Flow sorption calorimetry, a powerful tool to investigate the acid-base character of organic polymer surfaces

1997 ◽  
Vol 358 (1-2) ◽  
pp. 244-247 ◽  
Author(s):  
S. Schneider ◽  
F. Simon ◽  
D. Pleul ◽  
H.-J. Jacobasch
1993 ◽  
Vol 40 (1) ◽  
pp. 73-81 ◽  
Author(s):  
G.A. Takacs ◽  
V. Vukanovic ◽  
D. Tracy ◽  
J.X. Chen ◽  
F.D. Egitto ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 905
Author(s):  
Vinothkumar Ganesan ◽  
Sungho Yoon

A facile, one-pot design strategy to construct chromium(III)-phthalocyanine chlorides (Pc’CrCl) to form porous organic polymer (POP-Pc’CrCl) using solvent knitting Friedel-Crafts reaction (FCR) is described. The generated highly porous POP-Pc’CrCl is functionalized by post-synthetic exchange reaction with nucleophilic cobaltate ions to provide an heterogenized carbonylation catalyst (POP-Pc’CrCo(CO)4) with Lewis acid-base type bimetallic units. The produced porous polymeric catalyst is identical to that homogeneous counterpart in structure and coordination environments. The catalyst is very selective and effective for mono carbonylation of epoxide into corresponding lactone and the activities are comparable to those observed for a homogeneous Pc’CrCo(CO)4 catalyst. The (POP-Pc’CrCo(CO)4) also displayed a good catalytic activities and recyclability upon successive recycles.


2007 ◽  
Vol 111 (15) ◽  
pp. 3918-3926 ◽  
Author(s):  
Wenbin Zhong ◽  
Yongxin Wang ◽  
Yan ◽  
Yufeng Sun ◽  
Jianping Deng ◽  
...  

1986 ◽  
Vol 60 (9) ◽  
pp. 3315-3322 ◽  
Author(s):  
E. Sutcliffe ◽  
R. Srinivasan

2017 ◽  
Vol 2017 ◽  
pp. 1-7 ◽  
Author(s):  
Eduard Kraus ◽  
Lukas Orf ◽  
Michael Heilig ◽  
Benjamin Baudrit ◽  
Irina Starostina ◽  
...  

The existing wetting methods for the determination of acid-base properties on solid surfaces are discussed. Striving for a better understanding of the adhesive polymer interactions in adhesively joined polymers, the methods of Berger and van Oss-Chaudhury-Good were found as the most suitable methods for the investigation of wetting on solid polymer surfaces. Methods of nonlinear systems by Della Volpe and Siboni were adapted and evaluated on plastic surfaces. In the context of these investigations various data of the surface free energy as well as its components have been identified for a number of polymer surfaces by application of spatial equation solutions.


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