The mechanism of sulphur transfer between carbon-saturated iron and CaO-SiO2-Al2O3 slags

JOM ◽  
1950 ◽  
Vol 2 (9) ◽  
pp. 1111-1119 ◽  
Author(s):  
G. Derge ◽  
W. O. Philbrook ◽  
Kenneth M. Goldman
Keyword(s):  
Carbon Saturated Iron

scholarly journals Kinetics of the reaction of SiO(g) with carbon saturated iron

1985 ◽  
Vol 16 (4) ◽  
pp. 857-857
Author(s):  
B. Ozturk ◽  
R. J. Fruehan
Keyword(s):  
Kinetics Of ◽  
Carbon Saturated Iron

scholarly journals Distribution Ratio of Sulfur between CaO-SiO2-Al2O3-Na2O-TiO2 Slag and Carbon-Saturated Iron

Metals ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1068 ◽  
Author(s):  
Kanghui Zhang ◽  
Yanling Zhang ◽  
Tuo Wu
Keyword(s):  
Experimental Data ◽  
Distribution Ratio ◽  
Hot Metal ◽  
Tio2 Content ◽  
Na2o Content ◽  
Sulfur Distribution ◽  
Reducing Conditions ◽  
Hot Metal Desulfurization ◽  
Sulfur Distribution Ratio ◽  
Carbon Saturated Iron

To explore the feasibility of hot metal desulfurization using red mud, the sulfur distribution ratio (LS) between CaO-SiO2-Al2O3-Na2O-TiO2 slag and carbon-saturated iron is evaluated in this paper. First, the theoretical liquid areas of the CaO-SiO2-Al2O3 (-Na2O-TiO2) slag are discussed and the fluxing effects of Al2O3, Na2O, and TiO2 are confirmed. Then, LS is measured via slag-metal equilibrium experiments. The experimental results show that LS significantly increases with the increase of temperature, basicity, and Na2O content, whereas it decreases with the increase of Al2O3 and TiO2 content. Na2O in the slag will volatilize with high temperatures and reducing conditions. Furthermore, based on experimental data for the sulfur distribution ratio between CaO-SiO2-Al2O3-Na2O-TiO2 slag and the carbon-saturated iron, the following fitting formula is obtained: log L S = 45.584 Λ + 10568.406 − 17184.041 Λ T − 8.529

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