Single-crystal EPR studies of transition-metal ions in inorganic crystals at very high frequency

2001 ◽  
Vol 21 (3-4) ◽  
pp. 549-561 ◽  
Author(s):  
S. K. Misra ◽  
S. I. Andronenko ◽  
K. A. Earle ◽  
J. H. Freed
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Single Crystal ◽  
High Frequency ◽  
Transition Metal Ions ◽  
Very High Frequency ◽  
Inorganic Crystals ◽  
Very High

Diffusion of Transition Metal Ions in Single‐Crystal MgO

1962 ◽  
Vol 36 (11) ◽  
pp. 2917-2922 ◽  
Author(s):  
B. J. Wuensch ◽  
T. Vasilos
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Single Crystal ◽  
Transition Metal Ions

scholarly journals Dithiacrown Ether Substituted Porphyrazines:  Synthesis, Single-Crystal Structure, and Control of Aggregation in Solution by Complexation of Transition-Metal Ions

1996 ◽  
Vol 35 (4) ◽  
pp. 959-969 ◽  
Author(s):  
Cornelus F. van Nostrum ◽  
Franciscus B. G. Benneker ◽  
Hugo Brussaard ◽  
Huub Kooijman ◽  
Nora Veldman ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Ions ◽  
Single Crystal ◽  
Transition Metal Ions ◽  
Single Crystal Structure ◽  
And Control

Reactions of sodium N,N-diethyldithiocarbamate with some organic solvents

1970 ◽  
Vol 48 (24) ◽  
pp. 3827-3830 ◽  
Author(s):  
P. R. Heckley ◽  
D. G. Holah ◽  
A. N. Hughes ◽  
F. Leh
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Organic Solvents ◽  
Methylene Chloride ◽  
Transition Metal Ions ◽  
High Yield ◽  
Proton Abstraction ◽  
Partial Decomposition ◽  
Diethyldithiocarbamic Acid ◽  
Very High

Sodium N,N-diethyldithiocarbamate reacts smoothly with methylene chloride (even in the presence of various transition metal ions) to give the dithiocarbamate ester Et2NC(S)SCH2S(S)CNEt2 in very high yield. With chloroform and acetonitrile, proton abstraction occurs followed by partial decomposition of the N,N-diethyldithiocarbamic acid so formed to give diethylammonium N,N-diethyldithiocarbamate.

High‐Speed Organic Single‐Crystal Transistor Responding to Very High Frequency Band

2020 ◽  
Vol 30 (11) ◽  
pp. 1909501 ◽  
Author(s):  
Akifumi Yamamura ◽  
Takaaki Sakon ◽  
Kayo Takahira ◽  
Takahiro Wakimoto ◽  
Mari Sasaki ◽  
...  
Keyword(s):  
Single Crystal ◽  
Frequency Band ◽  
High Frequency ◽  
High Speed ◽  
High Frequency Band ◽  
Very High Frequency ◽  
Organic Single Crystal ◽  
Very High

HREM Study of electron-induced surface radiation damage in ReO3

1991 ◽  
Vol 49 ◽  
pp. 636-637
Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Oxides ◽  
Electron Irradiation ◽  
Transition Metal Oxides ◽  
Carbon Film ◽  
Transition Metal Ions ◽  
Surface Radiation ◽  
Valence Transition ◽  
Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

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