Synthesis of Pt–Co nanoparticles on multi-walled carbon nanotubes for methanol oxidation in H2SO4 solution

2011 ◽  
Vol 407 (1-2) ◽  
pp. 195-203 ◽  
Author(s):  
R.S. Amin ◽  
K.M. El-Khatib ◽  
R.M. Abdel Hameed ◽  
Eglal R. Souaya ◽  
Mohamed A. Etman
2013 ◽  
Vol 1 (6) ◽  
pp. 2050-2063 ◽  
Author(s):  
Deborah Vidick ◽  
Marcus Herlitschke ◽  
Claude Poleunis ◽  
Arnaud Delcorte ◽  
Raphael P. Hermann ◽  
...  

2018 ◽  
Vol 36 (4) ◽  
pp. 739-747 ◽  
Author(s):  
N.V. Lemesh ◽  
P.E. Strizhak

AbstractIn this work, multi-walled carbon nanotubes (MWCNTs) with significantly different mean diameters were produced by catalytic CVD over Ni and Co-based supported catalysts. Our results indicate that Ni nanoparticles in the Ni/MgO catalyst are responsible for controlling the inner diameters of the carbon nanotubes. Contrary, Co nanoparticles in the Co/MgO catalyst control the outer diameters of MWCNTs. The “base-growth” mechanism and smaller diameters of the MWCNTs grown on the Ni/MgO catalyst are associated with a strong metal-support interaction (SMSI) resulting from NixMg1−xO mixed oxide formation. The concept of the weak metal-support interaction (WMSI) between Co nanoparticles and MgO for the Co/MgO catalyst confirms the “tip-growth” mechanism of the MWCNTs.


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