Predictive character of solid state chemistry: Relation between structure, chemical bonding and physical properties of solids

1983 ◽  
Vol 92 (1) ◽  
pp. 1-26
Author(s):  
P Hagenmuller
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Chemical Bonding ◽  
Solid State Chemistry

scholarly journals Thermochemical electronegativities of the elements

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Christian Tantardini ◽  
Artem R. Oganov
Keyword(s):  
Solid State ◽  
Chemical Bonding ◽  
Structural Chemistry ◽  
Solid State Chemistry ◽  
Structure And Properties ◽  
Bond Energies ◽  
Dimensionless Numbers ◽  
Bond Polarity ◽  
Stability Structure ◽  
Definition Of

AbstractElectronegativity is a key property of the elements. Being useful in rationalizing stability, structure and properties of molecules and solids, it has shaped much of the thinking in the fields of structural chemistry and solid state chemistry and physics. There are many definitions of electronegativity, which can be roughly classified as either spectroscopic (these are defined for isolated atoms) or thermochemical (characterizing bond energies and heats of formation of compounds). The most widely used is the thermochemical Pauling’s scale, where electronegativities have units of eV−1/2. Here we identify drawbacks in the definition of Pauling’s electronegativity scale—and, correcting them, arrive at our thermochemical scale, where electronegativities are dimensionless numbers. Our scale displays intuitively correct trends for the 118 elements and leads to an improved description of chemical bonding (e.g., bond polarity) and thermochemistry.

scholarly journals Bonding diversity in rock salt-type tellurides: examining the interdependence between chemical bonding and materials properties

RSC Advances ◽  
2021 ◽  
Vol 11 (34) ◽  
pp. 20679-20686
Author(s):  
Jasmin Simons ◽  
Jan Hempelmann ◽  
Kai S. Fries ◽  
Peter C. Müller ◽  
Richard Dronskowski ◽  
...  
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Rock Salt ◽  
Chemical Bonding ◽  
Electronic Structures ◽  
Proper Understanding ◽  
Materials Properties ◽  
Solid State Materials ◽  
Future Technologies

Future technologies are in need of solid-state materials showing the desired chemical and physical properties, and designing such materials requires a proper understanding of their electronic structures.

Stacking disorder in Mo1+xV2−xO8 phase (). Solid state chemistry—X-rays–TEM—physical properties

2005 ◽  
Vol 7 (6) ◽  
pp. 726-734 ◽  
Author(s):  
J. Galy ◽  
F. Duc ◽  
G. Svensson ◽  
P. Baules ◽  
P. Rozier ◽  
...  
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Solid State Chemistry ◽  
X Rays ◽  
Stacking Disorder

A3Mn2Sb3S8 (A = K, Rb): A new type of multifunctional infrared nonlinear optical materials based on unique three-dimensional open frameworks

2021 ◽  
Author(s):  
Yu Xiao ◽  
Man-Man Chen ◽  
Yaying Shen ◽  
Peng-Fei Liu ◽  
Hua Lin ◽  
...  
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Optical Materials ◽  
Nonlinear Optical ◽  
Three Dimensional ◽  
Inorganic Materials ◽  
Considerable Progress ◽  
Nonlinear Optical Materials ◽  
Solid State Chemistry ◽  
New Type

Exploring inorganic materials with two or more different physical properties has become an important and emerging topic in solid-state chemistry. Despite considerable progress achieved recently, however, multifunctional infrared nonlinear-optical (IR-NLO)...

Solid State Chemistry

1968 ◽  
Vol 58 (5_6) ◽  
pp. 331-332
Author(s):  
K. Hauffe
Keyword(s):  
Solid State ◽  
Solid State Chemistry

Improved Sol-Gel Materials for Efficient Solid State Dye Lasers

1993 ◽  
Vol 329 ◽  
Author(s):  
Michael Canva ◽  
Patrick Georges ◽  
Jean-Fran^ois Perelgritz ◽  
Alain Brun ◽  
Fréddric Chaput ◽  
...  
Keyword(s):  
Solid State ◽  
Physical Properties ◽  
Room Temperature ◽  
Sol Gel ◽  
Tunable Lasers ◽  
Optical Quality ◽  
Dye Lasers ◽  
Laser Dyes ◽  
Host Matrix ◽  
Host Matrices

AbstractPhotoresistant laser dyes were trapped in silica based xerogel host matrices to obtain solid state tunable lasers. For this purpose very dense xerogel samples with improved chemical and physical properties were prepared at room temperature by the sol-gel technology. The as-prepared materials were polished to obtain optical quality surfaces and were used as new lasing media.Lasing action of such different dyes as rhodamine, perylene and pyrromethene doping dense sol-gel matrices was demonstrated. Efficiencies of 30 % or lifetimes of more than 100,000 shots were achieved with different new ≤dye dopant/host matrix≥ couples. Their different performances are reviewed and discussed.

Sign in / Sign up

Export Citation Format

Share Document