Kinetics of absorption of hydrogen sulfide into aqueous Fe(III) solutions

1997 ◽  
Vol 14 (5) ◽  
pp. 307-311 ◽  
Author(s):  
Satoru Asai ◽  
Hidemi Nakamura ◽  
Yasuhiro Konishi
2003 ◽  
Vol 58 (2) ◽  
pp. 417-427 ◽  
Author(s):  
S Ebrahimi ◽  
R Kleerebezem ◽  
M.C.M van Loosdrecht ◽  
J.J Heijnen

AIChE Journal ◽  
1990 ◽  
Vol 36 (9) ◽  
pp. 1331-1338 ◽  
Author(s):  
Satoru Asai ◽  
Yasuhiro Konishi ◽  
Tadahiro Yabu

2021 ◽  
Vol 2057 (1) ◽  
pp. 012043
Author(s):  
I A Romanov ◽  
V I Borzenko ◽  
A N Kazakov

Abstract This work is devoted to an experimental study and comparison of the kinetics of hydrogen absorption by an intermetallic compound LaNi4.4Al0.3Fe0.3 in form of pure intermetallic compound free backfill and a compact based on it obtained by cold pressing with a spiral matrix of nickel-foam. To calculate the kinetic parameters of the hydrogen absorption reaction, the initial rates method is used. The PCT absorption isotherms are measured at temperatures of 313, 333, and 353 K. The experimental data are described with quite high confidence by the chosen model, which assumes that the reaction rate controlling step is the dissociative absorption of hydrogen on the surface of the a-phase. The rate of hydrogen absorption increases with increasing pressure drop and temperature. It is shown that the rate of hydrogen absorption by the sample of pure IMC is significantly less dependent on temperature compared to the compact sample. In addition, the reaction rate at temperatures of 313 and 333 K is higher for the free backfill sample, and at 353 K it is higher for the metal hydride compact. The values of the absorption constant and the activation energy of the hydrogen absorption reaction are determined for both samples.


CORROSION ◽  
1958 ◽  
Vol 14 (12) ◽  
pp. 34-38 ◽  
Author(s):  
T. G. OWE BERG

Abstract The reaction mechanisms for the absorption of hydrogen by metals from moist hydrogen gas and dilute acid solutions, for the desorption from metals of dissolved hydrogen in the presence of water and for hydrogen solubility and permeation under those conditions are discussed. Their kinetics are also given. Formulae are derived for rates and equilibria. These are compared with experimental data. The migration of H atoms in the metal is concluded to be associated with zero or nearly zero activation energy. Diffusion is rapid enough to maintain almost uniform distribution of H atoms in the metal during absorption and desorption under ordinary conditions. 3.8.4


AIChE Journal ◽  
1984 ◽  
Vol 30 (6) ◽  
pp. 1021-1025 ◽  
Author(s):  
Pan Zhenglu ◽  
Hung-Shan Weng ◽  
Feng Han-Yu ◽  
J. M. Smith

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