Lithium nitride, Li3N, an unusual ionic conductor

2007 ◽  
pp. 77-108 ◽  
Author(s):  
Albrecht Rabenau
Keyword(s):  
Ionic Conductor ◽  
Lithium Nitride

Is there an N3− ion in the crystal structure of the ionic conductor lithium nitride (Li3N)?

1978 ◽  
Vol 34 (6) ◽  
pp. 999-1005 ◽  
Author(s):  
H. Schulz ◽  
K. Schwarz
Keyword(s):  
Crystal Structure ◽  
Ionic Crystal ◽  
Ionic Conductor ◽  
Small Range ◽  
Structure Parameters ◽  
Neutral Atoms ◽  
Lithium Nitride ◽  
Temperature Range ◽  
Free Ion

The structure parameters of Li3N in the temperature range -120 to 20°C were refined both for neutral atoms (Li0 and N0) and for ions (Li+ and N3-). For N3- new scattering curves were used which were calculated by applying stabilizing Watson-sphere potentials for different radii. All structure parameters depend critically on the scattering curves used. However, only on the assumption of ions, and only for N3- scattering curves corresponding to a small range of Watson radii, were physically meaningful structure parameters and R values down to 0.9% obtained. These structure refinements demonstrate that Li3N can be considered as an ionic crystal in which the N3- ion, though unstable as a free ion, is stabilized by the surrounding Li+ ions.

Exceeding three-electron reactions in Na3+2xMn1+xTi1-x(PO4)3 NASICON Cathode with High Energy Density for Sodium-ion Batteries

2021 ◽  
Author(s):  
Jiefei Liu ◽  
Kangshou Lin ◽  
Yu Zhou ◽  
Yu Zhou ◽  
Xianhua Hou ◽  
...  
Keyword(s):  
Energy Density ◽  
High Energy ◽  
Ionic Conductor ◽  
Sodium Ion ◽  
High Energy Density ◽  
Sodium Ion Batteries ◽  
Nasicon Structure

The sodium super ionic conductor (NASICON) materials are considered as the attractive cathode in sodium-ion batteries. Although the three-electron reactions in Na3MnTi(PO4)3 have greatly enhanced the capacity of NASICON-structure materials,...

NMR study of one-dimensional ionic conductor with hollandite-type structure iv) Rb-priderite

1986 ◽  
Vol 18-19 ◽  
pp. 878-882 ◽  
Author(s):  
Y ONODA ◽  
Y FUJIKI ◽  
S YOSHIKADO ◽  
T OHACHI ◽  
I TANIGUCHI
Keyword(s):  
Ionic Conductor ◽  
Type Structure ◽  
One Dimensional ◽  
Nmr Study

On the Role of High-Order Multiple Scattering Terms in Br K-Edge XANES of the Ionic Conductor AgBr

1993 ◽  
Vol 176 (2) ◽  
pp. 503-510 ◽  
Author(s):  
A. V. Soldatov ◽  
T. S. Ivanchenko ◽  
S. Della Longa ◽  
A. Bianconi
Keyword(s):  
Multiple Scattering ◽  
High Order ◽  
Ionic Conductor
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