Application of a hexapole collision and reaction cell in ICP-MS Part I: Instrumental aspects and operational optimization

1999 ◽  
Vol 365 (5) ◽  
pp. 415-421 ◽  
Author(s):  
I. Feldmann ◽  
N. Jakubowski ◽  
D. Stuewer
Keyword(s):  
Reaction Cell ◽  
Operational Optimization ◽  
Icp Ms

Understanding reactions with O2 for 90Sr measurements by ICP-MS with collision-reaction cell

2007 ◽  
Vol 265 (1) ◽  
pp. 15-22 ◽  
Author(s):  
Georges Favre ◽  
René Brennetot ◽  
Frédéric Chartier ◽  
Pierre Vitorge
Keyword(s):  
Reaction Cell ◽  
Icp Ms

Copper determination using ICP-MS with hexapole collision cell

2009 ◽  
Vol 63 (5) ◽  
Author(s):  
Vladislav Chrastný ◽  
Michael Komárek
Keyword(s):  
Inductively Coupled Plasma ◽  
Charge Ratio ◽  
Additional Mass ◽  
Reaction Cell ◽  
Bias Effect ◽  
Copper Determination ◽  
Mass Bias ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry

AbstractDetermination of copper using inductively coupled plasma mass spectrometry (ICP-MS) suffers from polyatomic overlays originating from Na+ and Mg2+ matrix elements due to the formation of 40Ar23Na+ and 40Ar25Mg+ in the mass-to-charge ratios of 63 and 65, respectively. The collision/reaction cell technology belongs to the most modern methods used to overcome polyatomic interferences. Gas-filled collision/reaction cell can cause an additional mass bias effect influencing analytical precision of the method. In this study, the additional mass bias effect of the hexapole collision/reaction cell ICP-MS was studied on an example of n(65Cu)/n(63Cu) isotope ratio. As a result, a method for suppressing polyatomic interference on the mass-to-charge ratio of 63 and 65 was introduced and additional mass bias of the collision/reaction cell was lowered to an acceptable level.

Sign in / Sign up

Export Citation Format

Share Document