Magnetic solid base catalyst CaO/CoFe2O4 for biodiesel production: Influence of basicity and wettability of the catalyst in catalytic performance

2014 ◽  
Vol 317 ◽  
pp. 1125-1130 ◽  
Author(s):  
Pingbo Zhang ◽  
Qiuju Han ◽  
Mingming Fan ◽  
Pingping Jiang
Keyword(s):  
Catalytic Performance ◽  
Biodiesel Production ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Magnetic Solid

scholarly journals Utilization of Carbide Lime Waste as Base Catalyst for Biodiesel Production

2018 ◽  
Vol 7 (4.35) ◽  
pp. 700 ◽  
Author(s):  
Koguleshun Subramaniam ◽  
Sasidevan Munusamy ◽  
Fei-ling Pua ◽  
Mohd Aizat Mohd Nasir ◽  
Rohaya Othman ◽  
...  
Keyword(s):  
Ester Group ◽  
Catalytic Performance ◽  
Biodiesel Production ◽  
Strength Analysis ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
X Ray ◽  
Solid Base Catalysts ◽  
Base Catalysts

Calcium rich solid base catalyst was synthesized from local waste carbide lime and its catalytic performance was evaluated via biodiesel production. Carbide lime waste was used to produce CLW-I and CLW-II solid base catalyst using different preparation methods. Characterization including base strength analysis, scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD) were investigated. Catalytic strength was examined by deploying the solid base catalysts for transesterification reaction of palm oil. Fourier Transform Infra-red (FTIR) was used to analyze the presence of ester group in biodiesel. The yield of biodiesel conversion was calculated based on the mass of biodiesel and glycerol. The highest biodiesel conversion rate of 75.30% was achieved by CLW-I solid base catalyst at 9% loading. The good catalytic performance of carbide lime waste derived solid base catalysts proves that it has high potential to replace the usage of conventional catalyst in the biodiesel industry.

Magnetic Solid Base Catalyst Fe3 O4 @Gly Used as Acid-Resistant Catalyst for Biodiesel Production

2018 ◽  
Vol 65 (6) ◽  
pp. 681-686 ◽  
Author(s):  
Pingbo Zhang ◽  
Min Shi ◽  
Mingming Fan ◽  
Pingping Jiang ◽  
Yuming Dong
Keyword(s):  
Biodiesel Production ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Magnetic Solid

scholarly journals Biodiesel production from soybean oils by a novel nano-magnetic solid base catalyst (K/ZrO2/γ-Fe2O3)

RSC Advances ◽  
2017 ◽  
Vol 7 (82) ◽  
pp. 51814-51821 ◽  
Author(s):  
Kang Liu ◽  
Rui Wang ◽  
Meiqing Yu
Keyword(s):  
Fossil Fuels ◽  
Biodiesel Production ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Alternative Source ◽  
Soybean Oils ◽  
Magnetic Solid

Biodiesel is emerging as a green alternative source to fossil fuels due to its clean and renewable advantages.

scholarly journals Hierarchical Cs–Pollucite Nanozeolite Modified with Novel Organosilane as an Excellent Solid Base Catalyst for Claisen–Schmidt Condensation of Benzaldehyde and Acetophenone

Processes ◽  
2020 ◽  
Vol 8 (1) ◽  
pp. 96 ◽  
Author(s):  
Aleid Ghadah Mohammad S. ◽  
Fitri Khoerunnisa ◽  
Severinne Rigolet ◽  
T. Jean Daou ◽  
Tau-Chuan Ling ◽  
...  
Keyword(s):  
Molecular Diffusion ◽  
Catalytic Performance ◽  
Morphological Properties ◽  
Molar Ratio ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Significant Deterioration ◽  
Consecutive Reaction ◽  
Surface Basicity

Cs–pollucite can be a potential solid base catalyst due to the presence of (Si-O-Al)−Cs+ basic sites. However, it severely suffers from molecular diffusion and pore accessibility problems due to its small micropore opening. Herein, we report the use of new organosilane, viz. dimethyloctadecyl[3-(trimethoxysilyl)propyl]ammonium chloride (TPOAC), as a promising pore-expanding agent to develop the hierarchical structure in nanosized Cs–pollucite. In respect to this, four different amounts of TPOAC were added during the synthesis of hierarchical Cs–pollucite (CP-x, x = 0, 0.3, 1.0, or 2.0, where x is the molar ratio of TPOAC) in order to investigate the effects of TPOAC in the crystallization process of Cs–pollucite. The results show that an addition of TPOAC altered the physico-chemical and morphological properties of hierarchical Cs–pollucite, such as the crystallinity, crystallite size, pore size distribution, surface areas, pore volume, and surface basicity. The prepared solids were also tested in Claisen–Schmidt condensation of benzaldehyde and acetophenone, where 82.2% of the conversion and 100% selectivity to chalcone were achieved by the CP-2.0 catalyst using non-microwave instant heating (200 °C, 100 min). The hierarchical CP-2.0 nanocatalyst also showed better catalytic performance than other homogenous and heterogeneous catalysts and displayed a high catalyst reusability with no significant deterioration in the catalytic performance even after five consecutive reaction runs.

scholarly journals Development of Biodiesel Production Technology from Waste Cooking Oil with Calcium Oxide as Solid Base Catalyst

2007 ◽  
Vol 50 (2) ◽  
pp. 79-86 ◽  
Author(s):  
Masato Kouzu ◽  
Shinya Yamanaka ◽  
Takekazu Kasuno ◽  
Masahiko Tajika ◽  
Yoichi Aihara ◽  
...  
Keyword(s):  
Calcium Oxide ◽  
Production Technology ◽  
Waste Cooking Oil ◽  
Biodiesel Production ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Cooking Oil

A novel waste water scale-derived solid base catalyst for biodiesel production

Fuel ◽  
2014 ◽  
Vol 124 ◽  
pp. 66-72 ◽  
Author(s):  
Pingbo Zhang ◽  
Qiuju Han ◽  
Mingming Fan ◽  
Pingping Jiang
Keyword(s):  
Waste Water ◽  
Biodiesel Production ◽  
Solid Base ◽  
Base Catalyst ◽  
Solid Base Catalyst
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