On the astrogeodetic determination of the geoid by least squares estimation

1971 ◽  
Vol 100 (1) ◽  
pp. 221-224 ◽  
Author(s):  
S. Heitz
Keyword(s):  
Least Squares ◽  
Least Squares Estimation

Determination of the composition of counterfeit Heptodin™ tablets by near infrared chemical imaging and classical least squares estimation

2009 ◽  
Vol 641 (1-2) ◽  
pp. 46-51 ◽  
Author(s):  
Marta B. Lopes ◽  
Jean-Claude Wolff ◽  
José M. Bioucas-Dias ◽  
Mário A.T. Figueiredo
Keyword(s):  
Least Squares ◽  
Near Infrared ◽  
Chemical Imaging ◽  
Least Squares Estimation

scholarly journals Determination of Terrain Profile from TLS Data by Applying Msplit Estimation

2020 ◽  
Vol 13 (1) ◽  
pp. 31
Author(s):  
Patrycja Wyszkowska ◽  
Robert Duchnowski ◽  
Andrzej Dumalski
Keyword(s):  
Data Processing ◽  
Least Squares ◽  
Laser Scanning ◽  
Terrestrial Laser Scanning ◽  
Vertical Displacement ◽  
Least Squares Estimation ◽  
Displacement Analysis ◽  
Empirical Tests ◽  
The Absolute

This paper presents an application of an Msplit estimation in the determination of terrain profiles from terrestrial laser scanning (TLS) data. We consider the squared Msplit estimation as well as the absolute Msplit estimation. Both variants have never been used to determine terrain profiles from TLS data (the absolute Msplit estimation has never been applied in any TLS data processing). The profiles are computed by applying polynomials of a different degree, determining which coefficients are estimated using the method in question. For comparison purposes, the profiles are also determined by applying a conventional least squares estimation. The analyses are based on simulated as well as real TLS data. The actual objects have been chosen to contain terrain details (or obstacles), which provide some measurements which are not referred to as terrain surface; here, they are regarded as outliers. The empirical tests prove that the proposed approach is efficient and can provide good terrain profiles even if there are outliers in an observation set. The best results are obtained when the absolute Msplit estimation is applied. One can suggest that this method can be used in a vertical displacement analysis in mining damages or ground disasters.

The Estimation of Blood Platelet Survival

1972 ◽  
Vol 28 (03) ◽  
pp. 447-456 ◽  
Author(s):  
E. A Murphy ◽  
M. E Francis ◽  
J. F Mustard
Keyword(s):  
Standard Deviation ◽  
Least Squares ◽  
Experimental Error ◽  
Blood Platelet ◽  
Least Squares Estimation ◽  
Systematic Relationship ◽  
Platelet Survival ◽  
The Mean ◽  
Normally Distributed

SummaryThe characteristics of experimental error in measurement of platelet radioactivity have been explored by blind replicate determinations on specimens taken on several days on each of three Walker hounds.Analysis suggests that it is not unreasonable to suppose that error for each sample is normally distributed ; and while there is evidence that the variance is heterogeneous, no systematic relationship has been discovered between the mean and the standard deviation of the determinations on individual samples. Thus, since it would be impracticable for investigators to do replicate determinations as a routine, no improvement over simple unweighted least squares estimation on untransformed data suggests itself.

Determination of Pyridostigmine Bromide in Presence of its Related Impurities by Four Modified Classical Least Square Based Models: A Comparative Study

2020 ◽  
Vol 17 (1) ◽  
pp. 87-94
Author(s):  
Ibrahim A. Naguib ◽  
Fatma F. Abdallah ◽  
Aml A. Emam ◽  
Eglal A. Abdelaleem
Keyword(s):  
Comparative Study ◽  
Least Squares ◽  
Orthogonal Projection ◽  
Predictive Ability ◽  
Least Square ◽  
Projection To Latent Structures ◽  
Preprocessing Method ◽  
Spectral Residual ◽  
Latent Structures

: Quantitative determination of pyridostigmine bromide in the presence of its two related substances; impurity A and impurity B was considered as a case study to construct the comparison. Introduction: Novel manipulations of the well-known classical least squares multivariate calibration model were explained in detail as a comparative analytical study in this research work. In addition to the application of plain classical least squares model, two preprocessing steps were tried, where prior to modeling with classical least squares, first derivatization and orthogonal projection to latent structures were applied to produce two novel manipulations of the classical least square-based model. Moreover, spectral residual augmented classical least squares model is included in the present comparative study. Methods: 3 factor 4 level design was implemented constructing a training set of 16 mixtures with different concentrations of the studied components. To investigate the predictive ability of the studied models; a test set consisting of 9 mixtures was constructed. Results: The key performance indicator of this comparative study was the root mean square error of prediction for the independent test set mixtures, where it was found 1.367 when classical least squares applied with no preprocessing method, 1.352 when first derivative data was implemented, 0.2100 when orthogonal projection to latent structures preprocessing method was applied and 0.2747 when spectral residual augmented classical least squares was performed. Conclusion: Coupling of classical least squares model with orthogonal projection to latent structures preprocessing method produced significant improvement of the predictive ability of it.

Least Squares Estimation in Uncertain Differential Equations

2020 ◽  
Vol 28 (10) ◽  
pp. 2651-2655 ◽  
Author(s):  
Yuhong Sheng ◽  
Kai Yao ◽  
Xiaowei Chen
Keyword(s):  
Differential Equations ◽  
Least Squares ◽  
Least Squares Estimation

scholarly journals Application of Derivative, Derivative Ratio, and Multivariate Spectral Analysis and Thin-Layer Chomatography-Densitometry for Determination of a Ternary Mixture Containing Drotaverine Hydrochloride, Caffeine, and Paracetamol

2007 ◽  
Vol 90 (2) ◽  
pp. 391-404 ◽  
Author(s):  
Fadia H Metwally ◽  
Yasser S El-Saharty ◽  
Mohamed Refaat ◽  
Sonia Z El-Khateeb
Keyword(s):  
Thin Layer ◽  
Least Squares ◽  
Ternary Mixture ◽  
Principal Component Regression ◽  
Pharmaceutical Preparations ◽  
Principal Component ◽  
Standard Addition ◽  
Drotaverine Hydrochloride ◽  
Assay Precision

Abstract New selective, precise, and accurate methods are described for the determination of a ternary mixture containing drotaverine hydrochloride (I), caffeine (II), and paracetamol (III). The first method uses the first (D1) and third (D3) derivative spectrophotometry at 331 and 315 nm for the determination of (I) and (III), respectively, without interference from (II). The second method depends on the simultaneous use of the first derivative of the ratio spectra (DD1) with measurement at 312.4 nm for determination of (I) using the spectrum of 40 μg/mL (III) as a divisor or measurement at 286.4 and 304 nm after using the spectrum of 4 μg/mL (I) as a divisor for the determination of (II) and (III), respectively. In the third method, the predictive abilities of the classical least-squares, principal component regression, and partial least-squares were examined for the simultaneous determination of the ternary mixture. The last method depends on thin-layer chromatography-densitometry after separation of the mixture on silica gel plates using ethyl acetatechloroformmethanol (16 + 3 + 1, v/v/v) as the mobile phase. The spots were scanned at 281, 272, and 248 nm for the determination of (I), (II), and (III), respectively. Regression analysis showed good correlation in the selected ranges with excellent percentage recoveries. The chemical variables affecting the analytical performance of the methodology were studied and optimized. The methods showed no significant interferences from excipients. Intraday and interday assay precision and accuracy values were within regulatory limits. The suggested procedures were checked using laboratory-prepared mixtures and were successfully applied for the analysis of their pharmaceutical preparations. The validity of the proposed methods was further assessed by applying a standard addition technique. The results obtained by applying the proposed methods were statistically analyzed and compared with those obtained by the manufacturer's method.

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