Iron-Cobalt Coatings Produced Using an Eco-friendly Route

2021 ◽  
Author(s):  
E. A. Denisova ◽  
L. A. Chekanova ◽  
S. V. Komogortsev ◽  
I. V. Nemtsev ◽  
R. S. Iskhakov ◽  
...  
Keyword(s):  
Iron Cobalt

Schiff Base Metal Complexes Precursor for Metal Oxide Nanomaterial: A Review

2020 ◽  
Vol 16 ◽  
Author(s):  
Meghshyam K. Patil ◽  
Vijay H. Masand ◽  
Atish K. Maldhure
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Metal Oxides ◽  
Base Metal ◽  
Carbonyl Compounds ◽  
Organic Transformations ◽  
Iron Cobalt ◽  
Methods Of Synthesis ◽  
Schiff Base Metal Complexes ◽  
Nickel Manganese

: Schiff bases and their complexes are versatile compounds, which have been synthesized from the condensation of carbonyl compounds with amino compounds and exhibit a broad range of applications in biological, medicinal, catalysis, and industrial purposes. Furthermore, Schiff base-metal complexes have been used as a precursor for the synthesis of different metal oxides, which includes oxides of iron, cobalt, copper, nickel, manganese, vanadium, cadmium, zinc, mercury, etc. and ferrites such as Fe3O4, ZnFe2O4, and ZnCo2O4. These metal oxides have been utilized for several applications, which includes as a catalyst for several organic transformations and for biological activity. This review encompasses different methods of synthesis of metal oxides using Schiff base metal complexes precursor, their characterization, and various applications in detail.

Extraction of iron, cobalt, nickel and copper with dibenzyl sulfoxide solution in toluene

1979 ◽  
Vol 44 (7) ◽  
pp. 2024-2031 ◽  
Author(s):  
František Vláčil ◽  
Huynh Dang Khanh
Keyword(s):  
Nitric Acid ◽  
Hydrochloric Acid ◽  
Distribution Ratio ◽  
Separation Factor ◽  
Chromatographic Separation ◽  
The Other ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Factor Α

The dependence of the distribution ratio of the metal on the concentration of hydrochloric of nitric acid was examined for Fe, Co, Ni and Cu extraction with 0.05M solution of dibenzylsulfoxide in toluene. Iron is extracted considerably more than the other metals, and is better extracted from hydrochloric acid than from nitric acid. The separation factor αFe/M (for 8M-HCl) is of the order of 104; this is not sufficient for a separation of trace quantities of iron from Co, Ni and Cu, but even at lower concentrations of HCl (e.g., 5M) the values is high enough for extraction chromatographic separation. The composition of the iron solvate extracted from HCl or LiCl medium was determined to be HFeCl4.2 B (B = dibenzyl sulfoxide).

scholarly journals Resonanz-Raman-Effekt von Thiocyanatkomplexen einiger Übergangsmetalle

1970 ◽  
Vol 25 (10) ◽  
pp. 1394-1400 ◽  
Author(s):  
W. Krasser ◽  
H. W. Nürnberg
Keyword(s):  
Raman Spectrum ◽  
Infrared Spectra ◽  
High Intensity ◽  
High Frequency ◽  
Resonance Raman ◽  
Ammonium Salts ◽  
Iron Cobalt ◽  
Decay Products ◽  
Thiocyanate Complexes ◽  
Resonance Raman Spectra

Abstract The thiocyanates of the transition metals iron, cobalt, copper as well as of rhenium and of tech-netium appear in solution as strongly coloured complexes. The resonance raman bands in the sol-vent acetonitrile are investigated. To achieve an unambiguous identification the infrared spectra were recorded too. The change in position and structure of the acetonitrile bands indicates strong complexation of iron, cobalt and copper with acetonitrile, thus indicating the existence of mixed acetonitrile-thiocyanate complexes. The resonance raman spectra of the rhenium-and technetium-thiocyanates present as tetramethyl ammonium salts show however no raman-and infrared-bands of complexed acetonitrile molecules.In the raman spectrum of the thiocyanates of iron, cobalt and copper mainly the totally sym-metric C≡N, S-C, Me-S and Me-N valence vibrations are observed, among which the S-C vibration shows a remarkably high intensity. Besides, a series of bands is obtained which is inter-preted partly as caused by decay products, and partly as bands of complexed acetonitrile. The thiocyanates of rhenium and of technetium show the three possible valence vibrations only. The high frequency of the S-C valence indicates the N-coordination of the thiocyanate group.

Coupling hierarchical iron cobalt selenide arrays with N-doped carbon as advanced anodes for sodium ion storage

2021 ◽  
Author(s):  
Peijia Wang ◽  
Jiajie Huang ◽  
Jing Zhang ◽  
Liang Wang ◽  
Peiheng Sun ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Sodium Ion ◽  
Carbon Shell ◽  
Carbon Cloth ◽  
Sodium Ion Batteries ◽  
Half Cell ◽  
Iron Cobalt ◽  
Ion Storage ◽  
Cobalt Selenide ◽  
Sodium Ion Storage

Hierarchically core–branched iron cobalt selenide arrays coated with N-doped carbon shell were designed and synthesized on carbon cloth, showing prominent electrochemical performance both in half-cell and full cell sodium ion batteries.

3D hierarchical iron-cobalt sulfide anchored on carbon fiber with abundant active short chain sulfur for high-efficiency capture of elemental mercury

2021 ◽  
Vol 418 ◽  
pp. 129442
Author(s):  
Zhilou Liu ◽  
Zhiheng Zhang ◽  
Ziliang Li ◽  
Xiaofeng Xie ◽  
Shuiping Zhong ◽  
...  
Keyword(s):  
Carbon Fiber ◽  
High Efficiency ◽  
Elemental Mercury ◽  
Short Chain ◽  
Cobalt Sulfide ◽  
Iron Cobalt
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