Thermodynamic characterization of metastable organic liquids at the quasi-static glass-transition-temperature

2007 ◽  
pp. 53-60 ◽  
Author(s):  
H. G. Kilian
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Organic Liquids ◽  
Thermodynamic Characterization

scholarly journals Design of an n-type low glass transition temperature radical polymer

2021 ◽  
Author(s):  
Teng Chi ◽  
Siddhartha Akkiraju ◽  
Zihao Liang ◽  
Ying Tan ◽  
Ho Joong Kim ◽  
...  
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Synthesis And Characterization ◽  
Design Synthesis

We document the design, synthesis, and characterization of the first low glass transition temperature, n-type (i.e., preferentially-reduced) radical polymer.

scholarly journals Polarization and Piezoelectric Properties of a Nitrile Substituted Polyimide

1996 ◽  
Vol 459 ◽  
Author(s):  
Joycelyn Simpson ◽  
Zoubeida Ounaies ◽  
Catharine Fay
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Remanent Polarization ◽  
Piezoelectric Properties ◽  
Synthesis And Characterization

ABSTRACTThis research focuses on the synthesis and characterization of a piezoelectric (β-CN)-APB/ODPA polyimide. The remanent polarization and piezoelectric d31 and g33 coefficients are reported to assess the effect of synthesis variations. Each of the materials exhibits a level of piezoelectricity which increases with temperature. The remanent polarization is retained at temperatures close to the glass transition temperature of the polyimide.

Preparation and characterization of post-derivatives from functional polystyrene (ATRP) with p-nitroanilineazomethine phenol and their thermal and optical study

e-Polymers ◽  
2006 ◽  
Vol 6 (1) ◽  
Author(s):  
Xifei Yu ◽  
Guo Zhang ◽  
Tongfei Shi ◽  
P.K. Dutta ◽  
Lijia An
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Liquid Crystalline ◽  
Gel Permeation Chromatography ◽  
Side Chain ◽  
Scanning Calorimetry ◽  
Xrd Study ◽  
Covalently Linked

AbstractThe functional polystyrene, (Cl-PS)2-CHCOOCH2CH2OH (designated as XPSt and coded P2) was prepared by ATRP at 1300C using CuCl and bipyridine as catalysts, 2,2-dichloro acetate-ethylene glycol (DCAG) as multifunctional initiator and THF as solvent. 4-Nitoroaniline azomethine-4’ phenol (P1) as chromophores were covalently linked to the functional end groups of the polymer by using simple displacement reaction. The functional polystyrenes, namely XPSt (P2) and (PS)2-CHCOOCH2CH2OH, designated as X-PSt and coded P3 and their post-derivatives, namely, DXPSt (P4) and DX-PSt (P5) respectively were characterized by IR, NMR and UV spectroscopies, gel permeation chromatography (GPC) and thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), polarising optical microscopy (POM) and XRD studies. DSC showed that incorporation of chromophores in the side chains of polymers towards the polystyrene moiety increases the rigidity of the polymer and subsequently, its glass transition temperature; however the incorporation of side chain towards the alcoholic functional group decreases the glass transition temperature. The post derivatives do not play any significant role to increase the thermal stability (TGA). There was evidence for liquid crystalline properties in the resulting polymer derivative DXPSt (P4) as observed from POM study, which defines the alignment of chromophores into the polymers. The XRD study shows crystalline behaviour of the polymer derivative, P4. The polymer derivative, DXPSt (P5) does not show such behaviour and this may be due to the bonding of azomethine towards the short chain alcoholic telechelic alcoholic sides of the copolymer.

Synthesis and characterization of new silicon-containing poly(arylene-1,3,4-oxadiazole)s

1995 ◽  
Vol 7 (4) ◽  
pp. 493-501 ◽  
Author(s):  
I Sava ◽  
B Schulz ◽  
S Zhu ◽  
M Bruma
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Synthesis And Characterization ◽  
Polycondensation Reaction ◽  
Cyclization Process ◽  
Film Forming ◽  
Temperature Solution ◽  
Solution Polycondensation

New silicon-containing aromatic polyhydrazides were synthesized by low-temperature solution polycondensation reaction of bis(p-chlorocarbonylphenyl)diphenylsilane with various aromatic dihydrazides, or of bis(p-carbohydrazidophenyl)diphenylsilane with diacid chlorides. The corresponding poly(arylene-1,3,4-oxadiazole)s wvere prepared by thermal cyclodehydration in the solid state. The cyclization process takes place at temperatures in the range of 250-300 IC. The resulting silicon-containing poly(arylene-1,3,4-oxadiazole)s are soluble in common organic solvents and have good film-forming abilities. They are stable up to 420-480 'C and their glass transition temperature is in the range of 262-278C.

scholarly journals Synthesis and characterization of methylammonium phosphates as crystalline approximants for anhydrous, low melting phosphate glasses

RSC Advances ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 1822-1830
Author(s):  
Martin Mangstl ◽  
Jan Konrad Wied ◽  
Johannes Weber ◽  
Christian Pritzel ◽  
Reinhard Trettin ◽  
...  
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Phosphate Glass ◽  
Phosphate Glasses ◽  
Synthesis And Characterization ◽  
The Novel

The novel glass shows the lowest glass transition temperature known for binary phosphate glass systems without acidic protons.

scholarly journals Synthesis and Characterization of Poly(Acrylic Acid)/Organo-Modified Nanohydroxyapatite Nanocomposites: Thermal, Optical and Biocompatibility Properties

2018 ◽  
Vol 18 (3) ◽  
pp. 54-67 ◽  
Author(s):  
M. E. Diken ◽  
S. Doğan ◽  
Y. Turhan ◽  
M. Doğan
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Simulated Body Fluid ◽  
Acrylic Acid ◽  
Body Fluid ◽  
Synthesis And Characterization ◽  
Uv Absorbance ◽  
Poly Acrylic Acid

AbstractThe aim of this study was to investigate the structural, thermal, optical and biocompatibility properties of poly(acrylic acid)(PAA)/organo-modified nanohydroxyapatite (OM-nHAp) nanocomposites synthesized by solvent intercalation method. The characterization of PAA/OM-nHAp nanocomposites was made by different techniques. SEM and TEM results showed that OM-nHAp particles were dispersed in the nanoscale into PAA matrix and that they were uniformly distributed within film. Glass transition temperature of PAA increased with OM-nHAp content. Ultraviolet (UV) absorbance experiments showed that PAA had a higher UV transmission than its nanocomposites. The biocompatibility of nanocomposites was also examined in simulated body fluid.

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