The study of chemical exchange reactions by nuclear magnetic resonance

S. Meiboom

doi:10.1007/bf02834721

[15] Applicability of magnetization transfer nuclear magnetic resonance to study chemical exchange reactions

Methods in Enzymology - Nuclear Magnetic Resonance Part A: Spectral Techniques and Dynamics ◽

10.1016/0076-6879(89)76017-1 ◽

1989 ◽

pp. 311-329 ◽

Cited By ~ 24

Author(s):

Jens J. Led ◽

Henrik Gesmar ◽

Frits Abildgaard

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Chemical Exchange ◽

Magnetization Transfer ◽

Exchange Reactions ◽

Nuclear Magnetic

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Chemical exchange at the ferroelectric phase transition of lead germanate revealed by solid state 207Pb nuclear magnetic resonance

Physical Chemistry Chemical Physics ◽

10.1039/c8cp06507a ◽

2019 ◽

Vol 21 (3) ◽

pp. 1100-1109 ◽

Cited By ~ 3

Author(s):

Claudia E. Avalos ◽

Brennan J. Walder ◽

Jasmine Viger-Gravel ◽

Arnaud Magrez ◽

Lyndon Emsley

Keyword(s):

Phase Transition ◽

Nuclear Magnetic Resonance ◽

Solid State ◽

Magnetic Resonance ◽

Ferroelectric Phase Transition ◽

Ferroelectric Phase ◽

Chemical Exchange ◽

Lead Germanate ◽

Mixed Order ◽

Nuclear Magnetic

Multi-dimensional NMR is used to quantitatively identify a mixed order–disorder and displacive mechanism for the ferroelectric phase transition of lead germanate.

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Resonance line broadening due to chemical exchange and quadrupole-induced relaxation in the nuclear magnetic resonance spectra of some boron–nitrogen adducts

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9730002139 ◽

1973 ◽

pp. 2139-2143 ◽

Cited By ~ 7

Author(s):

J. Richard Blackborow

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Resonance Line ◽

Chemical Exchange ◽

Line Broadening ◽

Nuclear Magnetic Resonance Spectra ◽

Boron Nitrogen ◽

Magnetic Resonance Spectra ◽

Nuclear Magnetic

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Nucleophilic substitution at bivalent sulphur. Part V. A study of exchange reactions at bivalent sulphur using 19F nuclear magnetic resonance spectroscopy

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29740001040 ◽

1974 ◽

pp. 1040 ◽

Cited By ~ 1

Author(s):

Donald R. Hogg ◽

Joseph Stewart

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Magnetic Resonance Spectroscopy ◽

Nucleophilic Substitution ◽

Nuclear Magnetic Resonance Spectroscopy ◽

Resonance Spectroscopy ◽

Exchange Reactions ◽

Nuclear Magnetic

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ChemInform Abstract: NUCLEOPHILIC SUBSTITUTION AT BIVALENT SULPHUR PART 5, A STUDY OF EXCHANGE REACTIONS AT BIVALENT SULPHUR USING (19)F NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY

Chemischer Informationsdienst ◽

10.1002/chin.197441118 ◽

1974 ◽

Vol 5 (41) ◽

pp. no-no

Author(s):

DONALD R. HOGG ◽

JOSEPH STEWART

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Magnetic Resonance Spectroscopy ◽

Nucleophilic Substitution ◽

Nuclear Magnetic Resonance Spectroscopy ◽

Resonance Spectroscopy ◽

Exchange Reactions ◽

Nuclear Magnetic

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Two-dimensional silicon-29 nuclear magnetic resonance spectroscopic study of chemical exchange pathways in potassium silicate solutions

Journal of Magnetic Resonance (1969) ◽

10.1016/0022-2364(88)90154-0 ◽

1988 ◽

Vol 78 (1) ◽

pp. 31-40 ◽

Cited By ~ 2

Author(s):

C.T.G Knight ◽

R.J Kirkpatrick ◽

Eric Oldfield

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Spectroscopic Study ◽

Chemical Exchange ◽

Potassium Silicate ◽

Two Dimensional ◽

Nuclear Magnetic

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Application of 11B nuclear magnetic resonance spectroscopy to the study of hydroboration—III. 11B Nuclear magnetic resonance study of exchange reactions of triorganyl boranes with borane in tetrahydrofurane and dimethyl sulfide

Spectrochimica Acta Part A Molecular Spectroscopy ◽

10.1016/0584-8539(82)80119-0 ◽

1982 ◽

Vol 38 (8) ◽

pp. 941-951 ◽

Cited By ~ 14

Author(s):

Rosalinda Contreras ◽

Bernd Wrackmeyer

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Magnetic Resonance Spectroscopy ◽

Nuclear Magnetic Resonance Spectroscopy ◽

Dimethyl Sulfide ◽

Nuclear Magnetic Resonance Study ◽

Resonance Spectroscopy ◽

Exchange Reactions ◽

Magnetic Resonance Study ◽

Nuclear Magnetic

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Nuclear Magnetic Resonance Methods for Determining Chemical-Exchange Rates1

Journal of the American Chemical Society ◽

10.1021/ja00966a001 ◽

1966 ◽

Vol 88 (14) ◽

pp. 3185-3194 ◽

Cited By ~ 266

Author(s):

Adam Allerhand ◽

H. S. Gutowsky ◽

J. Jonas ◽

R. A. Meinzer

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Chemical Exchange ◽

Nuclear Magnetic

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Nuclear magnetic resonance studies of multi-site chemical exchange. I. Matrix formulation of the Bloch equations

Canadian Journal of Chemistry ◽

10.1139/v70-612 ◽

1970 ◽

Vol 48 (23) ◽

pp. 3641-3653 ◽

Cited By ~ 60

Author(s):

L. W. Reeves ◽

K. N. Shaw

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Chemical Exchange ◽

Relaxation Times ◽

Bloch Equations ◽

Matrix Formulation ◽

Exchange Processes ◽

Site Exchange ◽

Saturation Effects ◽

Nuclear Magnetic

A concise matrix formulation of chemical exchange effects on a nuclear magnetic resonance (n.m.r.) spectrum using the Bloch equations is described. The method accommodates many-site exchange processes, site-dependent relaxation times, differing site populations, and saturation effects in a steady-state first-order spectrum. The simple two-site exchange system is analyzed in detail and saturation effects in this system are studied numerically. Alternative forms of the basic lineshape equation are derived, all of which are readily adapted to efficient computer calculations for complete lineshape fitting to obtain kinetic data for complicated chemical exchange processes.

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