Thermodynamic features of the Cu-ZSM-5 catalyzed NO decomposition reaction

2006 ◽  
Vol 23 (4) ◽  
pp. 547-554 ◽  
Author(s):  
Deuk Ki Lee
2006 ◽  
Vol 7 (1) ◽  
pp. 29-32 ◽  
Author(s):  
Junjiang Zhu ◽  
Zhen Zhao ◽  
Dehai Xiao ◽  
Jing Li ◽  
Xiangguang Yang ◽  
...  

2019 ◽  
Vol 9 (16) ◽  
pp. 4276-4285 ◽  
Author(s):  
Wentao Xu ◽  
Qige Wang ◽  
Kang Peng ◽  
Fengtao Chen ◽  
Xue Han ◽  
...  

The catalytic NO decomposition reaction is a hot research topic.


2007 ◽  
Vol 79 (11) ◽  
pp. 1895-1903 ◽  
Author(s):  
Hanne Falsig ◽  
Thomas Bligaard ◽  
Claus H. Christensen ◽  
Jens K. Nørskov

We establish the full potential energy diagram for the direct NO decomposition reaction over stepped transition-metal surfaces by combining a database of adsorption energies on stepped metal surfaces with known Brønsted-Evans-Polanyi (BEP) relations for the activation barriers of dissociation of diatomic molecules over stepped transition- and noble-metal surfaces. The potential energy diagram directly points to why Pd and Pt are the best direct NO decomposition catalysts among the 3d, 4d, and 5d metals. We analyze the NO decomposition reaction in terms of a Sabatier-Gibbs-type analysis, and we demonstrate that this type of analysis yields results that to within a surprisingly small margin of error are directly proportional to the measured direct NO decomposition over Ru, Rh, Pt, Pd, Ag, and Au. We suggest that Pd, which is a better catalyst than Pt under the employed reaction conditions, is a better catalyst only because it binds O slightly weaker compared to N than the other metals in the study.


1999 ◽  
Vol 1 (4) ◽  
pp. 649-656 ◽  
Author(s):  
Yasushige Kuroda ◽  
Ryotaro Kumashiro ◽  
Takefumi Yoshimoto ◽  
Mahiko Nagao

2009 ◽  
Vol 129 (3-4) ◽  
pp. 259-265 ◽  
Author(s):  
Rodrigo S. da Silveira ◽  
Andréa M. de Oliveira ◽  
Sibele B. C. Pergher ◽  
Victor Teixeira da Silva ◽  
Ione M. Baibich

1986 ◽  
Vol 47 (C7) ◽  
pp. C7-435-C7-440
Author(s):  
G.-K. CHUAH ◽  
N. KRUSE ◽  
G. ABEND ◽  
J. H. BLOCK

1980 ◽  
Vol 45 (6) ◽  
pp. 1780-1784 ◽  
Author(s):  
Atanas Andreev ◽  
Lachezar Prahov ◽  
Dimitar Shopov

The formation of Oxygen paramagnetic adducts of Co(II) containing ion-exchange resins in the presence of adsorbed ethylenediamine has been found. The EPR parameters of a complex of the type Co(III) (en)2O-2 and of O-2 species formed in the presence of Co(en)2+3 have been described. The catalytic properties of Co-ethylenediamine surface complexes with respect to the hydrogen peroxide decomposition reaction have been investigated and a probable mechanism has been suggested.


2019 ◽  
Vol 254 ◽  
pp. 300-311 ◽  
Author(s):  
Anchu Ashok ◽  
Anand Kumar ◽  
Janarthanan Ponraj ◽  
Said A. Mansour ◽  
Faris Tarlochan

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