The role of the axial ligand in heme-based catalysis

1996 ◽  
Vol 1 (4) ◽  
pp. 355-355 ◽  
Author(s):  
Ivonne Rietjens
Keyword(s):  
Axial Ligand

Role of the axial ligand in hemeCO backbonding; DFT analysis of vibrational data

2000 ◽  
Vol 297 (1-2) ◽  
pp. 11-17 ◽  
Author(s):  
Kathleen M. Vogel ◽  
Pawel M. Kozlowski ◽  
Marek Z. Zgierski ◽  
Thomas G. Spiro
Keyword(s):  
Axial Ligand

scholarly journals Role of the Imide Axial Ligand in the Spin and Oxidation State of Manganese Corrole and Corrolazine Complexes

2016 ◽  
Vol 55 (11) ◽  
pp. 5274-5280 ◽  
Author(s):  
Gerard Alcover-Fortuny ◽  
Rosa Caballol ◽  
Kristine Pierloot ◽  
Coen de Graaf
Keyword(s):  
Oxidation State ◽  
Axial Ligand

scholarly journals Defining the Role of the Axial Ligand of the Type 1 Copper Site in Amicyanin by Replacement of Methionine with Leucine

Biochemistry ◽  
2009 ◽  
Vol 48 (39) ◽  
pp. 9174-9184 ◽  
Author(s):  
Moonsung Choi ◽  
Narayanasami Sukumar ◽  
Aimin Liu ◽  
Victor L. Davidson
Keyword(s):  
Axial Ligand ◽  
Copper Site ◽  
Type 1 Copper

Spectroscopic Evidence of the Role of an Axial Ligand Histidinate in the Mechanism of Adrenal Cytochrome b561

Biochemistry ◽  
2012 ◽  
Vol 51 (44) ◽  
pp. 8730-8742 ◽  
Author(s):  
Giordano F. Z. da Silva ◽  
Vladimir P. Shinkarev ◽  
Yury A. Kamensky ◽  
Graham Palmer
Keyword(s):  
Axial Ligand ◽  
Spectroscopic Evidence ◽  
Cytochrome B561

First evidence of formation of stable DBU Zn-phthalocyanine complexes: synthesis and characterization

2005 ◽  
Vol 09 (07) ◽  
pp. 519-527 ◽  
Author(s):  
Roberta Del Sole ◽  
Agnese De Luca ◽  
Giuseppe Mele ◽  
Giuseppe Vasapollo
Keyword(s):  
Thermal Analysis ◽  
Axial Ligand ◽  
Synthesis And Characterization ◽  
One Pot ◽  
Strong Base ◽  
Pyridine Complex ◽  
The Stability ◽  
First Time ◽  
Complex Thermal Analysis

Novel Zn (II) phthalocyanine and naphthalocyanine DBU complexes have been prepared in a one-pot synthesis reacting phthalonitrile precursors with an excess of DBU (1,8-diazabicyclo[5.4.0]undec-7-ene). For the first time, it has been well evidenced that DBU played the role of coordinating axial ligand together with the well known role of strong base. Also, DBU complexes showed better solubility in organic solvents due to the coordination of the bulky axial DBU ligand, compared to the Zn (II) phthalocyanines and naphthalocyanines without coordinated DBU. The coordinating properties of DBU toward ZnPcs (DBU free) complexes have also been investigated along with the ZnPc (pyridine) complex. Thermal analysis results reflecting the stability of the synthesized complexes under air are also presented.

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