scholarly journals Epoxidation and oxidation reactions using 1,4-butanediol dimethacrylate crosslinked polystyrene-supported tertiary butyl hydroperoxide

2004 ◽  
Vol 116 (6) ◽  
pp. 319-324 ◽  
Author(s):  
M. S. Sheela ◽  
K. Sreekumar
1961 ◽  
Vol 39 (7) ◽  
pp. 1424-1433 ◽  
Author(s):  
K. M. Bell ◽  
C. A. McDowell

The mercury-photosensitized oxidation of isobutane has been studied over a wide range of pressures of the hydrocarbon and oxygen, in a conventional static photochemical apparatus at the temperatures of 30 °C and 100 °C. The main products of the reaction are tertiary butyl hydroperoxide, together with tertiary butyl alcohol, acetone, and corresponding small quantities of formaldehyde and methyl alcohol. Isobutyraldehyde was also detected; ditertiary butyl peroxide being notably absent. Peroxide yields suggest that a reaction between an excited isobutane molecule and oxygen is important in the initiation processes and that peroxide is formed in the reaction[Formula: see text]


Andrologia ◽  
2012 ◽  
Vol 45 (4) ◽  
pp. 232-239 ◽  
Author(s):  
N. Fatemi ◽  
M. H. Sanati ◽  
M. Jamali Zavarehei ◽  
H. Ayat ◽  
V. Esmaeili ◽  
...  

1968 ◽  
Vol 46 (13) ◽  
pp. 2329-2331 ◽  
Author(s):  
Maurice Codell ◽  
Henry Gisser ◽  
R. D. Iyengar

The complexity of the electron spin resonance signal, appearing at g = 1.96 on ZnO vacuum outgassed at higher temperatures, has been examined by adsorption of tertiary butyl hydroperoxide (TBHP). Two individual signals with g values 1.961 and 1.965 observed following TBHP adsorption have been attributed to Zn+ ions and oxygen vacancies with trapped electrons.


2002 ◽  
Vol 75 (5) ◽  
pp. 573-582 ◽  
Author(s):  
Abraham Spector ◽  
Wanchao Ma ◽  
Fang Sun ◽  
Dayu Li ◽  
Norman J. Kleiman

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