scholarly journals Ultraselective low temperature steam reforming of methanol over PdZn/ZnO catalysts—Influence of induced support defects on catalytic performance

2014 ◽  
Vol 154-155 ◽  
pp. 316-328 ◽  
Author(s):  
Katarzyna Morawa Eblagon ◽  
Patricia Heydorn Concepción ◽  
Hugo Silva ◽  
Adélio Mendes
Materials ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 5601
Author(s):  
Magdalena Mosińska ◽  
Małgorzata I. Szynkowska-Jóźwik ◽  
Paweł Mierczyński

The production of pure hydrogen is one of the most important problems of the modern chemical industry. While high volume production of hydrogen is well under control, finding a cheap method of hydrogen production for small, mobile, or his receivers, such as fuel cells or hybrid cars, is still a problem. Potentially, a promising method for the generation of hydrogen can be oxy–steam-reforming of methanol process. It is a process that takes place at relatively low temperature and atmospheric pressure, which makes it possible to generate hydrogen directly where it is needed. It is a process that takes place at relatively low temperature and atmospheric pressure, which makes it possible to generate hydrogen directly where it is needed. This paper summarizes the current state of knowledge on the catalysts used for the production of hydrogen in the process of the oxy–steam-reforming of methanol (OSRM). The development of innovative energy generation technologies has intensified research related to the design of new catalysts that can be used in methanol-reforming reactions. This review shows the different pathways of the methanol-reforming reaction. The paper presents a comparison of commonly used copper-based catalysts with other catalytic systems for the production of H2 via OSRM reaction. The surface mechanism of the oxy–steam-reforming of methanol and the kinetic model of the OSRM process are discussed.


2011 ◽  
Vol 47 (5) ◽  
pp. 1473-1475 ◽  
Author(s):  
Chien-Cheng Li ◽  
Ran-Jin Lin ◽  
Hong-Ping Lin ◽  
Yu-Kai Lin ◽  
Yan-Gu Lin ◽  
...  

2015 ◽  
Vol 58 (4-6) ◽  
pp. 281-294 ◽  
Author(s):  
Tamara Siqueira Moraes ◽  
Raimundo Crisostomo Rabelo Neto ◽  
Mauro Celso Ribeiro ◽  
Lisiane Veiga Mattos ◽  
Marios Kourtelesis ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (36) ◽  
pp. 30176-30183 ◽  
Author(s):  
Jiajia Zhou ◽  
Ye Zhang ◽  
Guisheng Wu ◽  
Dongsen Mao ◽  
Guanzhong Lu

A series of binary Cu/ZrO2 catalysts by choosing different composition ratios and different precipitation sequences have been prepared for the production of hydrogen by steam reforming of methanol (SRM).


RSC Advances ◽  
2015 ◽  
Vol 5 (120) ◽  
pp. 99461-99482 ◽  
Author(s):  
Lin Huang ◽  
Catherine Choong ◽  
Luwei Chen ◽  
Zhan Wang ◽  
Ziyi Zhong ◽  
...  

Rh4(CO)12-derived Rh/CeO2 is superior to the other oxide-supported Rh catalysts. Coking is the only cause of catalyst deactivation which affects the catalytic stability of Rh/CeO2. Both CeO2-supported Rh0 and Rh+ may participate in catalysis for ESR.


2005 ◽  
Vol 102 (3-4) ◽  
pp. 183-190 ◽  
Author(s):  
Xin-Rong Zhang ◽  
Lu-Cum Wang ◽  
Cheng-Zhang Yao ◽  
Yong Cao ◽  
Wei-Lin Dai ◽  
...  

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