The kinetics of methyl linoleate emulsion autoxidation in the presence of polyhydroxy compounds

1964 ◽  
Vol 41 (4) ◽  
pp. 331-334 ◽  
Author(s):  
A. F. Mabrouk
Keyword(s):  
Methyl Linoleate ◽  
Polyhydroxy Compounds ◽  
Kinetics Of

The autoxidation of unsaturated lipids in micelles. Synergism of inhibitors vitamins C and E

1983 ◽  
Vol 61 (6) ◽  
pp. 1288-1290 ◽  
Author(s):  
Lawrence Ross Coates Barclay ◽  
Steven Jeffrey Locke ◽  
Joseph Mark MacNeil
Keyword(s):  
Linoleic Acid ◽  
Methyl Linoleate ◽  
Sodium Dodecyl ◽  
Square Root ◽  
Micellar Phase ◽  
Chain Initiation ◽  
Unsaturated Lipids ◽  
Sds Micelles ◽  
Initiator Efficiency ◽  
Kinetics Of

The kinetics of thermally (30 °C) initiated autoxidations of unsaturated lipids, linoleic acid, and methyl linoleate are studied in 0.50 M sodium dodecyl sulfate (SDS) micelles. The rate of chain initiation, R1, was controlled by using known amounts of the thermal initiator, di-tert-butylhyponitrite (DBHN). The initiator efficiency, e, determined by the induction period method with x-tocopherol, was 0.30 for linoleic acid and varied (0.30 to 0.36) for methyl linoleate autoxiation as the concentration of the ester increased. The rate of autoxidation of linoleic acid follows the classical rate law since it is proportional to the substrate concentration and to the square root of chain initiation. The oxidizability of linoleic acid measured in micelles is 4.09 × 10−2 M−1/2 s−1/2. The oxidizability of methyl linoleate varied from 2.37 × 10−2 to 6.92 × 10−2 M−1/2 s−1/2 as the amount of solubilized ester increased. The latter results are indicative of pooling of the ester in the micellar phase. Additions of aqueous solutions of ascorbic acid to α-tocopherol-inhibited micellar autoxidations result in very significant extensions of the efficient inhibition period compared to that obtained with α-tocopherol alone. The mechanism of this synergism is briefly discussed.

Effect of Tocopherols on the Peroxidative Kinetics of Ethyl Eicosapentaenoate and Methyl Linoleate

1992 ◽  
Vol 56 (12) ◽  
pp. 2060-2061 ◽  
Author(s):  
Atsuyoshi Nishina ◽  
Yasuko Sakurai ◽  
Ken-ichi Hashimoto ◽  
Yoshihiro Isoda ◽  
Hideo Inatomi
Keyword(s):  
Methyl Linoleate ◽  
Kinetics Of

Studies on kinetics of catalytic isomerization of methyl linoleate

1985 ◽  
Vol 62 (4) ◽  
pp. 734-738 ◽  
Author(s):  
V. M. Deshpande ◽  
R. G. Gadkari ◽  
D. Mukesh ◽  
C. S. Narasimhan
Keyword(s):  
Methyl Linoleate ◽  
Catalytic Isomerization ◽  
Kinetics Of

scholarly journals Kinetics of Oxidation of Different Depths of Methyl Linoleate in Bulk Phase

2014 ◽  
Vol 20 (2) ◽  
pp. 183-187 ◽  
Author(s):  
Tiezheng Ma ◽  
Takashi Kobayashi ◽  
Shuji Adachi
Keyword(s):  
Methyl Linoleate ◽  
Bulk Phase ◽  
Kinetics Of Oxidation ◽  
Different Depths ◽  
Kinetics Of

Effect of microheterogeneity on the kinetics of oxidation of methyl linoleate in micelles

2016 ◽  
Vol 10 (2) ◽  
pp. 260-262 ◽  
Author(s):  
I. V. Moskalenko ◽  
S. Yu. Petrova ◽  
E. M. Pliss ◽  
A. I. Rusakov ◽  
A. L. Buchachenko
Keyword(s):  
Methyl Linoleate ◽  
Kinetics Of Oxidation ◽  
Kinetics Of

Superoxide radicals in the kinetics of nitroxide-inhibited oxidation of methyl linoleate in micelles

2017 ◽  
Vol 11 (3) ◽  
pp. 400-402 ◽  
Author(s):  
I. V. Tikhonov ◽  
E. M. Pliss ◽  
L. I. Borodin ◽  
V. D. Sen’
Keyword(s):  
Methyl Linoleate ◽  
Superoxide Radicals ◽  
Inhibited Oxidation ◽  
Kinetics Of

scholarly journals Thermal decomposition characteristics and kinetics of methyl linoleate under nitrogen and oxygen atmospheres

2015 ◽  
Vol 12 (3) ◽  
pp. 518-524 ◽  
Author(s):  
Xue-Chun Wang ◽  
Jian-Hua Fang ◽  
Bo-Shui Chen ◽  
Jiu Wang ◽  
Jiang Wu ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Methyl Linoleate ◽  
Kinetics Of
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