Calculation of the polychlorinated terphenyl congener distribution and gas chromatographic retention behavior of selected single standards on four stationary liquid phases

1998 ◽  
Vol 362 (4) ◽  
pp. 404-408 ◽  
Author(s):  
Gerald Remberg ◽  
Pat Sandra ◽  
Wolfgang Nyiry ◽  
Norbert Winker ◽  
A. Nikiforov
1995 ◽  
Vol 60 (5) ◽  
pp. 813-819 ◽  
Author(s):  
Jasmina Novakovic ◽  
Eva Tvrzická ◽  
Václav Všetečka ◽  
Vladimír Pouzar ◽  
Ladislav Feltl

The capillary gas-chromatographic retention behavior of six underivatized equine estrogens (estrone, equilin, equilenin and their corresponding 17α-diols) on a mixed stationary phase (non-polar CP-Sil 5 CB and slightly polar CP-Sil 19 CB capillary columns coupled in series) was characterized by their Kovats retention indices and steroid numbers. In order to find whether a correlation exists between the chromatographic retention and some physico-chemical properties of the compounds, their octanol-water partition coefficients and dipole moments were measured. No straightforward correlation was observed between the physico-chemical properties and the retention behavior, which suggests that the GC separation of equine estrogens is governed by some specific electron donor-electron acceptor interactions of a chemical nature.


Author(s):  
L. N. Bazhenova ◽  
V. E. Kirichenko ◽  
K. I. Pashkevich ◽  
I. P. Sereda ◽  
V. P. Mikhailenko

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