Concentration quenching and ignition of cuminescence of erbium ions in gadolnium oxychloride

1996 ◽  
Vol 63 (6) ◽  
pp. 849-854 ◽  
Author(s):  
T. M. Kozhan ◽  
V. V. Kuznetsova ◽  
P. P. Pershukevich ◽  
I. I. Sergeev ◽  
V. S. Khomenko
Keyword(s):  
Concentration Quenching ◽  
Erbium Ions

MICROSTRUCTURE AND OPTICAL PROPERTIES OF ERBIUM DOPED SILICA-BASED FILMS VIA FLAME HYDROLYSIS DEPOSITION AND AEROSOL DOPING

2009 ◽  
Vol 23 (06n07) ◽  
pp. 1873-1878 ◽  
Author(s):  
JIEHE SUI ◽  
HAIBO WANG ◽  
WEI CAI
Keyword(s):  
Solution Concentration ◽  
Concentration Quenching ◽  
Power Intensity ◽  
Erbium Ions ◽  
Erbium Doped ◽  
Doping Technique ◽  
Cooperative Upconversion ◽  
Pl Intensity ◽  
Flame Hydrolysis Deposition ◽  
Co Doped

Silica-based films on Si fabricated by flame hydrolysis deposition were doped with erbium ions using an aerosol doping technique, and co-doped with GeO 2, P 2 O 5 and B 2 O 3. The erbium solution concentration was varied from 4 to 8wt%. The results show that the refractive index of the films is not changed with erbium addition and no OH group is detected for erbium doped silica-based films. An obvious peak was observed at 1.542 µm with the FWHM of 65 nm, which corresponds to the 4 I 13/2 → 4 I 15/2 transition. With the increase of Er solution concentration, the photoluminescence (PL) intensity first increases, then decreases above 6 wt % Er solution concentration. The decrease in PL intensity with concentration is attributed to concentration quenching caused by Er - Er interaction. The dependence of PL intensity on pump power intensity further confirms the concentration quenching is cooperative upconversion.

Concentration quenching of the luminescence from trivalent thulium, terbium, and erbium ions embedded in an AlN matrix

2014 ◽  
Vol 145 ◽  
pp. 855-858 ◽  
Author(s):  
Felix Benz ◽  
Andreas Gonser ◽  
Reinhart Völker ◽  
Thomas Walther ◽  
Jan-Thomas Mosebach ◽  
...  
Keyword(s):  
Concentration Quenching ◽  
Erbium Ions

Influence of Boron anomaly on the NIR fluorescence concentration quenching of erbium ions in borate glasses

2021 ◽  
pp. 121274
Author(s):  
Song Chen ◽  
Siyu Zhu ◽  
Chenxing Liao ◽  
Weixiong You ◽  
Jianhui Huang ◽  
...  
Keyword(s):  
Concentration Quenching ◽  
Borate Glasses ◽  
Erbium Ions ◽  
Nir Fluorescence

Luminescence Properties of Europium-Doped Yttrium Oxides Derived from Their Dodecylsulfate-Templated Mesostructure and Nanotube Forms

2003 ◽  
Vol 775 ◽  
Author(s):  
Tsuyoshi Kijima ◽  
Kenichi Iwanaga ◽  
Tomomi Hamasuna ◽  
Shinji Mohri ◽  
Mitsunori Yada ◽  
...  
Keyword(s):  
Room Temperature ◽  
Broad Band ◽  
Concentration Quenching ◽  
Precipitation Method ◽  
Homogeneous Precipitation ◽  
Bulk Materials ◽  
Main Band ◽  
Homogeneous Precipitation Method ◽  
Order Of Magnitude ◽  
Weak Luminescence

AbstractEuropium-doped hexagonal-mesostructured and nanotubular yttrium oxides templated by dodecylsulfate species as well as surfactant free bulk oxides were synthesized by the homogeneous precipitation method. All the as grown nanostructured or bulk materials with amorphous or poorly crystalline frameworks showed weak luminescence bands at room temperature. On calcination at 1000°C these materials were converted into highly crystalline yttrium oxides, resulting in a total increase in intensity of all the bands by one order of magnitude. In the hexagonal-mesostructured system, the main band due to the 5D0-7F2 transition for the calcined phases showed a sharp but asymmetrical multiplet splitting indicating multiple Eu sites. Concentration quenching was found at a Eu content of 3 mol% or above for these phases. In contrast, the main emission for the calcined solids in the nanotubular system occurred as poorly resolved broad band and the intensity of the main band at higher Eu content was significantly enhanced compared with those for the other two systems.

scholarly journals Structure, Luminescence, and Magnetic Properties of Crystalline Manganese Tungstate Doped with Rare Earth Ion

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3717
Author(s):  
Jae-Young Jung ◽  
Soung-Soo Yi ◽  
Dong-Hyun Hwang ◽  
Chang-Sik Son
Keyword(s):  
Magnetic Field ◽  
Rare Earth ◽  
Sintering Temperature ◽  
Luminescent Properties ◽  
Concentration Quenching ◽  
Rare Earth Ions ◽  
Precipitation Method ◽  
Rare Earth Ion ◽  
Co Precipitation ◽  
Quenching Phenomenon

The precursor prepared by co-precipitation method was sintered at various temperatures to synthesize crystalline manganese tungstate (MnWO4). Sintered MnWO4 showed the best crystallinity at a sintering temperature of 800 °C. Rare earth ion (Dysprosium; Dy3+) was added when preparing the precursor to enhance the magnetic and luminescent properties of crystalline MnWO4 based on these sintering temperature conditions. As the amount of rare earth ions was changed, the magnetic and luminescent characteristics were enhanced; however, after 0.1 mol.%, the luminescent characteristics decreased due to the concentration quenching phenomenon. In addition, a composite was prepared by mixing MnWO4 powder, with enhanced magnetism and luminescence properties due to the addition of dysprosium, with epoxy. To one of the two prepared composites a magnetic field was applied to induce alignment of the MnWO4 particles. Aligned particles showed stronger luminescence than the composite sample prepared with unsorted particles. As a result of this, it was suggested that it can be used as phosphor and a photosensitizer by utilizing the magnetic and luminescent properties of the synthesized MnWO4 powder with the addition of rare earth ions.

Modeling of thermoluminescence in SrY2O4:Eu3+and their concentration quenching effect

Optik ◽  
2021 ◽  
Vol 232 ◽  
pp. 166607
Author(s):  
Amirouche Bouremani ◽  
Dahane Kadri ◽  
Ahmed Kadari ◽  
Vikas Dubey
Keyword(s):  
Concentration Quenching ◽  
Quenching Effect ◽  
Concentration Quenching Effect

Random laser in Nd:YBO3 nanocrystalline powders presenting luminescence concentration quenching

2019 ◽  
Vol 214 ◽  
pp. 116543 ◽  
Author(s):  
André L. Moura ◽  
Lauro J.Q. Maia ◽  
Vladimir Jerez ◽  
Anderson S.L. Gomes ◽  
Cid B. de Araújo
Keyword(s):  
Concentration Quenching ◽  
Nanocrystalline Powders ◽  
Random Laser ◽  
Luminescence Concentration Quenching

NIR and Upconversion Luminescence Properties of Nd3+ Doped in Gd2O3-CaO-SiO2-B2O3 Glass System

2014 ◽  
Vol 548-549 ◽  
pp. 124-128 ◽  
Author(s):  
S. Insiripong ◽  
S. Kaewjeang ◽  
U. Maghanemi ◽  
H.J. Kim ◽  
N. Chanthima ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Optical Absorption ◽  
Absorption Spectra ◽  
Upconversion Luminescence ◽  
Emission Spectra ◽  
Concentration Quenching ◽  
Luminescence Spectra ◽  
Optical Absorption Spectra ◽  
Glass Matrices ◽  
Nir Luminescence

In this work, properties of Nd3+ in Gd2O3-CaO-SiO2-B2O3 glass systems with composition 25Gd2O3-10CaO-10SiO2-(55-x)B2O3-xNd2O3 where x = 0.0, 0.5, 1.0, 1.5, 2.0 and 2.5 mol% were investigated. The optical absorption spectra show peaks at 4F3/2 (877 nm) , 4F5/2+2H9/2 (802 nm), 4F7/2+4S3/2 (743 nm), 4F9/2 (682 nm), 2H11/2 (627 nm), 2G7/2 +4G5/2 (582 nm), 4G7/2 +2K13/2 (527 nm), 4G11/2 (481 nm), 2P1/2 (427 nm) and 2L15/2 + 4D1/2 + 1I11/2+ 4D5/2+ 4D3/2 (355 nm) reflecting the Nd3+ ions in glass matrices. The densities were increased with increasing of Nd2O3 concentration. This indicates the increase of the molecular weight by the replacement of B2O3 with a heavier Nd2O3 oxide in the glass. The upconversion luminescence spectra show bands at 393 nm for all Nd2O3 concentration and the strongest intensity from 2.5 % mol of Nd2O3 was obtained. For NIR luminescence, the intensity of Nd3+ emission spectra increases with increasing concentrations of Nd3+ up to 1.5 mol% and beyond 1.5 mol% the concentration quenching is observed.

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