A novel polymeric ionic liquid-coated magnetic multiwalled carbon nanotubes for the solid-phase extraction of Cu, Zn-superoxide dismutase

2016 ◽  
Vol 939 ◽  
pp. 54-63 ◽  
Author(s):  
Qian Wen ◽  
Yuzhi Wang ◽  
Kaijia Xu ◽  
Na Li ◽  
Hongmei Zhang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Superoxide Dismutase ◽  
Ionic Liquid ◽  
Solid Phase Extraction ◽  
Multiwalled Carbon Nanotubes ◽  
Solid Phase ◽  
Phase Extraction ◽  
Multiwalled Carbon ◽  
Polymeric Ionic Liquid ◽  
Magnetic Multiwalled Carbon Nanotubes

Green Dispersive Micro Solid-Phase Extraction using Multiwalled Carbon Nanotubes for Preconcentration and Determination of Cadmium and Lead in Food, Water, and Tobacco Samples

2020 ◽  
Vol 16 (4) ◽  
pp. 381-392
Author(s):  
Ayman A. Gouda ◽  
Ali H. Amin ◽  
Ibrahim S. Ali ◽  
Zakia Al Malah
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase Extraction ◽  
Multiwalled Carbon Nanotubes ◽  
Solid Phase ◽  
Certified Reference Materials ◽  
Phase Extraction ◽  
Multiwalled Carbon ◽  
Flame Atomic Absorption ◽  
Relative Standard ◽  
Separation And Preconcentration

Background: Cadmium (Cd2+) and lead (Pb2+) have acute and chronic effects on humans and other living organisms. In the present work, new, green and accurate dispersive micro solid-phase extraction (DμSPE) method for the separation and preconcentration of trace amounts of cadmium (Cd2+) and lead (Pb2+) ions in various food, water and tobacco samples collected from Saudi Arabia prior to its Flame Atomic Absorption Spectrometric (FAAS) determinations was developed. Methods: The proposed method was based on a combination of oxidized multiwalled carbon nanotubes (O-MWCNTs) with a new chelating agent 5-benzyl-4-[4-methoxybenzylideneamino)-4H- 1,2,4-triazole-3-thiol (BMBATT) to enrich and separate trace levels of Cd2+ and Pb2+. The effect of separation parameters was investigated. The validation of the proposed preconcentration procedure was performed using certified reference materials. Results: Analyte recovery values ranged from 95-102%, indicating that the method is highly accurate. Furthermore, precision was demonstrated by the relative standard deviation (RSD < 3.0%). The limits of detection were 0.08 and 0.1 μg L−1 for Cd2+ and Pb2+ ions, respectively. The preconcentration factor was 200. Conclusion: The proposed method was used for the estimation of Cd2+ and Pb2+ ion content in various real samples, and satisfactory results were obtained. The proposed method has high adsorption capacity, rapid adsorption equilibrium, extremely low LODs, high preconcentration factors and shortens the time of sample preparation in comparison to classical SPE.

Preconcentration of atrazine and simazine with multiwalled carbon nanotubes as solid-phase extraction disk

2010 ◽  
Vol 96 (2) ◽  
pp. 348-351 ◽  
Author(s):  
Hideyuki Katsumata ◽  
Hiroshi Kojima ◽  
Satoshi Kaneco ◽  
Tohru Suzuki ◽  
Kiyohisa Ohta
Keyword(s):  
Carbon Nanotubes ◽  
Solid Phase Extraction ◽  
Multiwalled Carbon Nanotubes ◽  
Solid Phase ◽  
Phase Extraction ◽  
Multiwalled Carbon ◽  
As Solid Phase
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