Kinetics of the reaction between benzyl chloride and formic acid

1938 ◽  
Vol 7 (6) ◽  
pp. 411-415
Author(s):  
L. S. Heble ◽  
T. S. Wheeler
Keyword(s):  
Formic Acid ◽  
Benzyl Chloride ◽  
Kinetics Of

Kinetics of the permanganate oxidation of formic acid in aqueous solution

1987 ◽  
Vol 19 (8) ◽  
pp. 741-755 ◽  
Author(s):  
Isidro S. Monzó ◽  
Juan Palou ◽  
Joaquín Peñalver ◽  
Rosa Valero
Keyword(s):  
Aqueous Solution ◽  
Formic Acid ◽  
Permanganate Oxidation ◽  
Kinetics Of

THE KINETICS OF THE OXIDATION OF GASEOUS ACETALDEHYDE

1932 ◽  
Vol 7 (2) ◽  
pp. 149-161 ◽  
Author(s):  
W. H. Hatcher ◽  
E. W. R. Steacie ◽  
Frances Howland
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Induction Period ◽  
Reaction Vessel ◽  
Oxidation Products ◽  
Main Reaction ◽  
Chain Mechanism ◽  
Subsequent Reaction ◽  
A Chain ◽  
Kinetics Of

The kinetics of the oxidation of gaseous acetaldehyde have been investigated from 60° to 120 °C. by observing the rate of pressure decrease in a system at constant volume. A considerable induction period exists, during which the main products of the reaction are carbon dioxide, water, and formic acid. The main reaction in the subsequent stages involves the formation of peroxides and their oxidation products. The heat of activation of the reaction is 8700 calories per gram molecule. The indications are that the reactions occurring during the induction period are heterogeneous. The subsequent reaction occurs by a chain mechanism. The chains are initiated at the walls of the reaction vessel, and are also largely broken at the walls.

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