Electron count versus structural arrangement in clusters based on a cubic transition metal core with bridging main group elements

2005 ◽  
pp. 81-109 ◽  
Author(s):  
Jean-François Halet ◽  
Jean-Yves Saillard
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Metal Core ◽  
Main Group Elements ◽  
Structural Arrangement

Transition metal carbon quadruple bond: viability through single electron transmutation

2020 ◽  
Vol 22 (42) ◽  
pp. 24178-24180
Author(s):  
Amlan J. Kalita ◽  
Shahnaz S. Rohman ◽  
Chayanika Kashyap ◽  
Sabnam S. Ullah ◽  
Ankur K. Guha
Keyword(s):  
Transition Metal ◽  
Main Group ◽  
Single Electron ◽  
Main Group Elements ◽  
Quadruple Bond

Quadruple bonding to main group elements is extremely rare although they have four valence orbitals accessible for bonding.

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