End group effect on surface and interfacial segregation in PS-PMMA blend thin films

2006 ◽  
Vol 252 (19) ◽  
pp. 6648-6651 ◽  
Author(s):  
L. Kailas ◽  
P. Bertrand

In Part II of this series of papers (1) it was shown that (with suitable substances) films 1 molecule thick could be obtained on the surface of water, in which the molecules were packed with much the same degree of closeness as in other condensed forms of matter such as solids or liquids. Moreover, under proper conditions, it was shown that the molecules packed themselves, so as to give, for the measurement of the cross-section, some-times that of the hydrocarbon chain, sometimes that of the polar end group, called the "head." Concordant measures were obtained on different substances for the area of cross-section of a saturated normal chain of CH 2 groups, and for some common end groupings such as COOH, COOC 2 H 5 , etc. No check was, however, possible at that time on the measures of the dimensions of the groupings made by this method, as no other method had been applied to the measurement of these groups in condensed forms of matter. Sir W. H. Bragg's measurements of the dimensions of the naphthalene and anthracene molecule within the crystal have made and attempt to measure monomolecular films of substances containing an aromatic nucleus near the head of the molecule very desirable. The present paper describes the results of such and attempt carried out on benzene derivatives.


2015 ◽  
Vol 44 (4) ◽  
pp. 462-464 ◽  
Author(s):  
Toshihiko Tanaka ◽  
Masamitsu Ishitobi ◽  
Tetsuya Aoyama ◽  
Shinya Matsumoto
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1981 ◽  
Vol 112 (6-7) ◽  
pp. 871-873 ◽  
Author(s):  
Whei Oh Lin ◽  
Antonio Paulo Alto�
Keyword(s):  

2016 ◽  
Vol 7 (44) ◽  
pp. 6735-6743 ◽  
Author(s):  
Tathagata Mondal ◽  
Suhrit Ghosh

This article elucidates a remarkable end group effect on the macroscopic assembly pathway of chain folded polyurethanes (PU) PU-2 and PU-3, both of which contain a linear PU chain appended with n-type semiconducting naphthalene-diimide (NDI) chromophores.


2000 ◽  
Vol 33 (22) ◽  
pp. 8334-8343 ◽  
Author(s):  
S. D. Kim ◽  
A. Klein ◽  
L. H. Sperling ◽  
E. M. Boczar ◽  
B. J. Bauer

2014 ◽  
Vol 102 ◽  
pp. 278-287 ◽  
Author(s):  
Yinwen Li ◽  
Huilong Guo ◽  
Yunfei. Zhang ◽  
Jian Zheng ◽  
Zhaoxia Li ◽  
...  
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