X-ray satellite line structure of ferrite for CrK radiation

JOM ◽  
1957 ◽  
Vol 9 (1) ◽  
pp. 41-43
Author(s):  
V. Weiss ◽  
E. P. Klier
Keyword(s):  
X Ray ◽  
1993 ◽  
Vol 70-71 ◽  
pp. 35-39 ◽  
Author(s):  
C. Klauber
Keyword(s):  
X Ray ◽  

1964 ◽  
Vol 8 ◽  
pp. 371-383 ◽  
Author(s):  
William L. Baun ◽  
David W. Fischer

AbstractWavelengths and intensities are reported for the K series of magnesium, aluminum, and silicon, using primary excitation. Included in the tabulation for magnesium and aluminum are the diagram lines α1α2 and β and the nondiagram lines α', α3, α4, α5, and α6. Data are given for the Si K spectral lines α1α2, β, α3, and α4, Spectra are shown and line positions and intensities are detailed using both metal and oxide as the X-ray source. Significant differences are seen between metal and oxide spectra especially in wavelength and shape of Kβ, and large changes are noted in the intensities of some satellite lines. Spectra from a number of aluminum intermetallic compounds are discussed, including line positions, satellite line ratios, and line shape. It is shown that the spectra fall into three predictable groups; good conductors; poorer conductors; and semiconductors and insulators. Structurally similar compounds give similar spectra. For instance, line positions, shapes, and intensities are nearly identical for NbAl3 and TaAl3. It is not possible to correlate spectra with aluminum coordination number, and previous work using Kα, where secondary excitation was used, could not be reproduced using primary excitation. Possible reasons for this disagreement are discussed.


2009 ◽  
Vol 42 (8) ◽  
pp. 085701 ◽  
Author(s):  
P Hakel ◽  
R C Mancini ◽  
J Abdallah ◽  
M E Sherrill ◽  
H L Zhang

2001 ◽  
Vol 72 (1) ◽  
pp. 1245-1247 ◽  
Author(s):  
Peter Hakel ◽  
Roberto C. Mancini ◽  
Jean-Claude Gauthier ◽  
Emilio Mı́nguez ◽  
Jacques Dubau ◽  
...  

1966 ◽  
Vol 10 ◽  
pp. 374-389 ◽  
Author(s):  
David W. Fischer ◽  
William L. Baun

AbstractThe aluminum K X-ray emission lines and bands from a series of aluminum binary alloys and other binary compounds were investigated using 6 kV electron excitation and a flat crystal vacuum spectrometer. The overall shape of the emission band and its energy position as a function of alloy composition was determined. It appears from the data that the aluminum K band undergoes changes in shape and energy position which are dependent on the electronic configuration of the element with which the aluminum is chemically bonded. These band changes can be interpreted as indicating a change in the bonding character between the metal atoms. In the Al-Ni system, for instance, the Al K band becomes more symmetrical and shifts to lower energy as the nickel content is increased, indicating that perhaps the bonding on the aluminum atoms is becoming less metallic and more covalent in nature as the nickel to aluminum ratio is increased.The aluminum Kα4/Kα3 satellite line intensity ratio also varies in an orderly manner in aluminum binary compounds. In general, these satellite line changes go hand-in-hand with the K band changes. If the K band shifts to lower energy, the Kα4/Kα3 intensity ratio will always increase in value.


2019 ◽  
Vol 75 (3) ◽  
pp. 527-540 ◽  
Author(s):  
Hamish A. Melia ◽  
Christopher T. Chantler ◽  
Lucas F. Smale ◽  
Alexis J. Illig

A characterization of the Cu Kα1,2 spectrum is presented, including the 2p satellite line, Kα3,4, the details of which are robust enough to be transferable to other experiments. This is a step in the renewed attempts to resolve inconsistencies in characteristic X-ray spectra between theory, experiment and alternative experimental geometries. The spectrum was measured using a rotating anode, monolithic Si channel-cut double-crystal monochromator and backgammon detector. Three alternative approaches fitted five Voigt profiles to the data: a residual analysis approach; a peak-by-peak fit; and a simultaneous constrained method. The robustness of the fit is displayed across three spectra obtained with different instrumental broadening. Spectra were not well fitted by transfer of any of three prior characterizations from the literature. Integrated intensities, line widths and centroids are compared with previous empirical fits. The novel experimental setup provides insight into the portability of spectral characterizations of X-ray spectra. From the parameterization, an estimated 3d shake probability of 18% and a 2p shake probability of 0.5% are reported.


2017 ◽  
Vol 840 (2) ◽  
pp. 120 ◽  
Author(s):  
K. D. Murphy ◽  
M. A. Nowak ◽  
H. L. Marshall
Keyword(s):  
X Ray ◽  

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