Palaeoproduction control on anoxia and organic matter preservation and accumulation in the Kimmeridge Clay Formation of Yorkshire (G.B.): molecular assessment

2008 ◽  
pp. 49-62 ◽  
Author(s):  
Jean-Robert Disnar ◽  
Lalanirina Ramanampisoa
Keyword(s):  
Organic Matter ◽  
Molecular Assessment ◽  
Clay Formation

Modelling Transport of 14 C-Labelled Natural Organic Matter (NOM) in Boom Clay

2008 ◽  
Vol 1107 ◽  
Author(s):  
Alice Ionescu ◽  
Norbert Maes ◽  
Dirk Mallants
Keyword(s):  
Organic Matter ◽  
Natural Organic Matter ◽  
Water Movement ◽  
Numerical Code ◽  
Migration Behavior ◽  
Colloidal Transport ◽  
Boom Clay ◽  
Kinetically Controlled ◽  
Clay Formation ◽  
Hydrus 1D

AbstractIn Belgium, the Boom Clay formation is considered to be the reference formation for HLW disposal R&D. Assessments to date have shown that the host clay layer is a very efficient barrier for the containment of the disposed radionuclides. Due to absence of significant water movement), diffusion - the dominant transport mechanism, combined with generally high retardation of radionuclides, leads to extremely slow radionuclide migration. However, trivalent lanthanides and actinides form easily complexes with the fulvic and humic acids which occur in Boom Clay and in its interstitial water. Colloidal transport may possibly result in enhanced radionuclide mobility, therefore the mechanisms of colloidal transport must be better understood. Numerical modeling of colloidal facilitated radionuclide transport is regarded an important means for evaluating its importance for long-term safety.The paper presents results from modeling experimental data obtained in the framework of the EC TRANCOM-II project, and addresses the migration behavior of relevant radionuclides in a reducing clay environment, with special emphasis on the role of the Natural Organic Matter (NOM) [1]. Percolation type experiments, using stable 14C-labelled NOM, have been interpreted by means of the numerical code HYDRUS-1D [2]. Tracer solution collected at regular intervals was used for inverse modeling with the HYDRUS-1D numerical code to identify the most likely migration processes and the associated parameters. Typical colloid transport submodels tested included kinetically controlled attachment/detachment and kinetically controlled straining and liberation.

scholarly journals A source rock evaluation of the Mesozoic Sediments of the Well Hyllebjerg-1 Danish Subbasin

1988 ◽  
Vol 9 ◽  
pp. 1-105
Author(s):  
Birthe J Schmidt
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Geothermal Gradient ◽  
Organic Content ◽  
Lower Jurassic ◽  
Source Rocks ◽  
Marginal Areas ◽  
Algal Material ◽  
Clay Formation ◽  
Promising Source

The source rock potential of Mesozoic sediments (cuttings) from the Hyllebjerg 1 well, Danish Subbasin, has been assessed using a number of different petrographical and organochemical methods. Upper Jurassic sediments (Bream Formation) equivalent to the principal source rocks of the North Sea graben structures (Kimmeridge Clay Formation and lateral equivalents) do not show similar prominent source rock characteristics in this well, although a higher proportion of algal material is observed. Sediments with the most promising source rock characteristics for liquid hydrocarbons were· detected mainly in the lower- Jurassic sequences of the upper Fjerritslev Format ion (F-4 and upper F-3 Member) and in one horizon in the Upper Cretaceous Vedsted Formation which showed a good quality composition and a relatively high content of organic matter. But these sediments may be excluded as actual source rocks in this well as maturity (assuming the threshold value near 0. 60 % R ) is first reached at approximately 8500' 0 depth i.e. at the top of the Gassum Formation (Upper Triassic/ Lower Jurassic). The conditions may only by slightly different off - structure is this area, as the F-4 and F-3 Member sequence according to seismic sections is found at approximately the same depth. But the depth to ( and the thickness of) the Fjerritslev Formation is increasing towards the SE into the rimsynclines of the saltdomes nearby. While sufficient maturity is reached in the deeper part of the well, no commercial accumulations of hydrocarbons were encountered. This is attributed to the mainly reworked, unfavourable type of organic matter and the generally decreasing organic content downwards in the well, approaching the lower 1 imi t for potential source rocks ( set at O, 5% TOC). However, generation and migration of small amounts of gaseous hydrocarbons from Gassum Formation sediments containing more humic-influenced organic matter with only minor reworking cannot generally be excluded either here or elsewhere in the basin. Some more attention should also be paid to the Vinding Formation sediments which contain some algae- ri eh ( Botryocous-type) oil-prone horizons of more favourable source rock conditions. Mature sediments are found at shallower depths ( 8500 ') in this well in the central part of the basin compared to the more marginal areas (8900') where a slightly higher geothermal gradient in Jiyllebjerg 1 ( 28°C/km uncorrected) is seen compared with the marginal areas (23.5°C/km uncorrected) away from the basinal depocenter. The basinal depocenter also has a higher heat flow.

scholarly journals Dynamic climate-driven controls on the deposition of the Kimmeridge Clay Formation in the Cleveland Basin, Yorkshire, UK

2019 ◽  
Author(s):  
Elizabeth Atar ◽  
Christian März ◽  
Andrew Aplin ◽  
Olaf Dellwig ◽  
Liam Herringshaw ◽  
...  
Keyword(s):  
Organic Matter ◽  
Trace Metals ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Distal Part ◽  
Hadley Cell ◽  
Redox Conditions ◽  
Climate Modelling ◽  
Lower Variability ◽  
Clay Formation

Abstract. The Kimmeridge Clay Formation (KCF) is a laterally extensive, total organic carbon-rich succession deposited throughout Northwest Europe during the Kimmeridgian–Tithonian (Late Jurassic). Here we present a petrographic and geochemical dataset for a 40 metre-thick section of a well-preserved drill core recovering thermally-immature deposits of the KCF in the Cleveland Basin (Yorkshire, UK), covering an interval of approximately 800 kyr. The new data are discussed in the context of depositional processes, sediment source and supply, transport and dispersal mechanisms, water column redox conditions, and basin restriction. Armstrong et al. (2016) recently postulated that an expanded Hadley Cell, with an intensified but alternating hydrological cycle, heavily influenced sedimentation and total organic carbon (TOC) enrichment, through promoting the primary productivity and organic matter burial, in the UK sectors of the Boreal Seaway. Consistent with such climate boundary conditions, petrographic observations, total organic carbon and carbonate contents, and major and trace element data presented here indicate that the KCF of the Cleveland Basin was deposited in the distal part of the Laurasian Seaway. Depositional conditions alternated between three states that produced a distinct cyclicity in the lithological and geochemical records: lower variability mudstone intervals (LVMIs) which comprise of clay-rich mudstone, TOC-rich sedimentation, and carbonate-rich sedimentation. The lower variability mudstone intervals dominate the studied interval but are punctuated by three ~ 2–4 m thick intervals of alternating TOC-rich and carbonate-rich sedimentation (here termed higher variability mudstone intervals, HVMIs). During the lower variability mudstone intervals, conditions were quiescent with oxic to sub-oxic bottom water conditions. During the higher variability mudstone intervals, highly dynamic conditions resulted in repeated switching of the redox system in a way similar to the modern deep basins of the Baltic Sea. During carbonate-rich sedimentation, oxic conditions prevailed, most likely due to elevated depositional energies at the seafloor by current/wave action. During TOC-rich sedimentation, anoxic-euxinic conditions led to an enrichment of redox sensitive/sulphide forming trace metals at the seafloor and a preservation of organic matter, and an active Mn-Fe particulate shuttle delivered redox sensitive/sulphide forming trace metals to the seafloor. In addition, based on TOC–S–Fe relationships, organic matter sulphurisation appears to have increased organic material preservation in about half of the analysed samples throughout the core, while the remaining samples were either dominated by excess Fe input into the system or experienced pyrite oxidation and sulphur loss during oxygenation events. New Hg/TOC data do not provide evidence of increased volcanism during this time, consistent with previous work. Set in the context of recent climate modelling, our study provides a comprehensive example of the dynamic climate-driven depositional and redox conditions that can control TOC and metal accumulations in the distal part of a shallow epicontinental sea, and is therefore key to understanding the formation of similar deposits throughout Earth's history.

Controls on organic accumulation in late Jurassic shales of northwestern Europe as inferred from trace-metal geochemistry

2004 ◽  
Vol 175 (5) ◽  
pp. 491-506 ◽  
Author(s):  
Nicolas Tribovillard ◽  
Alain Trentesaux ◽  
Abdelkader Ramdani ◽  
François Baudinet ◽  
Armelle Riboulleau
Keyword(s):  
Organic Matter ◽  
Dilution Effect ◽  
Major Elements ◽  
Depositional Environments ◽  
Sediment Flux ◽  
Geochemical Data ◽  
Clay Shales ◽  
Reducing Conditions ◽  
Water Stratification ◽  
Clay Formation

Abstract In the Kimmeridge Clay Formation of the Wessex-Weald Basin, five organic-matter-rich intervals (or ORIs), dated from Kimmeridgian-Tithonian times, can be correlated from distal depositional environments in Dorset and Yorkshire (UK) to the proximal environments in Boulonnais, northern France. The ORIs are superimposed on a meter-scale cyclic distribution of organic matter (OM), referred to as primary cyclicity, which is commonly interpreted to result from Milankovitch climate forcing. The present work addresses the distribution of redox-sensitive and/or sulfide-forming trace metals and selected major elements (Si, Al and Fe) in Kimmeridge Clay shales from the Cleveland Basin (Yorkshire) and the Boulonnais cliffs with two objectives: 1) to determine whether the ORIs formed in similar paleoenvironments, and 2) to identify the mechanism(s) of OM accumulation. High-resolution geochemical data from primary cycles in the Yorkshire boreholes (Marton and Ebberstone boreholes), were studied and the results are then applied with lower resolution sampling at the ORI scale in the Flixton borehole and Boulonnais cliff. Good correlations are found between total organic carbon (TOC) vs Cu/Al and Ni/Al, but relationships between TOC and Mo/Al, V/Al and U/Al are more complex. Cu and Ni enrichment is interpreted to have resulted from passive accumulation with OM in an oxygen-deficient basinal setting, which prevented the subsequent loss of Cu and Ni from the sediment. Mo and V were significantly enriched only in sediments where considerable amounts of OM (TOC>7 %) accumulated, the result of strongly reducing conditions and OM burial. At the scale of the Flixton ORIs, the samples with the highest Mo and V concentrations also show relative Fe enrichment, suggesting pyrite formation in the water column (combination of euxinic conditions and presumably low sedimentation rates). Samples from all ORIs were slightly enriched in Si relative to Al, interpreted as reflecting decreased sediment flux during transgressive and early-highstand systems tracts. The data show that in some ORIs, OM accumulation proceeded while productivity was not particularly high and sediments were not experiencing strong anoxia. In other ORIs, OM accumulation was accompanied by widespread anoxia and possibly euxinic conditions in distal settings. Though somewhat different from each other, the ORIs have all developed during episodes of reduced terrigenous supply (transgressive episodes). The common feature linking these contrasted episodes of enhanced OM storage (ORIs) must be the conjunction of productivity coupled with a decrease in the dilution effect by the land-derived supply, in a depositional environment prone to water stratification and, therefore, favorable to OM preservation and accumulation.

Diagenesis in Upper Jurassic marine sandstones from the North Sea Well 14/26-1 and its significance

Clay Minerals ◽  
1986 ◽  
Vol 21 (4) ◽  
pp. 513-535 ◽  
Author(s):  
C. V. Jeans ◽  
M. J. Fisher
Keyword(s):  
Organic Matter ◽  
North Sea ◽  
Upper Jurassic ◽  
Immature Stage ◽  
Maximum Temperature ◽  
Burial Depth ◽  
Hydrocarbon Generation ◽  
Clay Formation ◽  
Later Phase ◽  
Ferroan Dolomite

AbstractA tightly cemented series of marine sandstones, interbedded with shales and mudstones, occurs in the lower part of the Kimmeridge Clay Formation (Kimmeridgian to Ryazanian) of Arco Well 14/26-1 (Core No. 5, 8067–8085 ft). The well is on the northern flank of the Fraserburgh Spur Basement Ridge. The sediments are in the immature stage of hydrocarbon generation and are now at their maximum temperature and burial depth: the bottom hole temperature is 75°C. The sandstone diagenesis was complex, essentially of an intrinsic type, and took place under considerable overpressures. Initially a series of early cements was precipitated (minor chalcedony, quartz, feldspar, ferroan calcite, non-ferroan dolomite and major ferroan dolomite). A later phase of diagenesis embraced two periods of intrastratal solution (each affecting both the silicate and the carbonate components of the sediment) separated by a phase of calcite precipitation and followed by a phase of kaolinite cementation. The early cements are interpreted as being of the intrinsic miagenetic type. The later phase of diagenesis (alternating intrastratal solution and cement precipitation) resulted from the interaction of (i) the biotic breakdown of organic matter by thermophyllic micro-organisms and (ii) the abiotic thermal alteration of organic matter with the mineral components of the sediment: of particular importance were varying PCO2 and the generation of carboxylic and phenolic acids. The diagenetic pattern is closely comparable to that known from various Upper Jurassic sandy shelf sediments in other parts of the northern North Sea which have very different burial histories.

Geochemical study of organic-matter rich cycles from the Kimmeridge Clay Formation of Yorkshire (UK): productivity versus anoxia

1994 ◽  
Vol 108 (1-2) ◽  
pp. 165-181 ◽  
Author(s):  
Nicolas-Pierre Tribovillard ◽  
Alain Desprairies ◽  
Elisabeth Lallier-Vergès ◽  
Philippe Bertrand ◽  
Nicole Moureau ◽  
...  
Keyword(s):  
Organic Matter ◽  
Geochemical Study ◽  
Clay Formation

scholarly journals An isotopic biogeochemical study of the Oxford Clay Formation (U.K.)

1992 ◽  
Vol 6 ◽  
pp. 162-162
Author(s):  
Fabien Kenig ◽  
John M. Hayes ◽  
Roger Summons
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Organic Matter ◽  
Saturated Hydrocarbon ◽  
Hydrocarbon Fraction ◽  
Gas Chromatography Mass Spectrometry ◽  
Geochemical Data ◽  
Chromatography Mass Spectrometry ◽  
Isotopic Analyses ◽  
Clay Formation

Lipids from a suite of 12 representative samples from the Lower Oxford Clay (LOC) and from the Middle and Upper Oxford Clay (MUOC) were extracted with organic solvent, separated, and analyzed qualitatively and quantitatively using gas chromatography-mass spectrometry (GC-MS) and isotopically using isotope-ratio-monitoring gas chromatography-mass spectrometry (irmGCMS). Determination of molecular structures allowed identification of compounds which retained enough chemical structural information to be recognizable as having a biochemical origin related to a specific organism or group of organisms (biomarkers). By allowing assignment of each compound to a portion of the local carbon cycle (production, sedimentation, and alteration), isotopic analyses of individual compounds provided further information regarding their origins. The 12 samples were chosen to represent the various macrofaunal assemblages define by Duff (1975) and to cover the total range of variability of the bulk geochemical parameters measured on sediments from LOC and MUOC (Kenig et al., this symposium).A relatively high content of unsaturated hydrocarbons, as well as the abundance of biogenic forms of molecular stereoisomers such as ββ hopanes and ααα steranes and other molecular indicators, confirms the low level of maturity of organic matter in the LOC. Contributions from the two main sources of sedimentary organic matter already identified from bulk geochemical data, marine phytoplankton and terrestrial organic matter, can be recognized in the saturated hydrocarbon fraction of all the samples analyzed. However, contributions from these two sources vary as a function of the TOC content, the HI, and the δ13C of organic matter. Saturated hydrocarbon fractions of high-TOC samples, formed during periods of high marine productivity, are mainly dominated by pristane and phytane and by tetra- and pentacyclic biomarkers. This dominance decreases with the TOC content and the 13C abundance. Conversely, the relative abundance of compounds indicative of terrigenous input increases. In samples with lower TOC, n-alkanes with a strong odd-carbon preference, peaking at C27, are particularly prominent in the saturated hydrocarbon fraction.Biosynthetic products with n-alkyl carbon skeletons are found in nearly all organisms. Accordingly, sedimentary n-alkanes are likely to derive from multiple sources. These can be partly distinguished by isotopic analysis of individual n-alkanes. In particular, marine and terrestrial sources can be resolved. Considering the variation of their relative abondance and of their isotopic composition as a function of TOC, δ13C of total organic matter and hydrogen index, the origins of n-alkanes, pristane and phytane as well as those of other biomarkers will be discussed. The paleobiological assemblage responsible for the production and alteration of the organic matter will be tentatively reconstructed.

Sign in / Sign up

Export Citation Format

Share Document