Recent contributions of kolbe electrolysis to organic synthesis

Electrochemistry IV - Topics in Current Chemistry ◽

10.1007/bfb0034365 ◽

2005 ◽

pp. 91-151 ◽

Cited By ~ 124

Author(s):

Hans-Jürgen Schäfer

Keyword(s):

Organic Synthesis ◽

Kolbe Electrolysis

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Organic synthesis via Kolbe and related non-Kolbe electrolysis: Enabling electro-strategy

Reaction Chemistry & Engineering ◽

10.1039/d1re00047k ◽

2021 ◽

Author(s):

Najwa Sbei ◽

Samina Aslam ◽

Nisar Ahmed

Keyword(s):

Organic Synthesis ◽

Value Added ◽

Environmentally Friendly ◽

Organic Transformations ◽

Synthetic Methodology ◽

Kolbe Electrolysis ◽

Conventional Methods

Enabling and environmentally friendly synthetic methodology is preferred over conventional methods that require expensive chemicals & oxidants to achieve value-added organic transformations. Electrochemical conversions encounter the conventional shortcomings and introduce...

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Solvent Control in Electro-Organic Synthesis

Synlett ◽

10.1055/s-0037-1610303 ◽

2018 ◽

Vol 30 (03) ◽

pp. 275-286 ◽

Cited By ~ 21

Author(s):

Lara Schulz ◽

Siegfried Waldvogel

Keyword(s):

Organic Synthesis ◽

Solvent Effects ◽

Coupling Reactions ◽

Dehydrogenative Coupling ◽

Solvent Control ◽

Kolbe Electrolysis ◽

Fluorinated Solvents

Exploiting the solvent control within electro-organic conversions is a far underestimated parameter in prep-scale electrolysis. The beneficial application in several transformations is outlined and in particular discussed for the dehydrogenative coupling of arenes and heteroarenes. This simple electrolytic strategy in fluorinated solvents allows the modulation of the substrate’s nucleophilicity and the stabilization of the intermediates as well as of the final product from over-oxidation.1 Introduction2 Solvent Effects in Kolbe Electrolysis and Anodic Fluorination3 Unique Solvent Effects of 1,1,1,3,3,3-Hexafluoropropan-2-ol (HFIP)4 Anodic Dehydrogenative Coupling Reactions with Use of HFIP as the Solvent5 Conclusion

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