Hydroxyapatite/gelatin functionalized graphene oxide composite coatings deposited on TiO2 nanotube by electrochemical deposition for biomedical applications

2015 ◽  
Vol 329 ◽  
pp. 76-82 ◽  
Author(s):  
Yajing Yan ◽  
Xuejiao Zhang ◽  
Huanhuan Mao ◽  
Yong Huang ◽  
Qiongqiong Ding ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Electrochemical Deposition ◽  
Biomedical Applications ◽  
Composite Coatings ◽  
Tio2 Nanotube ◽  
Functionalized Graphene ◽  
Functionalized Graphene Oxide ◽  
Oxide Composite

scholarly journals Synthesis of Silane Functionalized Graphene Oxide and Its Application in Anti-Corrosion Waterborne Polyurethane Composite Coatings

Coatings ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 587 ◽  
Author(s):  
Chao Chen ◽  
Shicheng Wei ◽  
Bin Xiang ◽  
Bo Wang ◽  
Yujiang Wang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Corrosion Rate ◽  
Electrochemical Impedance ◽  
Composite Coatings ◽  
Condensation Reaction ◽  
Waterborne Polyurethane ◽  
Functionalized Graphene ◽  
Functionalized Graphene Oxide ◽  
Polyurethane Composite ◽  
Modified Graphene Oxide

In this study, novel silane functionalized graphene oxide (PVSQ-GO) composite material is synthesized through the hydrolysis condensation reaction of vinyl triethoxysilane monomers occurred at the surface of graphene oxide. Results obtained from FTIR, Raman, X-ray photoelectronic spectroscopy (XPS), XRD and TGA measurements reveal that polyvinyl sesquisiloxane microspheres adhere to graphene oxide lamellae in the form of chemical bonds. Meanwhile, it is intuitive that abundant polyvinyl sesquisiloxane microspheres stick to the surface of graphene oxide and increase the thickness of the flake. Modified graphene oxide changes from hydrophilicity to hydrophobicity were owing to the existence of polyvinyl sesquisiloxane microspheres on the surface of graphene oxide (GO). PVSQ-GO composite exhibited good dispersion in eco-friendly waterborne polyurethane coating. Electrochemical impedance spectroscopy manifested that the anti-corrosion performance of waterborne polyurethane (WPU) coating embedded at 0.5 wt.% PVSQ-GO composite improved effectively. Tafel curves reveal that 0.5 wt.% PVSQ-GO/WPU coating specimen shows the lowest corrosion rate of 8.95 × 10−5 mm/year when compared with the other coating specimens. The good anti-corrosion abilities of PVSQ-GO composite coating can be interpreted as the good compatibility between PVSQ-GO composite and waterborne polyurethane, however, the intrinsic hydrophobicity of PVSQ-GO composite is beneficial to inhibit the permeation of corrosive medium and thus slows down the corrosion rate.

Sign in / Sign up

Export Citation Format

Share Document