Fourth-order zero-field splitting parameters of [Mn(cyclam)Br2]Br determined by single-crystal W-band EPR

S. Mossin; M. Stefan; P. ter Heerdt; A. Bouwen; E. Goovaerts; H. Weihe

doi:10.1007/bf03162431

Fourth-order zero-field splitting parameters of [Mn(cyclam)Br2]Br determined by single-crystal W-band EPR

Applied Magnetic Resonance ◽

10.1007/bf03162431 ◽

2001 ◽

Vol 21 (3-4) ◽

pp. 587-596 ◽

Cited By ~ 17

Author(s):

S. Mossin ◽

M. Stefan ◽

P. ter Heerdt ◽

A. Bouwen ◽

E. Goovaerts ◽

...

Keyword(s):

Single Crystal ◽

Fourth Order ◽

Zero Field ◽

Zero Field Splitting ◽

Order Zero ◽

Field Splitting ◽

W Band

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NMR paramagnetic relaxation due to the S=5∕2 complex, Fe(III)-(tetra-p-sulfonatophenyl)porphyrin: Central role of the tetragonal fourth-order zero-field splitting interaction

The Journal of Chemical Physics ◽

10.1063/1.1886748 ◽

2005 ◽

Vol 122 (18) ◽

pp. 184501 ◽

Cited By ~ 9

Author(s):

Nathaniel Schaefle ◽

Robert Sharp

Keyword(s):

Fourth Order ◽

Paramagnetic Relaxation ◽

Zero Field ◽

Zero Field Splitting ◽

Order Zero ◽

Field Splitting

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Importance of Fourth-Order Zero-Field Splitting Terms in Random-Orientation EPR Spectra of Eu(II)-Doped Strontium Aluminate

The Journal of Physical Chemistry A ◽

10.1021/jp030819+ ◽

2003 ◽

Vol 107 (51) ◽

pp. 11539-11546 ◽

Cited By ~ 6

Author(s):

Hideto Matsuoka ◽

Ko Furukawa ◽

Kazunobu Sato ◽

Daisuke Shiomi ◽

Yoshitane Kojima ◽

...

Keyword(s):

Fourth Order ◽

Epr Spectra ◽

Zero Field ◽

Strontium Aluminate ◽

Zero Field Splitting ◽

Random Orientation ◽

Order Zero ◽

Field Splitting

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The mechanism of paramagnetic NMR relaxation produced by Mn(II): Role of orthorhombic and fourth-order zero field splitting terms

The Journal of Chemical Physics ◽

10.1063/1.2981565 ◽

2008 ◽

Vol 129 (14) ◽

pp. 144307 ◽

Cited By ~ 1

Author(s):

Robert Sharp

Keyword(s):

Fourth Order ◽

Nmr Relaxation ◽

Paramagnetic Nmr ◽

Zero Field ◽

Zero Field Splitting ◽

Order Zero ◽

Field Splitting

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Single-ion and molecular contributions to the zero-field splitting in an iron(III)-oxo dimer studied by single crystal W-band EPR

Journal of Magnetic Resonance ◽

10.1016/j.jmr.2005.10.016 ◽

2006 ◽

Vol 179 (1) ◽

pp. 29-37 ◽

Cited By ~ 22

Author(s):

Peter ter Heerdt ◽

Mariana Stefan ◽

Etienne Goovaerts ◽

Andrea Caneschi ◽

Andrea Cornia

Keyword(s):

Single Crystal ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

W Band

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Zero-field splitting of Cr3+ in an electro-optical α-LiIO3 single crystal

Solid State Communications ◽

10.1016/s0038-1098(97)00021-5 ◽

1997 ◽

Vol 102 (6) ◽

pp. 467-471 ◽

Cited By ~ 6

Author(s):

Kee Tae Han ◽

Jongmin Kim

Keyword(s):

Single Crystal ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Gd3+EPR study of structural phase transition in NH4La(SO)2.4H2O single crystal: a superposition-model calculation of zero-field splitting parameters

Journal of Physics Condensed Matter ◽

10.1088/0953-8984/2/48/014 ◽

1990 ◽

Vol 2 (48) ◽

pp. 9613-9620 ◽

Cited By ~ 6

Author(s):

S K Misra ◽

Xiaochuan Li

Keyword(s):

Phase Transition ◽

Single Crystal ◽

Model Calculation ◽

Structural Phase Transition ◽

Structural Phase ◽

Zero Field ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting

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DETERMINATION OF PRINCIPAL AXES OF ZERO-FIELD SPLITTING TENSOR BY SINGLE CRYSTAL EPR STUDY

Acta Physica Sinica ◽

10.7498/aps.38.317 ◽

1989 ◽

Vol 38 (2) ◽

pp. 317

Author(s):

HAN SHI-YING

Keyword(s):

Single Crystal ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Principal Axes

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Gd3+ EPR study of phase transitions in A NH4Nd(SO4)2·4H2O single crystal and superposition-model calculation of the zero-field splitting parameters

Physica B Condensed Matter ◽

10.1016/0921-4526(90)90353-v ◽

1990 ◽

Vol 167 (3) ◽

pp. 209-219 ◽

Cited By ~ 8

Author(s):

Sushil K. Misra ◽

Xiaochuan Li ◽

Lucjan E. Misiak ◽

Changlu Wang

Keyword(s):

Phase Transitions ◽

Single Crystal ◽

Model Calculation ◽

Zero Field ◽

Superposition Model ◽

Zero Field Splitting ◽

Field Splitting

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Single crystal EPR studies on Mn(II)-doped sarcosine cadmium chloride and sarcosine cadmium bromide: Study of zero-field splitting tensor in iso-structural complexes

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy ◽

10.1016/s1386-1425(01)00549-2 ◽

2002 ◽

Vol 58 (3) ◽

pp. 509-517 ◽

Cited By ~ 7

Author(s):

D. Pathinettam Padiyan ◽

C. Muthukrishnan ◽

R. Murugesan

Keyword(s):

Single Crystal ◽

Cadmium Chloride ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Cadmium Bromide

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SUPERPOSITION MODEL ANALYSIS FOR THE ZERO-FIELD SPLITTING OFMn2+IN SOME CRYSTALS

Modern Physics Letters B ◽

10.1142/s0217984906012250 ◽

2006 ◽

Vol 20 (30) ◽

pp. 1917-1922 ◽

Cited By ~ 2

Author(s):

VIMAL KUMAR JAIN

Keyword(s):

Lattice Relaxation ◽

Zero Field ◽

Superposition Model ◽

Zero Field Splitting ◽

Intrinsic Parameter ◽

Order Zero ◽

Field Splitting ◽

Zero Field Splitting Parameter ◽

Local Lattice ◽

Splitting Parameter

The Newman superposition model has been applied to second-order zero-field splitting parameter [Formula: see text] taken from the literature for Mn2+in Hg(ClO4)2· 6 H2O , M ″ SiF6·6 H2O (M ″= Fe, Co, Zn ) and M ″ NbOF5·6 H2O (M ″= Co, Zn ). In the calculations, the local lattice relaxation has been taken into account. It is shown that nearly the same value of intrinsic parameter b2=-0.057(8) cm-1is obtained.

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