Electric field-responsive nanoparticles and electric fields: physical, chemical, biological mechanisms and therapeutic prospects

Tuning the Electric Field Response of MOFs by Rotatable Dipolar Linkers

10.26434/chemrxiv.8153198.v1 ◽

2019 ◽

Author(s):

Johannes P. Dürholt ◽

Babak Farhadi Jahromi ◽

Rochus Schmid

Keyword(s):

Electric Field ◽

Electric Fields ◽

Structural Changes ◽

Dielectric Behavior ◽

Two Dimensions ◽

Dielectric Constants ◽

Electric Response ◽

Dipole Strength ◽

Metal Organic ◽

Dynamics Simulations

Recently the possibility of using electric fields as a further stimulus to trigger structural changes in metal-organic frameworks (MOFs) has been investigated. In general, rotatable groups or other types of mechanical motion can be driven by electric fields. In this study we demonstrate how the electric response of MOFs can be tuned by adding rotatable dipolar linkers, generating a material that exhibits paralectric behavior in two dimensions and dielectric behavior in one dimension. The suitability of four different methods to compute the relative permittivity κ by means of molecular dynamics simulations was validated. The dependency of the permittivity on temperature T and dipole strength μ was determined. It was found that the herein investigated systems exhibit a high degree of tunability and substantially larger dielectric constants as expected for MOFs in general. The temperature dependency of κ obeys the Curie-Weiss law. In addition, the influence of dipolar linkers on the electric field induced breathing behavior was investigated. With increasing dipole moment, lower field strength are required to trigger the contraction. These investigations set the stage for an application of such systems as dielectric sensors, order-disorder ferroelectrics or any scenario where movable dipolar fragments respond to external electric fields.

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Meta-Deflectors Made of Dielectric Nanohole Arrays with Anti-Damage Potential

Photonics ◽

10.3390/photonics8040107 ◽

2021 ◽

Vol 8 (4) ◽

pp. 107

Author(s):

Haichao Yu ◽

Feng Tang ◽

Jingjun Wu ◽

Zao Yi ◽

Xin Ye ◽

...

Keyword(s):

Electric Field ◽

Electric Fields ◽

Laser Cutting ◽

High Complexity ◽

Damage Potential ◽

Optical Components ◽

Nanohole Arrays ◽

Intense Light ◽

Polarization Of Light ◽

Air Hole

In intense-light systems, the traditional discrete optical components lead to high complexity and high cost. Metasurfaces, which have received increasing attention due to the ability to locally manipulate the amplitude, phase, and polarization of light, are promising for addressing this issue. In the study, a metasurface-based reflective deflector is investigated which is composed of silicon nanohole arrays that confine the strongest electric field in the air zone. Subsequently, the in-air electric field does not interact with the silicon material directly, attenuating the optothermal effect that causes laser damage. The highest reflectance of nanoholes can be above 99% while the strongest electric fields are tuned into the air zone. One presentative deflector is designed based on these nanoholes with in-air-hole field confinement and anti-damage potential. The 1st order of the meta-deflector has the highest reflectance of 55.74%, and the reflectance sum of all the orders of the meta-deflector is 92.38%. The optothermal simulations show that the meta-deflector can theoretically handle a maximum laser density of 0.24 W/µm2. The study provides an approach to improving the anti-damage property of the reflective phase-control metasurfaces for intense-light systems, which can be exploited in many applications, such as laser scalpels, laser cutting devices, etc.

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Integrating flexible electronics for pulsed electric field delivery in a vascularized 3D glioblastoma model

npj Flexible Electronics ◽

10.1038/s41528-021-00115-x ◽

2021 ◽

Vol 5 (1) ◽

Author(s):

Marie C. Lefevre ◽

Gerwin Dijk ◽

Attila Kaszas ◽

Martin Baca ◽

David Moreau ◽

...

Keyword(s):

Electric Field ◽

Electric Fields ◽

Flexible Electronics ◽

Soft Tissues ◽

Multiphoton Microscopy ◽

Membrane Integrity ◽

Tumor Model ◽

Pulsed Electric Fields ◽

In Ovo ◽

Cell Membrane Integrity

AbstractGlioblastoma is a highly aggressive brain tumor, very invasive and thus difficult to eradicate with standard oncology therapies. Bioelectric treatments based on pulsed electric fields have proven to be a successful method to treat cancerous tissues. However, they rely on stiff electrodes, which cause acute and chronic injuries, especially in soft tissues like the brain. Here we demonstrate the feasibility of delivering pulsed electric fields with flexible electronics using an in ovo vascularized tumor model. We show with fluorescence widefield and multiphoton microscopy that pulsed electric fields induce vasoconstriction of blood vessels and evoke calcium signals in vascularized glioblastoma spheroids stably expressing a genetically encoded fluorescence reporter. Simulations of the electric field delivery are compared with the measured influence of electric field effects on cell membrane integrity in exposed tumor cells. Our results confirm the feasibility of flexible electronics as a means of delivering intense pulsed electric fields to tumors in an intravital 3D vascularized model of human glioblastoma.

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Electro-Optic Control of Lithium Niobate Bulk Whispering Gallery Resonators: Analysis of the Distribution of Externally Applied Electric Fields

Crystals ◽

10.3390/cryst11030298 ◽

2021 ◽

Vol 11 (3) ◽

pp. 298

Author(s):

Yannick Minet ◽

Hans Zappe ◽

Ingo Breunig ◽

Karsten Buse

Keyword(s):

Lithium Niobate ◽

Electric Field ◽

Electric Fields ◽

Frequency Comb ◽

Parametric Oscillation ◽

Pockels Effect ◽

Optical Mode ◽

Cylindrical Resonator ◽

Whispering Gallery ◽

Electro Optic

Whispering gallery resonators made out of lithium niobate allow for optical parametric oscillation and frequency comb generation employing the outstanding second-order nonlinear-optical properties of this material. An important knob to tune and control these processes is, e.g., the linear electro-optic effect, the Pockels effect via externally applied electric fields. Due to the shape of the resonators a precise prediction of the electric field strength that affects the optical mode is non-trivial. Here, we study the average strength of the electric field in z-direction in the region of the optical mode for different configurations and geometries of lithium niobate whispering gallery resonators with the help of the finite element method. We find that in some configurations almost 100% is present in the cavity compared to the ideal case of a cylindrical resonator. Even in the case of a few-mode resonator with a very thin rim we find a strength of 90%. Our results give useful design considerations for future arrangements that may benefit from the strong electro-optic effect in bulk whispering gallery resonators made out of lithium niobate.

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Double layers in the downward current region of the aurora

Nonlinear Processes in Geophysics ◽

10.5194/npg-10-45-2003 ◽

2003 ◽

Vol 10 (1/2) ◽

pp. 45-52 ◽

Cited By ~ 32

Author(s):

R. E. Ergun ◽

L. Andersson ◽

C. W. Carlson ◽

D. L. Newman ◽

M. V. Goldman

Keyword(s):

Magnetic Field ◽

Electron Beam ◽

Phase Space ◽

Electric Field ◽

Electric Fields ◽

Double Layers ◽

Parallel Electric Field ◽

Electrostatic Waves ◽

Current Region ◽

Decisive Evidence

Abstract. Direct observations of magnetic-field-aligned (parallel) electric fields in the downward current region of the aurora provide decisive evidence of naturally occurring double layers. We report measurements of parallel electric fields, electron fluxes and ion fluxes related to double layers that are responsible for particle acceleration. The observations suggest that parallel electric fields organize into a structure of three distinct, narrowly-confined regions along the magnetic field (B). In the "ramp" region, the measured parallel electric field forms a nearly-monotonic potential ramp that is localized to ~ 10 Debye lengths along B. The ramp is moving parallel to B at the ion acoustic speed (vs) and in the same direction as the accelerated electrons. On the high-potential side of the ramp, in the "beam" region, an unstable electron beam is seen for roughly another 10 Debye lengths along B. The electron beam is rapidly stabilized by intense electrostatic waves and nonlinear structures interpreted as electron phase-space holes. The "wave" region is physically separated from the ramp by the beam region. Numerical simulations reproduce a similar ramp structure, beam region, electrostatic turbulence region and plasma characteristics as seen in the observations. These results suggest that large double layers can account for the parallel electric field in the downward current region and that intense electrostatic turbulence rapidly stabilizes the accelerated electron distributions. These results also demonstrate that parallel electric fields are directly associated with the generation of large-amplitude electron phase-space holes and plasma waves.

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Clarifications on the Behavior of Alternative Gases to SF6 in Divergent Electric Field Distributions under AC Voltage

Energies ◽

10.3390/en14041065 ◽

2021 ◽

Vol 14 (4) ◽

pp. 1065

Author(s):

Houssem Eddine Nechmi ◽

Michail Michelarakis ◽

Abderrahmane (Manu) Haddad ◽

Gordon Wilson

Keyword(s):

Electric Field ◽

Electric Fields ◽

Partial Discharge ◽

Mean Value ◽

Electrode System ◽

Polarity Reversal ◽

Buffer Gas ◽

Co2 Gas ◽

Breakdown Mechanism ◽

Positive Cycle

Negative and positive partial discharge inception voltages and breakdown measurements are reported in a needle-plane electrode system as a function of pressure under AC voltage for natural gases (N2, CO2, and O2/CO2), pure NovecTM gases (C4F7N and C5F10O) and NovecTM in different natural gas admixtures. For compressed 4% C4F7N–96% CO2 and 6% C5F10O–12% O2–82% CO2 gas mixtures, the positive-streamer mode is identified as the breakdown mechanism. Breakdown and negative partial discharge inception voltages of 6% C5F10O–12% O2–82% CO2 are higher than those of 4% C4F7N–96% CO2. At 8.8 bar abs, the breakdown voltage of 6% C5F10O–12% O2–82% CO2 is equal to that of 12.77% O2–87.23% CO2 (buffer gas). Synergism in negative partial discharge inception voltage/electric field fits with the mean value and the sum of each partial pressure individually component for a 20% C4F7N–80% CO2 and 6% C5F10O–12% O2–82% CO2, respectively. In 9% C4F7N–91% CO2, the comparison of partial discharge inception electric fields is Emax (CO2) = Emax(C4F7N), and Emax (12.77% O2–87.23% CO2) = Emax(C5F10O) in 19% C5F10O–81%(12.77% O2–87.23% CO2). Polarity reversal occurs under AC voltage when the breakdown polarity changes from negative to positive cycle. Polarity reversal electric field EPR was quantified. Fitting results show that EPR (CO2) = EPR(9% C4F7N–91% CO2) and EPR(SF6) = EPR (22% C4F7N–78% CO2). EPR (4% C4F7N–96% CO2) = EPR (12.77% O2–87.23% CO2) and EPR (6% C5F10O–12% O2–82% CO2) < EPR (4% C4F7N–96% CO2) < EPR (CO2).

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Tuning Single-Molecule Conductance by Controlled Electric Field-Induced trans-to-cis Isomerisation

Applied Sciences ◽

10.3390/app11083317 ◽

2021 ◽

Vol 11 (8) ◽

pp. 3317

Author(s):

C.S. Quintans ◽

Denis Andrienko ◽

Katrin F. Domke ◽

Daniel Aravena ◽

Sangho Koo ◽

...

Keyword(s):

Electric Field ◽

Electric Fields ◽

Single Molecule ◽

Quantum Interference ◽

Single Molecule Level ◽

Wet Chemical Synthesis ◽

Single Molecule Junctions ◽

Tunnelling Microscopy ◽

The Difference

External electric fields (EEFs) have proven to be very efficient in catalysing chemical reactions, even those inaccessible via wet-chemical synthesis. At the single-molecule level, oriented EEFs have been successfully used to promote in situ single-molecule reactions in the absence of chemical catalysts. Here, we elucidate the effect of an EEFs on the structure and conductance of a molecular junction. Employing scanning tunnelling microscopy break junction (STM-BJ) experiments, we form and electrically characterize single-molecule junctions of two tetramethyl carotene isomers. Two discrete conductance signatures show up more prominently at low and high applied voltages which are univocally ascribed to the trans and cis isomers of the carotenoid, respectively. The difference in conductance between both cis-/trans- isomers is in concordance with previous predictions considering π-quantum interference due to the presence of a single gauche defect in the trans isomer. Electronic structure calculations suggest that the electric field polarizes the molecule and mixes the excited states. The mixed states have a (spectroscopically) allowed transition and, therefore, can both promote the cis-isomerization of the molecule and participate in electron transport. Our work opens new routes for the in situ control of isomerisation reactions in single-molecule contacts.

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Elucidating the Influence of Electric Fields toward CO2 Activation on YSZ (111)

Catalysts ◽

10.3390/catal11020271 ◽

2021 ◽

Vol 11 (2) ◽

pp. 271

Author(s):

Nisa Ulumuddin ◽

Fanglin Che ◽

Jung-Il Yang ◽

Su Ha ◽

Jean-Sabin McEwen

Keyword(s):

Electric Field ◽

Electric Fields ◽

Heterogeneous Catalysts ◽

Co2 Reduction ◽

Total Density ◽

Reverse Water Gas Shift ◽

High Thermodynamic Stability ◽

Shift Reaction ◽

Water Gas

Despite its high thermodynamic stability, the presence of a negative electric field is known to facilitate the activation of CO2 through electrostatic effects. To utilize electric fields for a reverse water gas shift reaction, it is critical to elucidate the role of an electric field on a catalyst surface toward activating a CO2 molecule. We conduct a first-principles study to gain an atomic and electronic description of adsorbed CO2 on YSZ (111) surfaces when external electric fields of +1 V/Å, 0 V/Å, and −1 V/Å are applied. We find that the application of an external electric field generally destabilizes oxide bonds, where the direction of the field affects the location of the most favorable oxygen vacancy. The direction of the field also drastically impacts how CO2 adsorbs on the surface. CO2 is bound by physisorption when a +1 V/Å field is applied, a similar interaction as to how it is adsorbed in the absence of a field. This interaction changes to chemisorption when the surface is exposed to a −1 V/Å field value, resulting in the formation of a CO3− complex. The strong interaction is reflected through a direct charge transfer and an orbital splitting within the Olatticep-states. While CO2 remains physisorbed when a +1 V/Å field value is applied, our total density of states analysis indicates that a positive field pulls the charge away from the adsorbate, resulting in a shift of its bonding and antibonding peaks to higher energies, allowing a stronger interaction with YSZ (111). Ultimately, the effect of an electric field toward CO2 adsorption is not negligible, and there is potential in utilizing electric fields to favor the thermodynamics of CO2 reduction on heterogeneous catalysts.

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Restraining Surface Charge Accumulation and Enhancing Surface Flashover Voltage through Dielectric Coating

Coatings ◽

10.3390/coatings11070750 ◽

2021 ◽

Vol 11 (7) ◽

pp. 750

Author(s):

Jixing Sun ◽

Sibo Song ◽

Xiyu Li ◽

Yunlong Lv ◽

Jiayi Ren ◽

...

Keyword(s):

Charge Transfer ◽

Electric Field ◽

Electric Fields ◽

Transition Process ◽

Metallic Particle ◽

Particle Charging ◽

Insulating Surfaces ◽

Surface Flashover ◽

Charging Time ◽

The Impact

A conductive metallic particle in a gas-insulated metal-enclosed system can charge through conduction or induction and move between electrodes or on insulating surfaces, which may lead to breakdown and flashover. The charge on the metallic particle and the charging time vary depending on the spatial electric field intensity, the particle shape, and the electrode surface coating. The charged metallic particle can move between the electrodes under the influence of the spatial electric field, and it can discharge and become electrically conductive when colliding with the electrodes, thus changing its charge. This process and its factors are mainly affected by the coating condition of the colliding electrode. In addition, the interface characteristics affect the particle when it is near the insulator. The charge transition process also changes due to the electric field strength and the particle charging state. This paper explores the impact of the coating material on particle charging characteristics, movement, and discharge. Particle charging, movement, and charge transfer in DC, AC, and superimposed electric fields are summarized. Furthermore, the effects of conductive particles on discharge characteristics are compared between coated and bare electrodes. The reviewed studies demonstrate that the coating can effectively reduce particle charge and thus the probability of discharge. The presented research results can provide theoretical support and data for studying charge transfer theory and design optimization in a gas-insulated system.

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Investigation of the Carrier Movement through the Tunneling Junction in the InGaP/GaAs Dual Junction Solar Cell Using the Electrically and Optically Biased Photoreflectance Spectroscopy

Energies ◽

10.3390/en14030638 ◽

2021 ◽

Vol 14 (3) ◽

pp. 638

Author(s):

Sanam SaeidNahaei ◽

Hyun-Jun Jo ◽

Sang Jo Lee ◽

Jong Su Kim ◽

Sang Jun Lee ◽

...

Keyword(s):

Solar Cell ◽

Electric Field ◽

Electric Fields ◽

Bias Voltage ◽

Tunnel Junction ◽

Photogenerated Carrier ◽

Internal Electric Field ◽

Junction Solar Cell ◽

Photoreflectance Spectroscopy ◽

Dc Bias

For examining the carrier movements through tunnel junction, electrically and optically-biased photoreflectance spectroscopy (EBPR and OBPR) were used to investigate the internal electric field in the InGaP/GaAs dual junction solar cell at room temperature. At InGaP and GaAs, the strength of p-n junction electric fields (Fpn) was perturbed by the external DC bias voltage and CW light intensity for EBPR and OBPR experiments, respectively. Moreover, the Fpn was evaluated using the Fast Fourier Transform (FFT) of the Franz—Keldysh oscillation from PR spectra. In the EBPR, the electric field decreased by increasing the DC bias voltage, which also decreased the potential barrier. In OBPR, when incident CW light is absorbed by the top cell, the decrement of the Fpn in the GaAs cell indicates that the photogenerated carriers are accumulated near the p-n junction. Photogenerated carriers in InGaP can pass through the tunnel junction, and the PR results show the contribution of the modification of the electric field by the photogenerated carriers in each cell. We suggest that PR spectroscopy with optical-bias and electrical-bias could be analyzed using the information of the photogenerated carrier passed through the tunnel junction.

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