materials thanks to their outstanding mechanical properties. NC materials demonstrate superior hardness and strength as compared with their coarse grained counterparts, but very often they possess a limited ductility or show low uniform elongation due to poor strain hardening ability. Here, we present the results of investigation of the microstructure and mechanical properties of nc Pd and Pd-x%Ag (x=20, 60) alloys. The initially coarse grained Pd-x% Ag samples were processed by high pressure torsion, which resulted in formation of homogenous ultrafine grain structure. The increase of Ag contents led to the decrease of the resulted grain size and change in deformation behavior, because of decreasing of stacking fault energy (SFE). The samples with larger Ag contents demonstrated the higher values of hardness, yield stress and ultimate stress. Remarkably the uniform elongation had also increased with increase of strength.


2010 ◽  
Vol 2010 (5) ◽  
pp. 456-460 ◽  
Author(s):  
N. A. Amirkhanova ◽  
R. Z. Valiev ◽  
E. Yu. Chernyaeva ◽  
E. B. Yakushina ◽  
I. P. Semenova

2015 ◽  
Vol 112 (47) ◽  
pp. 14501-14505 ◽  
Author(s):  
Xiaolei Wu ◽  
Muxin Yang ◽  
Fuping Yuan ◽  
Guilin Wu ◽  
Yujie Wei ◽  
...  

Grain refinement can make conventional metals several times stronger, but this comes at dramatic loss of ductility. Here we report a heterogeneous lamella structure in Ti produced by asymmetric rolling and partial recrystallization that can produce an unprecedented property combination: as strong as ultrafine-grained metal and at the same time as ductile as conventional coarse-grained metal. It also has higher strain hardening than coarse-grained Ti, which was hitherto believed impossible. The heterogeneous lamella structure is characterized with soft micrograined lamellae embedded in hard ultrafine-grained lamella matrix. The unusual high strength is obtained with the assistance of high back stress developed from heterogeneous yielding, whereas the high ductility is attributed to back-stress hardening and dislocation hardening. The process discovered here is amenable to large-scale industrial production at low cost, and might be applicable to other metal systems.


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