Halogen-bearing minerals in syenites and high-grade marbles of Dronning Maud Land, Antarctica: monitors of fluid compositional changes during late-magmatic fluid-rock interaction processes

1998 ◽  
Vol 132 (3) ◽  
pp. 246-268 ◽  
Author(s):  
Gregor Markl ◽  
Sandra Piazolo
Keyword(s):  
Magmatic Fluid ◽  
High Grade ◽  
Rock Interaction ◽  
Interaction Processes ◽  
Dronning Maud Land ◽  
Compositional Changes

The role of competitive fluid-rock interaction processes in the formation of high-grade gold deposits

2021 ◽  
Vol 313 ◽  
pp. 38-54
Author(s):  
Laura Petrella ◽  
Nicolas Thébaud ◽  
Katy Evans ◽  
Crystal LaFlamme ◽  
Sandra Occhipinti
Keyword(s):  
Gold Deposits ◽  
High Grade ◽  
Rock Interaction ◽  
Interaction Processes

Zircon ages and the distribution of Archaean and Proterozoic rocks in the Rauer Islands

1993 ◽  
Vol 5 (2) ◽  
pp. 193-206 ◽  
Author(s):  
P. D. Kinny ◽  
L. P. Black ◽  
J. W. Sheraton
Keyword(s):  
Granulite Facies ◽  
Metamorphic Rocks ◽  
Low Grade ◽  
High Grade ◽  
Ion Microprobe ◽  
Rock Interaction ◽  
Mafic Rocks ◽  
Grade Fluid ◽  
Vestfold Hills ◽  
Intrusive Suite

The application of zircon U-Pb geochronology using the SHRIMP ion microprobe to the Precambrian high-grade metamorphic rocks of the Rauer Islands on the Prydz Bay coast of East Antarctica, has resulted in major revisions to the interpreted geological history. Large tracts of granitic orthogneisses, previously considered to be mostly Proterozoic in age, are shown here to be Archaean, with crystallization ages of 3270 Ma and 2800 Ma. These rocks and associated granulite-facies mafic rocks and paragneisses account for up to 50% of exposures in the Rauer Islands. Unlike the 2500 Ma rocks in the nearby Vestfold Hills which were cratonized soon after formation, the Rauer Islands rocks were reworked at about 1000 Ma under granulite to amphibolite facies conditions, and mixed with newly generated felsic crust. Dating of components of this felsic intrusive suite indicates that this Proterozoic reworking was accomplished in about 30–40 million years. Low-grade retrogression at 500 Ma was accompanied by brittle shearing, pegmatite injection, partial resetting of U-Pb geochronometers and growth of new zircons. Minor underformed lamprophyre dykes intruded Hop and nearby islands later in the Phanerozoic. Thus, the geology of the Rauer Islands reflects reworking and juxtaposition of unrelated rocks in a Proterozoic orogenic belt, and illustrates the important influence of relatively low-grade fluid-rock interaction on zircon U-Pb systematics in high-grade terranes.

scholarly journals Preliminary chemical characterization of groundwater in the Rome Municipality

2015 ◽  
Author(s):  
Luca Pizzino ◽  
Daniele Cinti ◽  
Monia Procesi ◽  
Alessandra Sciarra
Keyword(s):  
Chemical Elements ◽  
Central Italy ◽  
Chemical Characterization ◽  
Mineral Waters ◽  
Measured Temperature ◽  
Large Variability ◽  
Rock Interaction ◽  
Interaction Processes ◽  
Two Samples ◽  
Water Rock Interaction

In summer 2015 a geochemical survey on groundwater was carried out at 31 sampling points (wells and piezometers) belonging to the new “Official monitoring groundwater network of Rome Municipality” (GMNR). The following parameters were measured: temperature, pH, electrical conductivity (i.e. salinity) and alkalinity; these data were used to compute partial pressure of CO2 (pCO2). Furthermore, samples were collected to characterise waters from a chemical point of view (major elements). To implement our data - base, chemical analyses of 6 CO2 - rich mineral waters of Rome were considered. Hydrochemical survey was mainly devoted to: i) classify waters in chemical facies; ii) investigate the main water-rock interaction processes governing the water’s chemical evolution, also affected by variable amounts of dissolved CO2 and iii) define the pCO2 level in groundwater in the frame of the knowledge so far acquired in the Tyrrhenian sector of central Italy.. Groundwater shows a dominant Ca-HCO3 chemistry; some samples belong to Na-HCO3, Na-Cl and CaCl2 hydrochemical facies. In the dominant facies waters show a large variability in the abundance of chemical elements, in their salinity (ranging between 0.46 e 3.83 g/l) and pH (in the interval 5.87-7.22); these features are mainly due to different water-rock interaction processes together with the presence of variable CO2 contents. Na-HCO3 waters show the lowest salinity values (TDS up to 0.32 g/l) and strongly alkaline pH; cation exchange processes with clays, causing Na enrichment and Ca and Mg removal from solution, can be invoked to justify the observed chemistry. Waters of the Castel Fusano Natural Reserve (CFNR) belong to the Na-Cl and Ca-Cl2 facies; the different chemistry reflects the geochemical processes going on in the considered coastal aquifers such as: i) mixing between freshwater and saline waters of marine origin (fossil waters, seawater intrusion) and ii) cationic exchanges with clays that make up the less permeable sediments of the area. Two samples of the CFNR group have Ca-HCO3 chemistry and represent aquifers not affected by salinization processes. Calculated pCO2 distribution is highly variable, from low (0.03 bar) to high values (0.72 bar), implying different CO2 input (and origin) in the studied aquifers. Highest levels of carbon dioxide are linked to the degassing processes going on in the Tyrrhenian sector of Central Italy.

scholarly journals HFSE‐REE Transfer Mechanisms During Metasomatism of a Late Miocene Peraluminous Granite Intruding a Carbonate Host (Campiglia Marittima, Tuscany)

Minerals ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 682
Author(s):  
Paoli ◽  
Dini ◽  
Petrelli ◽  
Rocchi
Keyword(s):  
External Source ◽  
Magmatic Fluid ◽  
Chemical Components ◽  
Fluid Composition ◽  
Peraluminous Granite ◽  
Rock Interaction ◽  
Complete Replacement ◽  
Element Mobilization ◽  
Geochemical Models ◽  
Metasomatic Event

The different generations of calc‐silicate assemblages formed during sequential metasomatic events make the Campiglia Marittima magmatic–hydrothermal system a prominent case study to investigate the mobility of rare earth element (REE) and other trace elements. These mineralogical assemblages also provide information about the nature and source of metasomatizing fluids. Petrographic and geochemical investigations of granite, endoskarn, and exoskarn bodies provide evidence for the contribution of metasomatizing fluids from an external source. The granitic pluton underwent intense metasomatism during post‐magmatic fluid–rock interaction processes. The system was initially affected by a metasomatic event characterized by circulation of K‐rich and Ca(‐Mg)‐rich fluids. A potassic metasomatic event led to the complete replacement of magmatic biotite, plagioclase, and ilmenite, promoting major element mobilization and crystallization of K‐feldspar, phlogopite, chlorite, titanite, and rutile. The process resulted in significant gain of K, Rb, Ba, and Sr, accompanied by loss of Fe and Na, with metals such as Cu, Zn, Sn, W, and Tl showing significant mobility. Concurrently, the increasing fluid acidity, due to interaction with Ca‐rich fluids, resulted in a diffuse Ca‐metasomatism. During this stage, a wide variety of calc‐silicates formed (diopside, titanite, vesuvianite, garnet, and allanite), throughout the granite body, along granite joints, and at the carbonate–granite contact. In the following stage, Ca‐F‐rich fluids triggered the acidic metasomatism of accessory minerals and the mobilization of high-field-strength elements (HFSE) and REE. This stage is characterized by the exchange of major elements (Ti, Ca, Fe, Al) with HFSE and REE in the forming metasomatic minerals (i.e., titanite, vesuvianite) and the crystallization of HFSE‐REE minerals. Moreover, the observed textural disequilibrium of newly formed minerals (pseudomorphs, patchy zoning, dissolution/reprecipitation textures) suggests the evolution of metasomatizing fluids towards more acidic conditions at lower temperatures. In summary, the selective mobilization of chemical components was related to a shift in fluid composition, pH, and temperature. This study emphasizes the importance of relating field studies and petrographic observations to detailed mineral compositions, leading to the construction of litho‐geochemical models for element mobilization in crustal magmatic‐hydrothermal settings.

Element and isotope mobility during water–rock interaction processes

2005 ◽  
Vol 30 (17-18) ◽  
pp. 993-996 ◽  
Author(s):  
Cedric Corteel ◽  
Andrea Dini ◽  
Annette Deyhle
Keyword(s):  
Rock Interaction ◽  
Interaction Processes ◽  
Water Rock Interaction

scholarly journals FluidRock Interactions in a Paleo-Geothermal Reservoir (Noble Hills Granite, California, USA). Part 2: The Influence of Fracturing on Granite Alteration Processes and Fluid Circulation at Low to Moderate Regional Strain

Geosciences ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 433
Author(s):  
Johanne Klee ◽  
Arezki Chabani ◽  
Béatrice A. Ledésert ◽  
Sébastien Potel ◽  
Ronan L. Hébert ◽  
...  
Keyword(s):  
Geothermal Reservoir ◽  
Death Valley ◽  
Distribution Analysis ◽  
Fracture Density ◽  
Fracture Zones ◽  
Rock Interaction ◽  
Interaction Processes ◽  
Regional Strain ◽  
Alteration Processes ◽  
Fracture Distribution

Fracture connectivity within fractured granitic basement geothermal reservoirs is an important factor controlling their permeability. This study aims to improve the understanding of fluid–rock interaction processes at low to moderate regional strain. The Noble Hills range (Death Valley, CA, USA) was chosen as a naturally exhumed paleo geothermal reservoir. A series of petrographic, petrophysical, and geochemical investigations, combined with a fracture distribution analysis, were carried out on samples collected across fracture zones. Our results indicate that several generations of fluids have percolated through the reservoir. An increase of (1) the alteration degree; (2) the porosity values; and (3) the calcite content was observed when approaching fracture zones. No correlation was identified among the alteration degree, the porosity, or the calcite content. At a local scale, samples showed that the degree of alteration does not necessarily depend on the fracture density or on the amount of the strain. It is concluded that the combined influence of strain and coeval fluid–rock interaction processes drastically influence the petrophysical properties of fracture zones, which in turn impact geothermal production potential.

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