Fluorescence probe studies during the curing of epoxy systems

Author(s):  
B. Strehmel ◽  
M. Younes ◽  
V. Strehmel ◽  
S. Wartewig
2017 ◽  
Vol 39 (1) ◽  
pp. 7-13
Author(s):  
Ye.P. Mamunya ◽  
◽  
O.K. Matkovska ◽  
O.V. Zinchenko ◽  
E.V. Lebedev ◽  
...  

2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>


2013 ◽  
Vol 30 (5) ◽  
pp. 555
Author(s):  
Shaoguang GENG ◽  
Xiaoying JIANG ◽  
Fengling CUI ◽  
Lei SHI

2021 ◽  
Vol 2 (2) ◽  
pp. 419-430
Author(s):  
Ankur Bajpai ◽  
James R. Davidson ◽  
Colin Robert

The tensile fracture mechanics and thermo-mechanical properties of mixtures composed of two kinds of epoxy resins of different chemical structures and functional groups were studied. The base resin was a bi-functional epoxy resin based on diglycidyl ether of bisphenol-A (DGEBA) and the other resins were (a) distilled triglycidylether of meta-amino phenol (b) 1, 6–naphthalene di epoxy and (c) fluorene di epoxy. This research shows that a small number of multifunctional epoxy systems, both di- and tri-functional, can significantly increase tensile strength (14%) over neat DGEBA while having no negative impact on other mechanical properties including glass transition temperature and elastic modulus. In fact, when compared to unmodified DGEBA, the tri-functional epoxy shows a slight increase (5%) in glass transition temperature at 10 wt.% concentration. The enhanced crosslinking of DGEBA (90 wt.%)/distilled triglycidylether of meta-amino phenol (10 wt.%) blends may be the possible reason for the improved glass transition. Finally, the influence of strain rate, temperature and moisture were investigated for both the neat DGEBA and the best performing modified system. The neat DGEBA was steadily outperformed by its modified counterpart in every condition.


Polymer ◽  
2021 ◽  
Vol 212 ◽  
pp. 123260 ◽  
Author(s):  
J. Gao ◽  
X. Chu ◽  
C.K. Henry ◽  
S.C. Santos ◽  
G.R. Palmese

2021 ◽  
Vol 188 (7) ◽  
Author(s):  
Yuedi Ding ◽  
Zhenqiang Fan ◽  
Bo Yao ◽  
Dong Xu ◽  
Minhao Xie ◽  
...  

2021 ◽  
Vol 235 ◽  
pp. 118056
Author(s):  
Rongzhi Chen ◽  
Kuo Zhan ◽  
Yizhou Xing ◽  
Zhaolong Wang ◽  
Yabin Zhu ◽  
...  
Keyword(s):  

Author(s):  
Haoyuan Yin ◽  
Haijun Chi ◽  
Zhuye Shang ◽  
Ali Qaitoon ◽  
Jianfei Yu ◽  
...  

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