Multi-walled carbon nanotube supported Pd and Pt nanoparticles with high solution affinity for effective electrocatalysis

2010 ◽  
Vol 256 (22) ◽  
pp. 6723-6728 ◽  
Author(s):  
Weichun Ye ◽  
Haiyuan Hu ◽  
Hong Zhang ◽  
Feng Zhou ◽  
Weimin Liu
Keyword(s):  
Carbon Nanotube ◽  
Pt Nanoparticles ◽  
Multi Walled Carbon Nanotube ◽  
Supported Pd

Multi-walled carbon nanotube supported Pd nanocubes with enhanced electrocatalytic activity

2016 ◽  
Vol 4 (12) ◽  
pp. 4485-4489 ◽  
Author(s):  
Wei Hong ◽  
Peiyan Bi ◽  
Changshuai Shang ◽  
Jin Wang ◽  
Erkang Wang
Keyword(s):  
Carbon Nanotube ◽  
Electrocatalytic Activity ◽  
Multi Walled Carbon Nanotube ◽  
Supported Pd

Multi-walled carbon nanotube supported Pd nanocubes with enhanced electrocatalytic activity are synthesized using KBr as the shape modulating reagent.

Uniformly deposited Pt nanoparticles onto crosslinked ionic liquids wrapped carbon nanotubes for methanol electrooxidation

RSC Advances ◽  
2016 ◽  
Vol 6 (86) ◽  
pp. 82726-82732 ◽  
Author(s):  
Li Luo ◽  
Zheng Zhou ◽  
Ye Ren ◽  
Guang-Xin Chen ◽  
Qifang Li
Keyword(s):  
Carbon Nanotubes ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Carbon Nanotube ◽  
Free Radical ◽  
Outer Surface ◽  
Pt Nanoparticles ◽  
Multi Walled Carbon Nanotube ◽  
Vinyl Benzyl

A type of skin-core structured hybrid with a multi-walled carbon nanotube (MWCNT) center was synthesized by in situ free-radical polymerization of vinyl-benzyl ionic liquid and divinylbenzene on the outer surface of MWCNTs.

scholarly journals Polypyrrole-multi walled carbon nanotube hybrid material supported Pt NPs for hydrogen evolution from the hydrolysis of MeAB at mild conditions

2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Yasar Karatas ◽  
Esra Kuyuldar ◽  
Hilal Acidereli ◽  
Mehmet Gulcan ◽  
Fatih Sen
Keyword(s):  
Activation Energy ◽  
Carbon Nanotube ◽  
Hybrid Material ◽  
Reaction Rate ◽  
Pt Nanoparticles ◽  
Catalytic Hydrolysis ◽  
Mild Conditions ◽  
Multi Walled Carbon Nanotube ◽  
Hydrolysis Of ◽  
Very High

AbstractHerein, we report a facile method for the preparation of polypyrrole-multi walled carbon nanotube hybrid material including Pt nanoparticles (Pt@PPy-MWCNT NPs) and the use in methylamine borane (MeAB) for hydrolysis reaction at mild conditions. The prepared catalyst of Pt@PPy-MWCNT NPs was characterized by some advanced analytical methods. The catalytic experiments showed the Pt@PPy-MWCNT NPs can catalyze MeAB in aquatic solution with high catalytical performance at mild conditions. The reaction rate of catalytic hydrolysis with Pt@PPy-MWCNT NPs was found to be -d[CH3NH2BH3]/dt = + d[H2]/3dt = kobs[Pt@PPy-MWCNT]1.19 [MeAB]0.88. The TOF value for the hydrolysis of MeAB catalyzed with Pt@PPy-MWCNT NPs was detected to be 10234.2 1/h (170.57 1/min) which is very high compared with TOF values found for other catalysts. Enthalpy, entropy and activation energy for the hydrolysis of MeAB were calculated to be 31.57 kJ mol−1, −119.97 J mol−1 K and 34.27 kJ mol−1, respectively.

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