Synchrotron radiation photoelectron spectroscopy and near-edge X-ray absorption fine structure study on oxidative etching of diamond-like carbon films by hyperthermal atomic oxygen

2010 ◽  
Vol 256 (24) ◽  
pp. 7678-7683 ◽  
Author(s):  
Masahito Tagawa ◽  
Kumiko Yokota ◽  
Akira Kitamura ◽  
Koji Matsumoto ◽  
Akitaka Yoshigoe ◽  
...  
Coatings ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 330 ◽  
Author(s):  
Kazuhiro Kanda ◽  
Shuto Suzuki ◽  
Masahito Niibe ◽  
Takayuki Hasegawa ◽  
Tsuneo Suzuki ◽  
...  

In this paper, the local structure of silicon-containing diamond-like carbon (Si-DLC) films is discussed based on the measurement of C K-edge and Si K-edge near-edge x-ray absorption fine structure (NEXAFS) spectra using the synchrotron radiation of 11 types of Si-DLC film fabricated with various synthesis methods and having different elemental compositions. In the C K-edge NEXAFS spectra of the Si-DLC films, the σ* band shrunk and shifted to the lower-energy side, and the π* peak broadened with an increase in the Si content in the Si-DLC films. However, there were no significant changes observed in the Si K-edge NEXAFS spectra with an increase in the Si content. These results indicate that Si–Si bonding is not formed with precedence in Si-DLC film.


2003 ◽  
Vol 42 (Part 1, No. 6B) ◽  
pp. 3971-3975 ◽  
Author(s):  
Teruyuki Kitagawa ◽  
Kazuya Miyauchi ◽  
Kazuhiro Kanda ◽  
Yutaka Shimizugawa ◽  
Noriaki Toyoda ◽  
...  

1989 ◽  
Vol 60 (7) ◽  
pp. 2533-2536 ◽  
Author(s):  
N. Matsubayashi ◽  
I. Kojima ◽  
M. Kurahashi ◽  
A. Nishijima ◽  
A. Itoh ◽  
...  

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Hiroyuki Ikemoto ◽  
Takafumi Miyanaga

AbstractIn this review, we make a survey of the structure studies for the chalcogen elements and several chalcogenides in liquid, amorphous and nanosized state by using X-ray absorption fine structure (XAFS). The chalcogen elements have hierarchic structures; the chain structure constructed with the strong covalent bond as a primary structure, and the weaker interaction between chains as a secondary one. Existence of these two kinds of interactions induces exotic behaviors in the liquid, amorphous and nanosized state of the chalcogen and chalcogenides. XAFS is a powerful structure analysis technique for multi-element systems and the disordered materials, so it is suitable for the study of such as liquid, amorphous and nanosized mixtures. In section 2, the structures for the liquid state are discussed, which show the interesting semiconductor-metal transition depending on their temperatures and components. In section 3, the structure for the amorphous states are discussed. Especially, some of chalcogens and chalcogenides present the photostructural change, which is important industrial application. In section 4, the structures of nanosized state, nanoparticles and isolated chain confined into the narrow channel, are discussed. The studies of the nanoparticle and the isolated chain reveal the alternative role between the intrachain covalent bonds and the interchain interaction.


1984 ◽  
Vol 30 (2) ◽  
pp. 672-677 ◽  
Author(s):  
P. A. Montano ◽  
W. Schulze ◽  
B. Tesche ◽  
G. K. Shenoy ◽  
T. I. Morrison

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