scholarly journals Electric quadrupole interactions and the - phase transition in Ce: the role of conduction electrons

2000 ◽  
Vol 17 (1) ◽  
pp. 15-32 ◽  
Author(s):  
A.V. Nikolaev ◽  
K.H. Michel
1985 ◽  
Vol 63 (1) ◽  
pp. 3-23 ◽  
Author(s):  
A. Brooks Harris ◽  
Horst Meyer

A review is presented of our understanding of the orientational ordering in solid hydrogen, where ortho-H2 molecules are subject to anisotropic electric quadrupole–quadrupole interactions. This review pertains to solid H2 at low pressures and is concerned mostly with NMR experiments. After a discussion of the phase transition from the disordered hexagonal close-packed (hep) to the long-range ordered cubic phase, a description is given of experimental investigations of the ordering in the hep phase for ortho concentrations X < 0.53. This ordering appears to take place continuously as the temperature decreases. The question as to whether or not this phase is to be called a quadrupolar glass phase is addressed, and comparison is made with the orientational freezing in other compounds. A theoretical analysis is given to show that the ortho–para mixture is the analog of a spin glass in a random field for which no phase transition is expected.


2008 ◽  
Vol 77 (2) ◽  
Author(s):  
Trevor Stevens ◽  
Mikkel B. Johnson ◽  
Leonard S. Kisslinger ◽  
Ernest M. Henley ◽  
W.-Y Pauchy Hwang ◽  
...  

2015 ◽  
Vol 44 (36) ◽  
pp. 16036-16044 ◽  
Author(s):  
Emily Reynolds ◽  
Gordon J. Thorogood ◽  
Maxim Avdeev ◽  
Helen E. A. Brand ◽  
Qinfen Gu ◽  
...  

High temperature synchrotron X-ray and neutron diffraction powder diffraction studies of the uranium perovskites Ba2CaUO6and BaSrCaUO6reveal unusual phase transition behavior associated with the progressive loss of cooperative octahedral tilting.


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