Rapid uranium preconcentration and separation method from fresh water samples for total U and 235U/238U isotope ratio measurements by ICP-MS

2007 ◽  
Vol 592 (1) ◽  
pp. 101-105 ◽  
Author(s):  
K. Tagami ◽  
S. Uchida
Keyword(s):  
Fresh Water ◽  
Water Samples ◽  
Isotope Ratio ◽  
Separation Method ◽  
Icp Ms ◽  
Isotope Ratio Measurements

scholarly journals Gd Matrix Effects on Eu Isotope Fractionation in Geological Rocks Using MC-ICP-MS: Optimizing Europium Isotope Ratio Measurements in Geological Samples

2021 ◽  
Author(s):  
Seung-Gu Lee ◽  
Tsuyoshi Tanaka
Keyword(s):  
Isotope Ratio ◽  
Isotope Fractionation ◽  
Matrix Effects ◽  
Internal Standard ◽  
Geological Samples ◽  
Chemical Reagent ◽  
True Value ◽  
Icp Ms ◽  
Silicate Rocks ◽  
Isotope Ratio Measurements

<p></p><p>Eu has only two isotopes (151Eu and 153 Eu). Eu and Gd are one of the rare earth elements that are very difficult to completely separate from each other. Eu isotope ratio can be determined by MC-ICP-MS using internal Sm or Gd spikes to correct for mass discrimination. NIST3117a ultrapure chemical reagent shows almost no Eu isotope fractionation regardless of the kind of normalization isotope pair. However, Eu isotope ratio in the silicate rocks was effected by Gd matrix during MC-ICP-MS measurement if a trace amount of Gd impurity remains in the purified Eu fraction. In this report, we tried to determine optimizing conditions for precise and accurate Europium isotope ratio measurements in geological samples using MC-ICP-MS. The pure Eu fraction with almost no Gd matrix separated from geological samples and NIST3117a ultrapure chemical reagent show almost same degree of Eu isotope fractionation regardless of the kind of normalization isotope pair. However, Eu isotope ratio in the silicate rocks was effected by Gd matrix during MC-ICP-MS measurement using if 154 Gd interference relative to 154 Sm as internal standard is more than ca. 0.1%. Particularly, highly fractionated granite and high silica volcanic rock with extremely low Eu concentration compared to Gd require high – purity Eu separation with a high recovery rate to obtain the true value of the Eu isotope fractionation in the geological rocks. <br></p><br><p></p>

A fast, single column extraction chromatography method for the isolation of Neodymium from iron-rich materials prior to radiogenic isotope ratio measurements

2022 ◽  
Author(s):  
Abdelmouhcine GANNOUN ◽  
Krzysztof SUCHORSK ◽  
Christian Pin
Keyword(s):  
Extraction Chromatography ◽  
Isotope Ratio ◽  
Separation Method ◽  
Chromatography Method ◽  
Radiogenic Isotope ◽  
Synergistic Enhancement ◽  
Isotopic Analyses ◽  
Single Column ◽  
Column Extraction ◽  
Isotope Ratio Measurements

A novel separation method is described for the separation of Nd from Fe-rich, silicate samples in view of isotopic analyses. The procedure is based on the synergistic enhancement of the...

scholarly journals Copper Isotope Ratio Measurements of Cu-Dominated Minerals Without Column Chromatography Using MC-ICP-MS

2020 ◽  
Vol 8 ◽  
Author(s):  
Yan Zhang ◽  
Zhian Bao ◽  
Nan Lv ◽  
Kaiyun Chen ◽  
Chunlei Zong ◽  
...  
Keyword(s):  
Column Chromatography ◽  
Isotope Ratio ◽  
Copper Isotope ◽  
Icp Ms ◽  
Isotope Ratio Measurements

Strategies for isotope ratio measurements with a double focusing sector field ICP-MS

1999 ◽  
Vol 364 (5) ◽  
pp. 495-498 ◽  
Author(s):  
M. Hamester ◽  
D. Wiederin ◽  
J. Wills ◽  
W. Kerl ◽  
C. B. Douthitt
Keyword(s):  
Isotope Ratio ◽  
Icp Ms ◽  
Double Focusing ◽  
Isotope Ratio Measurements
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