Substituted calix[n]arenes. Synthesis ofp-isopropylcalix[4]arene and the structure of its benzene clathrate

1996 ◽  
Vol 37 (3) ◽  
pp. 470-473 ◽  
Author(s):  
A. M. Yuldashev ◽  
B. T. Ibragimov ◽  
S. A. Talipov ◽  
H. L. Gapparov
Keyword(s):  
1980 ◽  
Vol 35 (6) ◽  
pp. 784-785 ◽  
Author(s):  
T. Stanley Cameron ◽  
Christine Chan

Abstract Hexaziridinocyclotriphosphazene forms a 2:1 clathrate with benzene. The benzene makes a sandwich between the two phosphazene molecules with the planes of the rings parallel. The geminal aziridinyl groups have a most unusual eclipsed conformation.


1999 ◽  
Vol 40 (5) ◽  
pp. 721-725 ◽  
Author(s):  
T. Kitazawa ◽  
A. Nishimura

1986 ◽  
Vol 39 (12) ◽  
pp. 1983 ◽  
Author(s):  
AJ Edwards ◽  
BF Hoskins ◽  
G Winter

The crystal and molecular structures of bis (O- benzylxanthato )nickel(II), Ni( bzxa )2, and the benzene clathrate of its 1,10-phenanthroline adduct, Ni( bzxa )2( phen ).C6H6, are reported. Crystals of Ni( bzxa )2 are orthorhombic, with the space group P bca. There are four molecules per unit cell, which has dimensions a 6.961(1), b 35.008(8), c 7.277(2)Ǻ. The refinement converged with R 0.031 and Rw 0.037 after use of 1732 independent reflections for which I ≥ 2σ(I). Asymmetry of the nickel-sulfur bonds is observed. The adduct crystallizes in the space group C2/c. There are four molecules each of the adduct and benzene per unit cell, which has dimensions a 7.133(3), b 18.196(5), c 24.282(5)Ǻ, β 97.01(2)°. The refinement converged with R 0.064 and Rw 0.052 after use of 1123 independent reflections for which I ≥ 2σ(I). The packing clearly indicates that this host-guest compound is of the clathrate type.


Author(s):  
S. Akyüz ◽  
A. B. Dempster ◽  
R. L. Morehouse ◽  
N. Zengin

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