On the extrapolation behavior of empirical equations of state

1997 ◽  
Vol 18 (6) ◽  
pp. 1415-1443 ◽  
Author(s):  
R. Span ◽  
W. Wagner
2008 ◽  
Vol 63 (6) ◽  
pp. 718-724 ◽  
Author(s):  
Wilfried B. Holzapfel

Both phonon dispersion and anharmonicity contribute to the thermo-physical properties of solids in such a way that serious mistakes can be made, if these effects are not taken into account in the realization of semi-empirical equations of state (EOS) from limited experimental data sets. These effects are illustrated in comparisons of EOS data for different types of solids.


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