High-spin structure of the neutron-rich 107,109 45Rh isotopes: the role of triaxiality

1999 ◽  
Vol 6 (4) ◽  
pp. 405-413 ◽  
Author(s):  
Ts. Venkova ◽  
M.-G. Porquet ◽  
I. Deloncle ◽  
B.J.P. Gall ◽  
H. De Witte ◽  
...  
Keyword(s):  
1989 ◽  
Vol 173 ◽  
Author(s):  
Takeji Takui ◽  
Makoto Endoh ◽  
Masayuki Okamoto ◽  
Kazunobu Satoh ◽  
Toyohiro Shichiri ◽  
...  

ABSTRACTA chemical modification exploiting functional groups such as ether and methylene as bridges between high-spin assemblies has been carried out as a usable method to increase dimensionality of spin structure. Exchange interaction via an ether or a methylene bridge between two high-spin assemblies has been studied by single-crystal ESR spectroscopy. Whether it is ferromagnetic or antiferromagnetic depends upon the substituted position of the bridge, demonstrating the important role of the topological nature in spin alignment. It turns out that superexchange interaction or hyperconjugation mechanism can dominate spin alignment between high-spin assemblies. Using the criteria obtained, model compounds for units of organic ferrimagnets have been synthesized. They possess antiferromagnetically-exchange coupled heterospins and the salient features of their spin structures are characterized in terms of the spin density distribution as determined by single-crystal 1H-ENDOR (Electron-Nuclear-DOuble Resonance) spectroscopy.


CrystEngComm ◽  
2021 ◽  
Vol 23 (15) ◽  
pp. 2854-2861
Author(s):  
Kristian Handoyo Sugiyarto ◽  
Djulia Onggo ◽  
Hiroki Akutsu ◽  
Varimalla Raghavendra Reddy ◽  
Hari Sutrisno ◽  
...  

Mononuclear complex [Fe(3-bpp)2](CF3COO)2 exhibits a thermal (HS + HS) ⇋ (HS + LS) transition at ∼226 K which is not associated with any crystallographic transition.


2002 ◽  
Vol 146 ◽  
pp. 595-596 ◽  
Author(s):  
Takayuki Matsuzawa ◽  
Hitoshi Nakada ◽  
Kengo Ogawa

2012 ◽  
Vol 86 (5) ◽  
Author(s):  
R. O. Hughes ◽  
G. J. Lane ◽  
G. D. Dracoulis ◽  
A. P. Byrne ◽  
P. H. Nieminen ◽  
...  

2009 ◽  
Vol 80 (3) ◽  
Author(s):  
M. Ionescu-Bujor ◽  
A. Iordachescu ◽  
S. M. Lenzi ◽  
D. R. Napoli ◽  
N. Mărginean ◽  
...  
Keyword(s):  

2020 ◽  
Vol 4 ◽  
pp. 170
Author(s):  
N. Fotiades ◽  
Et al.

The high-spin structure of 193Hg was investigated by in-beam γ-ray spectro­scopic techniques. The tandem accelerator at Daresbury Laboratory, U. K., was used to populate excited states of 193Hg through the reaction 150Nd(48Ca,5n)193Hg at a beam energy of 213 MeV and the EUROGAM detector array was used to de­ tect the γ-rays emitted by the deexciting nuclei. The normal level scheme has been further extended and a new band has been observed. In addition two new ΔI=1 structures of competing dipole and quadrupole transitions were found which will be discussed in detail.


1999 ◽  
Vol 59 (4) ◽  
pp. 2009-2032 ◽  
Author(s):  
W. F. Mueller ◽  
H. Q. Jin ◽  
J. M. Lewis ◽  
W. Reviol ◽  
L. L. Riedinger ◽  
...  
Keyword(s):  

Sign in / Sign up

Export Citation Format

Share Document