Determination of 0.1 to 1000 � g/ml cadmium in a hydrometallurgical zinc refining process stream by a flow injection technique with computer controlled injection method

1996 ◽  
Vol 355 (2) ◽  
pp. 144-149
Author(s):  
Yutaka Hayashibe ◽  
Yasumasa Sayama ◽  
Koichi Oguma
Keyword(s):  
Flow Injection ◽  
Refining Process ◽  
Injection Technique ◽  
Process Stream ◽  
Injection Method ◽  
Computer Controlled

scholarly journals Rapid and Automated Analytical Methods for Redox Species Based on Potentiometric Flow Injection Analysis Using Potential Buffers

2011 ◽  
Vol 2011 ◽  
pp. 1-14 ◽  
Author(s):  
Hiroki Ohura ◽  
Toshihiko Imato
Keyword(s):  
Flow Injection ◽  
Analytical Methods ◽  
Injection Technique ◽  
Selective Electrode ◽  
Redox Species ◽  
Injection Method ◽  
Highly Sensitive ◽  
Bromide Ion ◽  
Oxidative Species

Two analytical methods, which prove the utility of a potentiometric flow injection technique for determining various redox species, based on the use of some redox potential buffers, are reviewed. The first is a potentiometric flow injection method in which a redox couple such as Fe(III)-Fe(II), Fe-Fe(CN), and bromide-bromine and a redox electrode or a combined platinum-bromide ion selective electrode are used. The analytical principle and advantages of the method are discussed, and several examples of its application are reported. Another example is a highly sensitive potentiometric flow injection method, in which a large transient potential change due to bromine or chlorine as an intermediate, generated during the reaction of the oxidative species with an Fe(III)-Fe(II) potential buffer containing bromide or chloride, is utilized. The analytical principle and details of the proposed method are described, and examples of several applications are described. The determination of trace amounts of hydrazine, based on the detection of a transient change in potential caused by the reaction with a Ce(IV)-Ce(III) potential buffer, is also described.

scholarly journals Sequential determination of chromium(VI) and chromium(III) by potentiometric flow-injection method.

2000 ◽  
Vol 49 (1) ◽  
pp. 59-64 ◽  
Author(s):  
Hiroki OHURA ◽  
Toshihiko IMATO ◽  
Ikuo MATSUO ◽  
Sumio YAMASAKI
Keyword(s):  
Flow Injection ◽  
Injection Method ◽  
Sequential Determination ◽  
Chromium Vi

scholarly journals Spectrophotometric flow injection procedure to indirect determination of paracetamol in pharmaceutical formulations using o-tolidine as reagent

2018 ◽  
Vol 33 (2) ◽  
pp. 47
Author(s):  
Orlando Fatibello-Filho ◽  
Heberth Juliano Vieira
Keyword(s):  
Standard Deviation ◽  
Detection Limit ◽  
Flow Injection ◽  
Pharmaceutical Formulations ◽  
Injection Method ◽  
Indirect Determination ◽  
Analytical Curve ◽  
Relative Standard ◽  
Injection Procedure

A spectrophotometric flow injection method for the determination of paracetamol in pharmaceutical formulations is proposed. The procedure was based on the oxidation of paracetamol by sodium hypochloride and the determination of the excess of this oxidant using o-tolidine dichloride as chromogenic reagent at 430 nm. The analytical curve was linear in the paracetamol concentration range from 8.50 x 10-6 to 2.51 x 10-4 mol L-1 with a detection limit of 5.0 x 10-6 mol L-1. The relative standard deviation was smaller than 1.2% for 1.20 x 10-4 mol L-1 paracetamol solution (n = 10). The results obtained for paracetamol in pharmaceutical formulations using the proposed flow injection method and those obtained using a USP Pharmacopoeia method are in agreement at the 95% confidence level.

Sensitive flow-injection technique for the determination of dissolved organic carbon in natural and waste waters

1992 ◽  
Vol 261 (1-2) ◽  
pp. 287-294 ◽  
Author(s):  
R.T. Edwards ◽  
I.D. McKelvie ◽  
P.C. Ferrett ◽  
B.T. Hart ◽  
J.B. Bapat ◽  
...  
Keyword(s):  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Flow Injection ◽  
Injection Technique ◽  
Waste Waters

Spectrophotometric determination of urinary iodine by flow-injection analysis with on-line catalytic digestion

1996 ◽  
Vol 42 (12) ◽  
pp. 2021-2027 ◽  
Author(s):  
Z Yaping ◽  
Y Dongxing ◽  
C Jixiang ◽  
L Tianshiu ◽  
C Huiqin
Keyword(s):  
Flow Injection ◽  
Reference Sample ◽  
Urinary Iodine ◽  
Iodine Concentration ◽  
Urine Samples ◽  
Injection Technique ◽  
Freeze Dried ◽  
On Line ◽  
Iodine In Urine

Abstract A flow-injection technique involving on-line catalytic digestion and spectrophotometric detection has been developed for the determination of iodine in urine. After urine samples are digested by KMnO4-K2Cr2O7-H2SO4 solution, the iodine in the urine catalyzes the reaction of As(III) with Ce(IV). The remaining Ce(IV) is then reacted with brucine and the product is detected with a spectrophotometer at 480 nm. With this technique, we obtained a detection limit for urinary iodine of 0.039 mumol/L, and the linear range was 0.039-7.88 mumol/L with a CV < 3%. Analytical recovery ranged between 92% and 104% (mean 99%). The sampling frequency of the flow-injection technique was 70/h. We applied the method to measure the iodine concentration in a freeze-dried urine reference sample and in collected urine samples, and compared the results with those obtained by the accepted alkaline ashing technique. The proposed technique has the advantages of being simple, rapid, precise, accurate, and sensitive. It can be used to assess iodine-deficient populations as well as those receiving treatment.

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