Osmotic coefficients of aqueous solutions of potassium acesulfame, sodium saccharin, and ammonium and tetramethylammonium cyclohexylsulfamates at the freezing point of solutions

2010 ◽  
Vol 141 (2) ◽  
pp. 149-155 ◽  
Author(s):  
Darja Rudan-Tasic ◽  
Nataša Poklar Ulrih ◽  
Cveto Klofutar
1971 ◽  
Vol 16 (2) ◽  
pp. 222-226 ◽  
Author(s):  
Fred. Kurata ◽  
Thomas W. Yergovich ◽  
George W. Swift

2008 ◽  
Vol 40 (9) ◽  
pp. 1346-1351 ◽  
Author(s):  
Begoña González ◽  
Noelia Calvar ◽  
Ángeles Domínguez ◽  
Eugénia A. Macedo

1946 ◽  
Vol 24f (5) ◽  
pp. 287-299 ◽  
Author(s):  
K. A. Clendenning ◽  
D. E. Wright

Freezing point, viscosity, and boiling point data are presented for aqueous solutions of levo-2,3-butanediol containing methanol, ethanol, ethylene glycol, and tetrahydrofurfuryl alcohol as third components. All four ternary systems show freezing points of −50 °C. and lower over a considerable range of compositions. Among the compounds tested as third components, methanol was most effective as a thinning agent and accessory freezing point depressant. The data indicate that 20% methanol–40% butanediol–40% water is suitable for use at temperatures as low as −50 °C.


Measurements of freezing-point depression with a precision of ± 0-0002° C have been made on aqueous solutions of potassium chloride and the sulphates of copper, zinc, magnesium, calcium, cobalt and nickel. The results for the sulphates have been analyzed using the theory of incomplete dissociation in a manner which makes clear the physical status of the dissociation constants obtained, and the relation between the approaches associated with the names of Bjerrum and Davies. The values of the dissociation constants are compared with those obtained by other methods.


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