Hydrogen adsorption on activated carbon nanotubes with an atomic-sized vanadium catalyst investigated by electrical resistance measurements

2012 ◽  
Vol 258 (7) ◽  
pp. 2749-2756 ◽  
Author(s):  
Ji Sun Im ◽  
Jumi Yun ◽  
Seok Chang Kang ◽  
Sung Kyu Lee ◽  
Young-Seak Lee
2001 ◽  
Vol 706 ◽  
Author(s):  
Xiaohong Chen ◽  
Urszula Dettlaff-Weglikowska ◽  
Miroslav Haluska ◽  
Martin Hulman ◽  
Siegmar Roth ◽  
...  

AbstractThe hydrogen adsorption capacity of various carbon nanostructures including single-wall carbon nanotubes, graphitic nanofibers, activated carbon, and graphite has been measured as a function of pressure and temperature. Our results show that at room temperature and a pressure of 80 bar the hydrogen storage capacity is less than 1 wt.% for all samples. Upon cooling, the capacity of hydrogen adsorption increases with decreasing temperature and the highest value was observed to be 2.9 wt. % at 50 bar and 77 K. The correlation between hydrogen storage capacity and specific surface area is discussed.


2005 ◽  
Vol 20 (12) ◽  
pp. 3214-3223 ◽  
Author(s):  
M.K. Haas ◽  
J.M. Zielinski ◽  
G. Dantsin ◽  
C.G. Coe ◽  
G.P. Pez ◽  
...  

Hydrogen isotherms on a variety of single-walled carbon nanotube (SWNT) samples were measured using a differential pressure adsorption apparatus, which provides highly accurate data. A number of these SWNT samples were modified by a non-destructive cutting process, which reduced the aspect ratio of the nanotube bundles by two orders of magnitude. There were no apparent differences in the microporosity of SWNT as a function of aspect ratio. The adsorption of helium on SWNT is shown to be non-negligible and results in artificially low hydrogen capacities using conventional adsorption methodology. With no accounting for helium adsorption, the hydrogen adsorption results show that cut and uncut SWNT have similar hydrogen capacities of <1 wt% at 25 °C and pressures up to 110 bar. However, an analysis of hydrogen capacity versus N2 Brunauer–Emmett–Teller surface area suggests that there is an enhanced heat of adsorption of hydrogen for SWNT versus activated carbon.


2010 ◽  
Author(s):  
S. M. Sanip ◽  
M. A. R. Saidin ◽  
M. Aziz ◽  
A. F. Ismail ◽  
Mohamad Rusop ◽  
...  

2020 ◽  
Vol 11 (6) ◽  
pp. 1383-1389
Author(s):  
A. V. Shchegolkov ◽  
V. S. Yagubov ◽  
A. V. Shchegolkov ◽  
N. R. Memetov

2018 ◽  
Vol 80 (6) ◽  
pp. 739-750 ◽  
Author(s):  
A. V. Shkolin ◽  
A. A. Fomkin ◽  
V. Yu. Yakovlev ◽  
I. E. Men’shchikov

Adsorption ◽  
2007 ◽  
Vol 13 (1) ◽  
pp. 53-59 ◽  
Author(s):  
V. Gayathri ◽  
R. Geetha

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