Effects of grain boundary chemistry on the intergranular cracking behavior of Ni-16Cr-9Fe in high-temperature water

1992 ◽  
Vol 23 (12) ◽  
pp. 3343-3359 ◽  
Author(s):  
G. S. Was ◽  
J. K. Sung ◽  
T. M. Angeliu
2004 ◽  
Vol 261-263 ◽  
pp. 885-902 ◽  
Author(s):  
G.S. Was ◽  
B. Alexandreanu ◽  
J. Busby

Grain boundary properties are known to affect the intergranular stress corrosion cracking (IGSCC) and irradiation assisted stress corrosion cracking behavior of austenitic alloys in high temperature water. However, it is only recently that sufficient evidence has accumulated to show that the disposition of deformation in and near the grain boundary plays a key role in intergranular cracking. Grain boundaries that can transmit strain to adjacent grains can relieve stresses without undergoing localized deformation. Grain boundaries that cannot transmit strain will either experience high stresses or high strains. High stresses can lead to wedge-type cracking and sliding can lead to rupture of the protective oxide film. These processes are also applicable to irradiated materials in which the deformation can become highly localized in the form of dislocation channels and deformation twins. These deformation bands conduct tremendous amounts of strain to the grain boundaries. The capability of a boundary to transmit strain to a neighboring grain will determine its propensity for cracking, analogous to that in unirradiated metals. Thus, IGSCC in unirradiated materials and IASCC in irradiated materials are governed by the same local processes of stress and strain accommodation at the boundary.


Author(s):  
Raul B. Rebak

Austenitic stainless steels such as type 304 and 316 are susceptible to stress corrosion cracking in high temperature water environments typical of boiling water reactors (BWR) and pressurized water reactors (PWR). The accumulation over time of irradiation dose on the austenitic materials increases further their susceptibility to environmental cracking. Ferritic steels containing chromium are less susceptible to irradiation damage such as void swelling. Ferritic steels also offer desirable higher thermal conductivity and lower thermal expansion coefficient. Little is known however about the stress corrosion cracking behavior of ferritic steels in high temperature water. Crack propagation rate studies were conducted using four types of wrought and welded ferritic steels (5 to 17% Cr) in high purity water at 288°C containing dissolved oxygen or dissolved hydrogen. Results show that the ferritic steels are notably more resistant to environmental assisted cracking than the austenitic materials.


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