Polarographic study of the kinetics of oxidation of allyl alcohol by chloramine-T

1978 ◽  
Vol 87 (6) ◽  
pp. 215-217
Author(s):  
K Ganapathy ◽  
B Vijayan
Keyword(s):  
Allyl Alcohol ◽  
Polarographic Study ◽  
Kinetics Of Oxidation ◽  
Chloramine T ◽  
Kinetics Of

scholarly journals Kinetics of oxidation of allyl alcohol by chloramine-T in hydrochloric acid medium: effect of high acid concentrations

1975 ◽  
Vol 28 (4) ◽  
pp. 899 ◽  
Author(s):  
DS Mahadevappa ◽  
HMK Naidu
Keyword(s):  
Hydrochloric Acid ◽  
Allyl Alcohol ◽  
Alcohol Concentration ◽  
Medium Effect ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Hydrochloric Acid Medium ◽  
Entropy Of Activation ◽  
Chloramine T ◽  
Kinetics Of

The kinetics of oxidation of allyl alcohol by chloramine-T in presence of hydrochloric acid(0.15-0.29M) has been studied. At 0�C the rate is first order with respect to chloramine-T, second order in [H+] and independent of the alcohol concentration. The energy of activation and entropy of activation of the reaction have been found to be 55.6 kJ mol -1 and -153 J K-1 respectively. A mechanism is proposed.

Kinetics of oxidation of amino acids by chloramine T. A reinvestigation

1985 ◽  
pp. 1507 ◽  
Author(s):  
M. Shanmugam Ramachandran ◽  
T. Subburamiyer Vivekanandam ◽  
Rajarathinam Nithyanandhan
Keyword(s):  
Amino Acids ◽  
Kinetics Of Oxidation ◽  
Chloramine T ◽  
Kinetics Of
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