Catalytically active species in Ni-based catalytic systems for low-temperature methanol synthesis probed by in situ ATR/FTIR in combination with reaction kinetics

2006 ◽  
Vol 313 (1) ◽  
pp. 58-62 ◽  
Author(s):  
S OHYAMA
Keyword(s):  
Low Temperature ◽  
Reaction Kinetics ◽  
Methanol Synthesis ◽  
Active Species ◽  
Catalytic Systems ◽  
Catalytically Active

Single molecule study of samarium oxide nanoparticles as a purely heterogeneous catalyst for one-pot aldehyde chemistry

2016 ◽  
Vol 6 (19) ◽  
pp. 7113-7121 ◽  
Author(s):  
Gregory K. Hodgson ◽  
Stefania Impellizzeri ◽  
Juan C. Scaiano
Keyword(s):  
Heterogeneous Catalysis ◽  
Homogeneous Catalysis ◽  
Single Molecule ◽  
Metal Ion ◽  
Active Species ◽  
Oxide Nanoparticles ◽  
Samarium Oxide ◽  
One Pot ◽  
Catalytically Active

Heterogeneous catalysis holds distinct advantages over homogeneous catalysis; however, it is only truly advantageous if unaffected by metal ion leaching or in situ formation of a soluble catalytically active species.

In-Situ DRIFT Study of a New Low-Temperature Methanol Synthesis Mechanism

2005 ◽  
Vol 78 (1) ◽  
pp. 135-137 ◽  
Author(s):  
Ruiqin Yang ◽  
Yilu Fu ◽  
Yi Zhang ◽  
Bolian Xu ◽  
Noritatsu Tsubaki
Keyword(s):  
Low Temperature ◽  
Methanol Synthesis ◽  
Synthesis Mechanism ◽  
In Situ Drift

scholarly journals Pentacarbonylmethylmanganese(I) as a Synthon for Mn(I) Pincer Catalysts

2019 ◽  
Author(s):  
Karthika J. Kadassery ◽  
David Lacy
Keyword(s):  
Active Species ◽  
Substrate Activation ◽  
Catalytically Active ◽  
Metal Ligand

<p>Mn(I) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO)5 as a synthon in place of typical Mn(CO)5Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O–H, N–H, and even C–H bonds.<br></p>

scholarly journals Pentacarbonylmethylmanganese(I) as a Synthon for Mn(I) Pincer Catalysts

2019 ◽  
Author(s):  
Karthika J. Kadassery ◽  
David Lacy
Keyword(s):  
Active Species ◽  
Substrate Activation ◽  
Catalytically Active ◽  
Metal Ligand

<p>Mn(I) complexes that enable metal-ligand cooperative substrate activation catalyze a range of transformations. Use of MeMn(CO)5 as a synthon in place of typical Mn(CO)5Br was explored and found to be quite versatile, generating catalytically active species in situ by activation of O–H, N–H, and even C–H bonds.<br></p>

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