Chiral acetylenic sulfoxides and related compounds in organic synthesis

Author(s):  
Albert W. M. Lee ◽  
W. H. Chan
2015 ◽  
Vol 13 (28) ◽  
pp. 7599-7613 ◽  
Author(s):  
H. Iida ◽  
Y. Imada ◽  
S.-I. Murahashi

Using simple riboflavin related compounds as biomimetic catalysts, catalytic oxidation of various substrates with hydrogen peroxide or molecular oxygen can be performed selectively under mild conditions. The principle of these reactions is fundamental and will provide a wide scope for environmentally benign future practical methods.


2020 ◽  
Vol 17 (8) ◽  
pp. 946-957
Author(s):  
Ravindra V. Kupwade

The chemistry of hypervalent iodine compounds has been experiencing considerable attention of organic chemists during the past few years. Hypervalent iodine reagents have found ubiquitous applications in organic synthesis because of their mild and highly chemoselective oxidizing properties, easy commercial availability, and environmental benign character. Along with oxidation of alcohol, they have also shown to be useful in number of organic transformations which include oxidative functionalization of carbonyl compounds, catalytic imidations, cyclization, oxidative coupling of phenols, amines and related compounds. Among various hypervalent iodine reagents, iodine-V compounds (λ5-iodanes) have attracted much attention in recent years. This review narrates the particular advances in iodine (V) reagents with special emphasis on the use of DMP in organic transformations.


Synthesis ◽  
1989 ◽  
Vol 1989 (10) ◽  
pp. 721-734 ◽  
Author(s):  
Herbert Frauenrath

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