Catalytic performance of bismuth molybdate catalysts in the oxidative dehydrogenation of C4 raffinate-3 to 1,3-butadiene

2007 ◽  
Vol 317 (2) ◽  
pp. 244-249 ◽  
Author(s):  
Ji Chul Jung ◽  
Heesoo Kim ◽  
Yong Seung Kim ◽  
Young-Min Chung ◽  
Tae Jin Kim ◽  
...  
RSC Advances ◽  
2015 ◽  
Vol 5 (111) ◽  
pp. 91295-91301 ◽  
Author(s):  
Xin Chen ◽  
Qianli Yang ◽  
Bozhao Chu ◽  
Hang An ◽  
Yi Cheng

This work presents a new method of catalyst surface modification by using oxygen plasma to change the oxidation state of active sites in metal oxide catalysts.


2008 ◽  
Vol 9 (10) ◽  
pp. 2059-2062 ◽  
Author(s):  
Ji Chul Jung ◽  
Howon Lee ◽  
Heesoo Kim ◽  
Sunyoung Park ◽  
Young-Min Chung ◽  
...  

2017 ◽  
Vol 534 ◽  
pp. 58-69 ◽  
Author(s):  
E.V. Ishchenko ◽  
R.V. Gulyaev ◽  
T.Yu. Kardash ◽  
A.V. Ishchenko ◽  
E.Yu. Gerasimov ◽  
...  

Author(s):  
Aline Villarreal ◽  
Gabriella Garbarino ◽  
Paola Riani ◽  
Aida Gutiérrez Alejandre ◽  
Jorge Ramírez ◽  
...  

The influence of incorporating a small amount of silica on the catalytic performance of MoO3/Al2O3 catalyst was studied. Molybdenum supported on pure alumina and 5% SiO2-Al2O3 supports were synthesized. The catalysts were characterized by XRD, Raman, UV-Vis and IR spectroscopies, FE-SEM microscopy, and their activity was evaluated in the oxidative dehydrogenation of ethanol to acetaldehyde. Molybdenum supported on pure alumina gives a 74% yield to acetaldehyde (at 573 K) due to the generation of oxy-dehydrogenation active sites by molybdenum and to the decrement of the alumina dehydration sites. For the molybdenum catalyst supported on silica-containing alumina, the molybdenum species were displaced from the strongest alumina’s acid-base couples, located on nanoparticles edges, corners and defects, to weaker ones located on plane faces causing the rise of weakly bonded species with less active redox behavior.  


2012 ◽  
Vol 445-446 ◽  
pp. 321-328 ◽  
Author(s):  
Piotr Michorczyk ◽  
Piotr Kuśtrowski ◽  
Paula Niebrzydowska ◽  
Anna Wach

2008 ◽  
Vol 25 (6) ◽  
pp. 1316-1321 ◽  
Author(s):  
Ji Chul Jung ◽  
Howon Lee ◽  
Sunyoung Park ◽  
Young-Min Chung ◽  
Tae Jin Kim ◽  
...  

2010 ◽  
Vol 75 (8) ◽  
pp. 1115-1124 ◽  
Author(s):  
Gheorghiţa Mitran ◽  
Ioan-Cezar Marcu ◽  
Adriana Urdă ◽  
Ioan Săndulescu

Vanadium-molybdenum oxides supported on Al2O3, CeO2 and TiO2 were prepared by a ?wet? impregnation method, characterized using DRX, N2 adsorption, UV-Vis spectroscopy, electrical conductivity measurements and tested in the oxidative dehydrogenation of isobutane. The catalytic performance in the oxidative dehydrogenation of isobutane at 400-550?C depended on the nature of support and on the content of VMoO species on the support. The catalysts supported on alumina were more active and selective than those supported on ceria and titania.


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